Organic Chemistry
3rd Edition
ISBN: 9781119338352
Author: Klein
Publisher: WILEY
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Chapter 11, Problem 34IP
Interpretation Introduction
Interpretation:
A multi-step synthesis of 1-penten-3-ol using acetylene as only source of carbon atoms has to be given.
Concept Introduction:
Catalytic hydrogenation: It is the addition of molecular hydrogen across triple bond in presence of Lindlar’s catalyst. This catalyst stops hydrogenation to
Ozonolysis: It involves breaking of alkene double bond and addition of oxygen atoms to form carbonyl compounds.
Hydro-halogenation reaction: In this reaction, hydrogen halide added across the unsaturated bond (alkene).
Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides
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Phenol is the starting material for the synthesis of 2,3,4,5,6-pentachlorophenol, known al-ternatively as pentachlorophenol, or more simply as penta. At one time, penta was widely used as a wood preservative for decks, siding, and outdoor wood furniture. Draw the structural formula for pentachlorophenol and describe its synthesis from phenol.
12
Mass Spectrometry
(d) This unknown contains oxygen, but it does not show any significant infrared absorption
peaks above 3000 cm .
59
100-
BO
40
Relative Abundance
M(102)
-
15 20
25 30 35 40 45 50 5
60 65 70 75 80
85 90 95 100 105
miz
Draw a Haworth projection of a common cyclic form of this monosaccharide:
H
HO
H
HO
H
HO
H
H
-OH
CH2OH
Click and drag to start drawing a
structure.
Х
:
D
Chapter 11 Solutions
Organic Chemistry
Ch. 11.1 - Prob. 1CCCh. 11.1 - Prob. 2CCCh. 11.2 - Prob. 1LTSCh. 11.2 - Prob. 3PTSCh. 11.2 - Prob. 4ATSCh. 11.3 - Prob. 2LTSCh. 11.3 - Prob. 5PTSCh. 11.3 - As we will see in Chapter 26, steroids are a class...Ch. 11.4 - Prob. 3LTSCh. 11.4 - Prob. 7PTS
Ch. 11.4 - Prob. 8ATSCh. 11.5 - Prob. 4LTSCh. 11.5 - Prob. 9PTSCh. 11.5 - Prob. 10ATSCh. 11 - Prob. 11PPCh. 11 - Prob. 12PPCh. 11 - Prob. 13PPCh. 11 - Prob. 14PPCh. 11 - Prob. 15PPCh. 11 - Prob. 16PPCh. 11 - Prob. 17PPCh. 11 - Prob. 18PPCh. 11 - Prob. 19PPCh. 11 - Prob. 20PPCh. 11 - Prob. 21PPCh. 11 - Prob. 22PPCh. 11 - Prob. 23PPCh. 11 - Prob. 24PPCh. 11 - Prob. 25PPCh. 11 - Prob. 26PPCh. 11 - Prob. 27IPCh. 11 - Prob. 28IPCh. 11 - Prob. 29IPCh. 11 - Prob. 30IPCh. 11 - Prob. 31IPCh. 11 - In a study of volatile compounds extracted from...Ch. 11 - Kakkon is the root of an Asian plant that has...Ch. 11 - Prob. 34IPCh. 11 - Prob. 35IPCh. 11 - Prob. 37IPCh. 11 - The aroma, taste, and general quality of wine are...Ch. 11 - Prob. 39CPCh. 11 - Prob. 40CPCh. 11 - Prob. 42CPCh. 11 - Prob. 43CP
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