GENERAL CHEMISTRY(LL)-W/MASTERINGCHEM.
11th Edition
ISBN: 9780134566030
Author: Petrucci
Publisher: PEARSON
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Chapter 11, Problem 26E
Dimethylolpropionic acid, shown below, is used in the preparation of resins.
Represent the bonding in the dimethylolpropionic acid molecule by using the method in Figure 11-19 to indicate hybridization schemes and orbital overlaps. What is the maximum number of atoms that can lie in the same plane?
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Questions 4 and 5
For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.
Predict the major organic product(s), if any, of the following reactions. Assume all reagents are in excess unless otherwise indicated.
Chapter 11 Solutions
GENERAL CHEMISTRY(LL)-W/MASTERINGCHEM.
Ch. 11 - Prob. 1ECh. 11 - Explain why it is necessary to hybridize atomic...Ch. 11 - Describe the molecular geometry of H2O suggested...Ch. 11 - Describe the molecular geometry of NH2 suggested...Ch. 11 - In which of the following, CO32-,SO2,CCl4,CO,NO3-...Ch. 11 - In the manner of Example 11-1, describe the...Ch. 11 - For each of the following species, identify the...Ch. 11 - Propose a plausible Lewis structure, geometric...Ch. 11 - Describe a hybridization scheme for the central Cl...Ch. 11 - Describe a hybridization scheme for the central S...
Ch. 11 - Match each of the following species with one of...Ch. 11 - Propose a hybridization scheme to account for...Ch. 11 - Indicate which of the following molecules and ions...Ch. 11 - In the manner of Figure 11-18, indicate the...Ch. 11 - Write Lewis structures for the following...Ch. 11 - Represent bonding in the carbon dioxide molecule,...Ch. 11 - Use the method of Figure 11-19 to represent...Ch. 11 - Use the method of Figure 11-19 to represent...Ch. 11 - The molecular model below represents citric acid,...Ch. 11 - Malic is e common organic acid found in unripe...Ch. 11 - Shown below are ball-and-stick models. Describe...Ch. 11 - Shown below are ban-and-stick models. Describe...Ch. 11 - Prob. 23ECh. 11 - The structure of the molecule allene, CH2CCH2 , is...Ch. 11 - Angelic acid, shown below, occurs in symbol root,...Ch. 11 - Dimethylolpropionic acid, shown below, is used in...Ch. 11 - Explain the essential difference in how the...Ch. 11 - Describe the bond order of diatomic carbon, C2 ,...Ch. 11 - Prob. 29ECh. 11 - The paramagnetism of gaseous B2 has been...Ch. 11 - Prob. 31ECh. 11 - Is it correct to say that when a diatomic molecule...Ch. 11 - For the following pairs of molecular orbitals,...Ch. 11 - For each of the species C2+,O2,F2+ , and NO+ ; a....Ch. 11 - Write plausible molecular orbital occupancy...Ch. 11 - We have used the term “isoelectronic” to refer to...Ch. 11 - Consider the molecules NO+ and N2+ and use...Ch. 11 - Consider the molecules CO+ and CN- and use...Ch. 11 - Construct the molecular orbital diagram for CF....Ch. 11 - Construct the molecular orbital diagram for SrCl....Ch. 11 - Explain why the concept of delocalized molecular...Ch. 11 - Explain how it is possible to avoid the concept of...Ch. 11 - In which of the following molecules would you...Ch. 11 - In which of the following ions would you expect to...Ch. 11 - The Lewis structure of N2 indicates that the...Ch. 11 - Show that both the valence bond method and...Ch. 11 - A group of spectroscopists believe that they have...Ch. 11 - Lewis theory is satisfactory to explain bonding in...Ch. 11 - The compound potassium sesquoxide has the...Ch. 11 - Draw a Lewis structure for the urea molecule, CO(...Ch. 11 - Methyl nitrate, CH2NO2 , is used as a rocket...Ch. 11 - Fluorine nitrate, FONO2 , is an oxidizing agent...Ch. 11 - Draw a Lewis structure(s) for the nitrite ion, NO2...Ch. 11 - Think of the reaction shown here as involving the...Ch. 11 - Prob. 55IAECh. 11 - Prob. 56IAECh. 11 - The molecule formamide, HCONH2 , has the...Ch. 11 - Pyridine, C2H2N , is used in the synthesis of...Ch. 11 - Prob. 59IAECh. 11 - The ion F2Cl is linear, but the ion F2Cl+ is bent....Ch. 11 - Prob. 61IAECh. 11 - Prob. 62IAECh. 11 - Prob. 63IAECh. 11 - Prob. 64IAECh. 11 - Histidine, an essential amino acid, serves as a...Ch. 11 - The anion I42 is linear, and the anion I5 is...Ch. 11 - Prob. 67IAECh. 11 - A conjugated hydrocarbon has an alternation of...Ch. 11 - An elusive intermediate of atmospheric reactions...Ch. 11 - Resonance energy is the difference in energy...Ch. 11 - Furan, C4H4O , is a substance derivable from oat...Ch. 11 - As discussed in Are You Wondering 11-1, the sp...Ch. 11 - In Chapter 10, we saw that electronegativity...Ch. 11 - Borazine, B2N2H2 is often referred to as inorganic...Ch. 11 - Which of the following combinations of orbitals...Ch. 11 - Prob. 76FPCh. 11 - Prob. 77SAECh. 11 - Prob. 78SAECh. 11 - Explain the important distinctions between the...Ch. 11 - A molecule in which sp2 hybrid orbitals are used...Ch. 11 - Prob. 81SAECh. 11 - The hybridization scheme for the central atom...Ch. 11 - Of the following, the species with a bond order of...Ch. 11 - The hybridization scheme for Xe in XeF2 is (a) sp;...Ch. 11 - Delocalized molecular orbitals are found in (a)...Ch. 11 - Prob. 86SAECh. 11 - Why does the hybridization sp2d not account for...Ch. 11 - What is the total number of (a) bonds and (b) p...Ch. 11 - Which of the following species are paramagnetic?...Ch. 11 - Use the valence molecular orbital configuration to...Ch. 11 - Use the valence molecular orbital configuration to...Ch. 11 - Which of these diatomic molecules do you think has...Ch. 11 - For each of the following ions or molecules,...Ch. 11 - Draw Lewis structures for the NO2 and NO2+ ions,...Ch. 11 - In which of the following is the central atom sp...Ch. 11 - Prob. 96SAECh. 11 - According to molecular orbital theory, the O22 ion...Ch. 11 - What is the angle between the hybrid orbitals...Ch. 11 - Consider the molecule with the Lewis structure...Ch. 11 - Construct a concept map that embodies the ideas of...Ch. 11 - Prob. 101SAECh. 11 - Construct a concept map that describes the...
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