Using KF as an example, write equations that refer to ∆ H soln and ∆ H hyd · Lattice energy was defined in Chapter 3 as ∆ H for the reaction K + ( g ) + F − ( g ) → KF( s ). Show how you would utilize Hess’s law to calculate ∆ H so1n from ∆ H hyd and ∆ H LE for KF, where ∆ H LE = lattice energy. ∆ H soln for KF, as for other soluble ionic compounds, is a relatively small number. How can this be since ∆ H hyd and ∆ H LE are relatively large negative numbers?
Using KF as an example, write equations that refer to ∆ H soln and ∆ H hyd · Lattice energy was defined in Chapter 3 as ∆ H for the reaction K + ( g ) + F − ( g ) → KF( s ). Show how you would utilize Hess’s law to calculate ∆ H so1n from ∆ H hyd and ∆ H LE for KF, where ∆ H LE = lattice energy. ∆ H soln for KF, as for other soluble ionic compounds, is a relatively small number. How can this be since ∆ H hyd and ∆ H LE are relatively large negative numbers?
Solution Summary: The author explains how Hess's law calculates the enthalpy change for reactants to products, whether the process takes place in single or sequence of steps.
Using KF as an example, write equations that refer to ∆Hsoln and ∆Hhyd· Lattice energy was defined in Chapter 3 as ∆H for the reaction K+(g) + F− (g) → KF(s). Show how you would utilize Hess’s law to calculate ∆Hso1n from ∆Hhyd and ∆HLE for KF, where ∆HLE = lattice energy. ∆Hsoln for KF, as for other soluble ionic compounds, is a relatively small number. How can this be since ∆Hhyd and ∆HLE are relatively large negative numbers?
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Gramicidin A can adopt more than one structure; NMR spectroscopy has revealed an “end-to-end” dimer form, and x-ray crystallography has revealed an “anti-parallel double- helical” form. Briefly outline and describe an experimentalapproach/strategy to investigate WHICH configuration (“end-to-end dimer” vs “anti-paralleldouble helical”) gramicidin adopts in an actual lipid bilayer.
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