The mechanism of the given reaction should be proposed. Concept introduction: In the presence of acid catalyst, this reaction takes place through partial S N 1 and partial S N 2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product. Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

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Answer 1

Question

Chapter 11, Problem 75P

(a)

Interpretation Introduction

Interpretation:

The mechanism of the given reaction should be proposed.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(b)

Interpretation Introduction

Interpretation:

The structure of all products that formed in the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(c)

Interpretation Introduction

Interpretation:

The reason should be explained for the formation of six member ring compound in the given reaction.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

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Answer 2

Question

Chapter 11, Problem 75P

(a)

Interpretation Introduction

Interpretation:

The mechanism of the given reaction should be proposed.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(b)

Interpretation Introduction

Interpretation:

The structure of all products that formed in the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(c)

Interpretation Introduction

Interpretation:

The reason should be explained for the formation of six member ring compound in the given reaction.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

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Answer 3

Question

Chapter 11, Problem 75P

(a)

Interpretation Introduction

Interpretation:

The mechanism of the given reaction should be proposed.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(b)

Interpretation Introduction

Interpretation:

The structure of all products that formed in the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(c)

Interpretation Introduction

Interpretation:

The reason should be explained for the formation of six member ring compound in the given reaction.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

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Answer 4

Question

Chapter 11, Problem 75P

(a)

Interpretation Introduction

Interpretation:

The mechanism of the given reaction should be proposed.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(b)

Interpretation Introduction

Interpretation:

The structure of all products that formed in the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(c)

Interpretation Introduction

Interpretation:

The reason should be explained for the formation of six member ring compound in the given reaction.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Expert Solution & Answer

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Answer 5

Chapter 11, Problem 75P

(a)

Interpretation Introduction

Interpretation:

The mechanism of the given reaction should be proposed.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(b)

Interpretation Introduction

Interpretation:

The structure of all products that formed in the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

(c)

Interpretation Introduction

Interpretation:

The reason should be explained for the formation of six member ring compound in the given reaction.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 6

Chapter 11, Problem 75P

(a)

Interpretation Introduction

Interpretation:

The mechanism of the given reaction should be proposed.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 7

Chapter 11, Problem 75P

(a)

Interpretation Introduction

Interpretation:

The mechanism of the given reaction should be proposed.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of all products that formed in the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of all products that formed in the given reaction should be drawn.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The reason should be explained for the formation of six member ring compound in the given reaction.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The reason should be explained for the formation of six member ring compound in the given reaction.

Concept introduction:

In the presence of acid catalyst, this reaction takes place through partial SN1 and partial SN2 pathway. Epoxides are reactive, Epoxides get protonated followed by alcohol attacks to the stable carbocation and form the product.

Epoxides are reactive, methoxide ion attacks epoxides in a less sterically hindered position which forms the alkoxide ion, and then it gets proton from alcohol which form the product.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 11.1 - Why are NH3 and CH3NH2 no longer nucleophiles when...Ch. 11.1 - Prob. 2P Ch. 11.1 - Prob. 5P Ch. 11.2 - Prob. 7P Ch. 11.3 - Prob. 9P Ch. 11.3 - Show how 1-propanol can be converted into the...Ch. 11.4 - Which of the following alcohols dehydrates the...Ch. 11.4 - Prob. 12P Ch. 11.4 - Prob. 13P Ch. 11.4 - Propose a mechanism for each of the following...

Solution Summary: The author explains the mechanism of the reaction in the presence of acid catalyst.

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Chapter 11 Solutions