EBK INTRODUCTORY CHEMISTRY
8th Edition
ISBN: 8220100480485
Author: DECOSTE
Publisher: CENGAGE L
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Textbook Question
Chapter 11, Problem 83AP
Consider the bright line spectrum of hydrogen shown in Fig.
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
८८
2
"Br
{t༐B,gt)-bemn€-nehpརི་ཚ༐lnoa
Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 11 Solutions
EBK INTRODUCTORY CHEMISTRY
Ch. 11.4 - now have evidence that electron energy levels in...Ch. 11.8 - Prob. 11.1SCCh. 11.9 - Prob. 11.2SCCh. 11.10 - Prob. 11.3SCCh. 11.10 - Prob. 1CTCh. 11 - ow does probability ?t into the description of the...Ch. 11 - Prob. 2ALQCh. 11 - Prob. 3ALQCh. 11 - onsider the following statements: “The ionization...Ch. 11 - n going across a row of the periodic table,...
Ch. 11 - Prob. 6ALQCh. 11 - rue or false? The hydrogen atom has a 3 orbital....Ch. 11 - Prob. 8ALQCh. 11 - ake sense of the fact that metals tend to lose...Ch. 11 - Show how using the periodic table helps you find...Ch. 11 - r Questions 11—13, you will need to consider...Ch. 11 - Prob. 12ALQCh. 11 - Prob. 13ALQCh. 11 - Prob. 14ALQCh. 11 - Prob. 15ALQCh. 11 - What evidence do we have that energy levels in an...Ch. 11 - Explain the hydrogen emission spectrum. Why is it...Ch. 11 - There am an infinite number of allowed transitions...Ch. 11 - You have learned that each orbital is allowed two...Ch. 11 - Atom A has valence electrons that are lower in...Ch. 11 - Prob. 21ALQCh. 11 - Prob. 1QAPCh. 11 - hat questions were left unanswered by Rutherford’s...Ch. 11 - Prob. 3QAPCh. 11 - Prob. 4QAPCh. 11 - Prob. 5QAPCh. 11 - Prob. 6QAPCh. 11 - he “Chemistry in Focus" segment Light as a Sex...Ch. 11 - Prob. 8QAPCh. 11 - hen lithium salts are heated in a flame, they emit...Ch. 11 - The energy of a photon of visible light emitted by...Ch. 11 - Prob. 11QAPCh. 11 - When an atom in an excited state returns to its...Ch. 11 - How is the energy carried per photon of light...Ch. 11 - When an atom energy from outside, the atom goes...Ch. 11 - Describe briefly why the study of electromagnetic...Ch. 11 - What does it mean to say that the hydrogen atom...Ch. 11 - Because a given element’s atoms emit only certain...Ch. 11 - How does the energy possessed by an emitted photon...Ch. 11 - Prob. 19QAPCh. 11 - When a tube containing hydrogen atoms is energized...Ch. 11 - What are the essential points of Bohr‘s theory of...Ch. 11 - According to Bohr, what happens to the electron...Ch. 11 - How does the Bohr theory account for the observed...Ch. 11 - Why was Bohr's theory for the hydrogen atom...Ch. 11 - What major assumption (that was analogous to what...Ch. 11 - Discuss briefly the difference between an orbit...Ch. 11 - Why was Schrodinger not able to describe exactly...Ch. 11 - Section 11.6 uses a "firefly" analogy to...Ch. 11 - Your text describes the probability map for an s...Ch. 11 - Consider the following representation of a set of...Ch. 11 - What are the differences between the :math>2s...Ch. 11 - What overall shape do the 2p and 3p orbitals have?...Ch. 11 - Prob. 33QAPCh. 11 - When the electron in hydrogen is in the n=3...Ch. 11 - Although a hydrogen atom has only one electron,...Ch. 11 - Complete the following table. trong>Value of n...Ch. 11 - When describing the electrons in an orbital, we...Ch. 11 - Why can only two electrons occupy a particular...Ch. 11 - How does the energy of a principal energy level...Ch. 11 - The number of sublevels in a principal energy...Ch. 11 - According to the Pauli exclusion principle, a...Ch. 11 - Prob. 42QAPCh. 