The change in a blood cell when placed in pure water is to be explained. Concept Introduction: Blood solution is an isotonic solution as the concentration of the dissolved solute and red blood cells and are the same in it. A blood solution may also have more or less solute concentration as compared to the red blood cells. When the solute concentration is more than red blood cells in a blood solution, it is called hypertonic while when the solute concentration is less than red blood cells, it is called hypotonic. For both hypertonic and hypotonic blood solutions, water may leave or enter the red blood cells, depending on the solute concentration, via osmosis. Osmosis is a process in which the transfer of the solvent particles takes place through a barrier that restricts the passage of the solute particles.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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Question

Chapter 11, Problem 88QP

Interpretation Introduction

Interpretation:

The change in a blood cell when placed in pure water is to be explained.

Concept Introduction:

Blood solution is an isotonic solution as the concentration of the dissolved solute and red blood cells and are the same in it. A blood solution may also have more or less solute concentration as compared to the red blood cells. When the solute concentration is more than red blood cells in a blood solution, it is called hypertonic while when the solute concentration is less than red blood cells, it is called hypotonic. For both hypertonic and hypotonic blood solutions, water may leave or enter the red blood cells, depending on the solute concentration, via osmosis. Osmosis is a process in which the transfer of the solvent particles takes place through a barrier that restricts the passage of the solute particles.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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