The respective reactant (methyl substituted piperidine) and respective product (diene) should be given. Concept introduction: Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt. These quaternary ammonium salt under goes an elimination reaction easily. Hofmann elimination: Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Question

Want to see the full answer?

Answer 1

Question

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Photochemical smog is formed in part by the action of light on nitrogen dioxide. The wavelength of radiation absorbed by NO2 in this reaction is 197 nm.(a) Draw the Lewis structure of NO2 and sketch its π molecular orbitals.(b) When 1.56 mJ of energy is absorbed by 3.0 L of air at 20 °C and 0.91 atm, all the NO2 molecules in this sample dissociate by the reaction shown. Assume that each absorbed photon leads to the dissociation (into NO and O) of one NO2 molecule. What is the proportion, in parts per million, of NO2 molecules in this sample? Assume that the sample behaves ideally.

Correct each molecule in the drawing area below so that it has the skeletal ("line") structure it would have if it were dissolved in a 0.1 M aqueous solution of HCI. If there are no changes to be made, check the No changes box under the drawing area. No changes. HO Explanation Check NH, 2 W O :□ G ©2025 M unter Accessibility

An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.

Answer 2

Question

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 6

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 7

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 17

Ch. 11.1 - Why are NH3 and CH3NH2 no longer nucleophiles when...Ch. 11.1 - Prob. 2P Ch. 11.1 - Prob. 5P Ch. 11.2 - Prob. 7P Ch. 11.3 - Prob. 9P Ch. 11.3 - Show how 1-propanol can be converted into the...Ch. 11.4 - Which of the following alcohols dehydrates the...Ch. 11.4 - Prob. 12P Ch. 11.4 - Prob. 13P Ch. 11.4 - Propose a mechanism for each of the following...

Solution Summary: The author explains how amines can be converted into quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate.

Concept explainers

Want to see the full answer?

Chapter 11 Solutions