CHEMISTRY IN FOCUS (LL)-TEXT
CHEMISTRY IN FOCUS (LL)-TEXT
7th Edition
ISBN: 9781337399845
Author: Tro
Publisher: CENGAGE L
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Chapter 11, Problem 36E
Interpretation Introduction

Interpretation:

The error in the argument that natural sources such as volcanoes add more chlorine to the stratosphere is to be explained.

Concept Introduction:

Ozone is a component of photochemical smog and is formed by the action of sunlight. Ozone in the troposphere is polluted, but in the stratosphere, it is a natural and essential part of our atmosphere. HCFCs and CFCs are a class of inert compounds of carbon, chlorine, and fluorine. They are quite useful for many applications. But the inertness of HCFCs has an environmental effect because of the presence of chlorine. However, due to the presence of hydrogen, they are more reactive and less environmentally degrading than CFCs.

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fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

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CHEMISTRY IN FOCUS (LL)-TEXT

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