11 - Which of the following orbital designations...Ch. 11 - Prob. 44QAPCh. 11 - Which orbital is the first be filled in any atom?...Ch. 11 - When a hydrogen atom is in its ground state, in...Ch. 11 - Prob. 47QAPCh. 11 - How are the electron arrangements in a given group...Ch. 11 - Write the full electron configuration ( 1s22s2...Ch. 11 - To which element does each of the following...Ch. 11 - Write the full electron configuration...Ch. 11 - To which element does each of the following...Ch. 11 - Write the complete orbital diagram for each of the...Ch. 11 - Prob. 54QAPCh. 11 - Prob. 55QAPCh. 11 - Prob. 56QAPCh. 11 - Why do we believe that the valence electrons of...Ch. 11 - Would you expect the Valence electrons of rubidium...Ch. 11 - Using the symbol of the previous noble gas in...Ch. 11 - Prob. 60QAPCh. 11 - Prob. 61QAPCh. 11 - How many valence electrons does each of the...Ch. 11 - How many 3d electrons are found in each of the...Ch. 11 - Based on the elements’ locations on the periodic...Ch. 11 - For each of the following elements, indicate which...Ch. 11 - Write the valence-electron configuration of each...Ch. 11 - Prob. 67QAPCh. 11 - The “Chemistry in Focus" segment The Chemistry of...Ch. 11 - What are some of the physical properties that...Ch. 11 - Prob. 70QAPCh. 11 - Give some similarities than exist among the...Ch. 11 - Give some similarities that exist among the...Ch. 11 - Which of the following elements most easily gives...Ch. 11 - Which elements in a given period (horizontal row)...Ch. 11 - Where are the most nonmetallic elements located on...Ch. 11 - Why do the metallic elements of a given period...Ch. 11 - Prob. 77QAPCh. 11 - The “Chemistry in Focus" segment Fireworks...Ch. 11 - Prob. 79QAPCh. 11 - In each of the following sets of elements, which...Ch. 11 - Arrange the following sets of elements in order of...Ch. 11 - In each of the following sets of elements,...Ch. 11 - Consider the bright line spectrum of hydrogen...Ch. 11 - Prob. 84APCh. 11 - The portion of the electromagnetic spectrum...Ch. 11 - A beam of light can be thought of as consisting of...Ch. 11 - Prob. 87APCh. 11 - The Energy levels of hydrogen (and other atoms)...Ch. 11 - According to Bohr, the electron in the hydrogen...Ch. 11 - Prob. 90APCh. 11 - Electrons found in the outemost principal energy...Ch. 11 - Prob. 92APCh. 11 - Prob. 93APCh. 11 - Prob. 94APCh. 11 - Prob. 95APCh. 11 - Prob. 96APCh. 11 - Without referring to your textbook or a periodic...Ch. 11 - Prob. 98APCh. 11 - Prob. 99APCh. 11 - Prob. 100APCh. 11 - ight waves move through space at a speed of ters...Ch. 11 - Prob. 102APCh. 11 - ow does the attractive force that the nucleus...Ch. 11 - Prob. 104APCh. 11 - Prob. 105APCh. 11 - Prob. 106APCh. 11 - hy do we believe that the three electrons in the...Ch. 11 - Prob. 108APCh. 11 - Prob. 109APCh. 11 - Prob. 110APCh. 11 - Prob. 111APCh. 11 - Prob. 112APCh. 11 - Prob. 113APCh. 11 - Prob. 114APCh. 11 - Prob. 115APCh. 11 - Prob. 116APCh. 11 - n each of the following sets of elements, indicate...Ch. 11 - Prob. 118APCh. 11 - Determine the maximum number of electrons that can...Ch. 11 - hich of the following statements is(are) true? The...Ch. 11 - ive the electron configurations for the following...Ch. 11 - Prob. 122CPCh. 11 - Prob. 123CPCh. 11 - Prob. 124CPCh. 11 - Prob. 125CPCh. 11 - Prob. 126CP
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