
(a)
Interpretation:
The rate of the given reaction has to be expressed in terms of
Concept Introduction:
When the rate is expressed in terms of change in reactant concentration, a minus sign has to be given. Since change in time will be a positive quantity and reactant concentration decreases with time change in concentration of reactant will be negative. So in order to make the rate a positive quantity negative sign is given.
But if the rate is expressed in terms of change in concentration of products, which is a positive quantity, no need of negative sign in the rate expression.
(b)
Interpretation:
The rate of the given reaction has to be expressed in terms of
Concept Introduction:
Refer to part (a).

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Chapter 11 Solutions
Bundle: Chemistry: The Molecular Science, 5th, Loose-Leaf + OWLv2 with Quick Prep 24-Months Printed Access Card
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