7th Edition

ISBN: 9781119457282

Author: JESPERSEN

Publisher: WILEY

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Textbook Question

Chapter 11, Problem 93RQ

Intermolecular Forces and Physical Properties

Which compound should have the higher vapor pressure at 25 °C , butanol or diethyl ether? Which should have the higher boiling point?

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Chapter 11, Problem 92RQ

Chapter 11, Problem 94RQ

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12. Normal boiling point of ethanol (C2H5OH) is 78 °C, and of propanol (C3H;OH) is 97 °C. a. Explain the reason for the difference in boiling points of these two alcohols. b. When the underline methyl group in propanol, CH3CH2CH2OH, is replaced with a hydroxyl group (HOCH2CH2OH), boiling point of the molecule increases to 197 °C. Explain the reason for observed increase in the boiling point.

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Essential oils are concentrated liquid containing metabolites extracted from plant sources and are widely used in the production of perfumes. The structures of some of these compounds present in essential oils, along with acetone, are presented below. CH3 H2C CH H2 H3CO, CH2 CH H2C H2C CH FCH2 HO H3C CH2 Compound A MM: 164.2 g/mol Boiling Point: 254 C Compound B MM: 162.19 g/mol Boiling Point: 232 C Compound C MM: 136.24 g/mol Boiling Point: 176 C Determine the most possible boiling point of each of the compounds. Refer to the possible boiling points listed above. An equal volume of COMPOUNDS A, B and C were stored in separate beakers which were left uncovered at room temperature. 1. 2. If the three liquids were allowed to stand for about 10 minutes, which of the following will have the least amount of liquid b. What physical property is the basis of the answer? Among the three liquids, what is the most recommended ingredient of a perfume that will have the most lasting scent? а.…

Chapter 11 Solutions

CHEMISTRY:MOLECULAR..(LL)-PRINT..W/CODE

Ch. 11 - Prob. 1PE Ch. 11 - List the following in order of their boiling...Ch. 11 - Propylamine and trimethylamine have the same...Ch. 11 - People living in arid, dry, regions can cool their...Ch. 11 - Use the kinetic molecular theory to explain why...Ch. 11 - Considering Figure 11.24, in which direction...Ch. 11 - Suppose a liquid is in equilibrium with its vapor...Ch. 11 - The Dead Sea is approximately 1300 ft below sea...Ch. 11 - The atmospheric pressure at the summit of Mt....Ch. 11 - Benzene has a boiling point of 80.1C, and a...

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