(a)
Interpretation:
Products of the given reaction have to be determined.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.
Heck reaction:
A reaction that breaks the double bond of
Organoboron compound:
An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:
Coupling reaction:
A reaction that joins two groups with a carbon-carbon bond.
(b)
Interpretation:
Products of the given reaction have to be determined.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.
Heck reaction:
A reaction that breaks the double bond of alkene and then joins the fragments.
Organoboron compound:
An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:
Coupling reaction:
A reaction that joins two groups with a carbon-carbon bond.
(c)
Interpretation:
Products of the given reaction have to be determined.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.
Heck reaction:
A reaction that breaks the double bond of sa alkene and then joins the fragments.
Organoboron compound:
An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:
Coupling reaction:
A reaction that joins two groups with a carbon-carbon bond.
(d)
Interpretation:
Products of the given reaction have to be determined.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.
Heck reaction:
A reaction that breaks the double bond of alkene and then joins the fragments.
Organoboron compound:
An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:
Coupling reaction:
A reaction that joins two groups with a carbon-carbon bond.
(e)
Interpretation:
Product of the given reaction has to be written.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.
Heck reaction:
A reaction that breaks the double bond of alkene and then joins the fragments.
Organoboron compound:
An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:
Coupling reaction:
A reaction that joins two groups with a carbon-carbon bond.
(f)
Interpretation:
Product of the given reaction has to be identified.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.
Heck reaction:
A reaction that breaks the double bond of an alkene and then joins the fragments.
Organoboron compound:
An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:
Coupling reaction:
A reaction that joins two groups with a carbon-carbon bond.
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Chapter 11 Solutions
CHEM 262 ORG CHEM EBOOK DIGITAL DELIVERY
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- When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.arrow_forwardWhen 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol. Which experimental number must be initialled by the Lab TA for the first run of Part 1 of the experiment? a) the heat capacity of the calorimeter b) Mass of sample c) Ti d) The molarity of the HCl e) Tfarrow_forwardPredict products for the Following organic rxn/s by writing the structurels of the correct products. Write above the line provided" your answer D2 ①CH3(CH2) 5 CH3 + D₂ (adequate)" + 2 mited) 19 Spark Spark por every item. 4 CH 3 11 3 CH 3 (CH2) 4 C-H + CH3OH CH2 CH3 + CH3 CH2OH 0 CH3 fou + KMnDy→ C43 + 2 KMn Dy→→ C-OH ") 0 C-OH 1110 (4.) 9+3 =C CH3 + HNO 3 0 + Heat> + CH3 C-OH + Heat CH2CH3 - 3 2 + D Heat H 3 CH 3 CH₂ CH₂ C = CH + 2 H₂ → 2 2arrow_forward
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