7th Edition

ISBN: 9781119664796

Author: JESPERSEN

Publisher: WILEY

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Chapter 11, Problem 7PE

Suppose a liquid is in equilibrium with its vapor in a piston-cylinder apparatus like that in Figure 11.24. If the piston is pushed in a short way and the system is allowed to return to equilibrium, what will have happened to the total number of molecules in both the liquid and the vapor?

Figure 11.24 The effect of a volume change on the vapor pressure of a liquid.

(a) Equilibrium exists between liquid and vapor. (b) The volume is increased, which upsets the equilibrium and causes the pressure to drop. The rate of condensation is now less than the rate of evaporation, which hasn’t changed. (c) After more liquid has evaporated, equilibrium is restored and the vapor pressure has returned to its initial value.

Chapter 11, Problem 7PE, Suppose a liquid is in equilibrium with its vapor in a piston-cylinder apparatus like that in Figure

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Chapter 11 Solutions

MOLECULAR NATURE OF MATTER 7/E LL W/AC

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