ATKINS' PHYSICAL CHEMISTRY-ACCESS
ATKINS' PHYSICAL CHEMISTRY-ACCESS
11th Edition
ISBN: 9780198834700
Author: ATKINS
Publisher: OXF
Question
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Chapter 11, Problem 11B.6BE
Interpretation Introduction

Interpretation:

The molecules that show pure rotational microwave spectrum have to be stated.

Concept introduction:

Microwave spectroscopy is a spectroscopic technique governing the absorption of radiations in the microwave region.  For a molecule to exhibit pure rotational spectrum, the molecule must possess a permanent electric dipole moment.  The molecules possessing dipole moment is considered as a handle that stirs the electromagnetic field into oscillation.  Polar molecules possess electric dipole moment and thus are classified as microwave active.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Chapter 11 Solutions

ATKINS' PHYSICAL CHEMISTRY-ACCESS

Ch. 11 - Prob. 11E.2STCh. 11 - Prob. 11F.2STCh. 11 - Prob. 11A.1DQCh. 11 - Prob. 11A.2DQCh. 11 - Prob. 11A.3DQCh. 11 - Prob. 11A.1AECh. 11 - Prob. 11A.1BECh. 11 - Prob. 11A.2AECh. 11 - Prob. 11A.2BECh. 11 - Prob. 11A.3AECh. 11 - Prob. 11A.3BECh. 11 - Prob. 11A.4AECh. 11 - Prob. 11A.4BECh. 11 - Prob. 11A.5AECh. 11 - Prob. 11A.5BECh. 11 - Prob. 11A.6AECh. 11 - Prob. 11A.6BECh. 11 - Prob. 11A.7AECh. 11 - Prob. 11A.7BECh. 11 - Prob. 11A.8AECh. 11 - Prob. 11A.8BECh. 11 - Prob. 11A.9AECh. 11 - Prob. 11A.9BECh. 11 - Prob. 11A.10AECh. 11 - Prob. 11A.10BECh. 11 - Prob. 11A.11AECh. 11 - Prob. 11A.11BECh. 11 - Prob. 11A.12AECh. 11 - Prob. 11A.12BECh. 11 - Prob. 11A.1PCh. 11 - Prob. 11A.2PCh. 11 - Prob. 11A.3PCh. 11 - Prob. 11A.4PCh. 11 - Prob. 11A.5PCh. 11 - Prob. 11A.7PCh. 11 - Prob. 11A.8PCh. 11 - Prob. 11A.9PCh. 11 - Prob. 11A.11PCh. 11 - Prob. 11B.1DQCh. 11 - Prob. 11B.2DQCh. 11 - Prob. 11B.3DQCh. 11 - Prob. 11B.4DQCh. 11 - Prob. 11B.5DQCh. 11 - Prob. 11B.6DQCh. 11 - Prob. 11B.7DQCh. 11 - Prob. 11B.8DQCh. 11 - Prob. 11B.1AECh. 11 - Prob. 11B.1BECh. 11 - Prob. 11B.3AECh. 11 - Prob. 11B.3BECh. 11 - Prob. 11B.4BECh. 11 - Prob. 11B.5AECh. 11 - Prob. 11B.5BECh. 11 - Prob. 11B.6AECh. 11 - Prob. 11B.6BECh. 11 - Prob. 11B.7AECh. 11 - Prob. 11B.7BECh. 11 - Prob. 11B.8AECh. 11 - Prob. 11B.8BECh. 11 - Prob. 11B.9AECh. 11 - Prob. 11B.9BECh. 11 - Prob. 11B.10AECh. 11 - Prob. 11B.10BECh. 11 - Prob. 11B.11AECh. 11 - Prob. 11B.11BECh. 11 - Prob. 11B.12AECh. 11 - Prob. 11B.12BECh. 11 - Prob. 11B.13AECh. 11 - Prob. 11B.13BECh. 11 - Prob. 11B.14AECh. 11 - Prob. 11B.14BECh. 11 - Prob. 11B.1PCh. 11 - Prob. 11B.2PCh. 11 - Prob. 11B.3PCh. 11 - Prob. 11B.4PCh. 11 - Prob. 11B.5PCh. 11 - Prob. 11B.6PCh. 11 - Prob. 11B.7PCh. 11 - Prob. 11B.8PCh. 11 - Prob. 11B.9PCh. 11 - Prob. 11B.10PCh. 11 - Prob. 11B.11PCh. 11 - Prob. 11B.12PCh. 11 - Prob. 11B.13PCh. 11 - Prob. 11B.14PCh. 11 - Prob. 11C.1DQCh. 11 - Prob. 11C.2DQCh. 11 - Prob. 11C.3DQCh. 11 - Prob. 11C.4DQCh. 11 - Prob. 11C.1AECh. 11 - Prob. 11C.1BECh. 11 - Prob. 11C.2AECh. 11 - Prob. 11C.2BECh. 11 - Prob. 11C.3AECh. 11 - Prob. 11C.3BECh. 11 - Prob. 11C.4AECh. 11 - Prob. 11C.4BECh. 11 - Prob. 11C.5AECh. 11 - Prob. 11C.5BECh. 11 - Prob. 11C.6AECh. 11 - Prob. 11C.6BECh. 11 - Prob. 11C.7AECh. 11 - Prob. 11C.7BECh. 11 - Prob. 11C.8AECh. 11 - Prob. 11C.8BECh. 11 - Prob. 11C.2PCh. 11 - Prob. 11C.3PCh. 11 - Prob. 11C.4PCh. 11 - Prob. 11C.5PCh. 11 - Prob. 11C.6PCh. 11 - Prob. 11C.7PCh. 11 - Prob. 11C.8PCh. 11 - Prob. 11C.9PCh. 11 - Prob. 11C.10PCh. 11 - Prob. 11C.11PCh. 11 - Prob. 11C.12PCh. 11 - Prob. 11C.13PCh. 11 - Prob. 11C.15PCh. 11 - Prob. 11C.17PCh. 11 - Prob. 11C.18PCh. 11 - Prob. 11C.19PCh. 11 - Prob. 11D.1DQCh. 11 - Prob. 11D.2DQCh. 11 - Prob. 11D.3DQCh. 11 - Prob. 11D.1AECh. 11 - Prob. 11D.1BECh. 11 - Prob. 11D.2AECh. 11 - Prob. 11D.2BECh. 11 - Prob. 11D.3AECh. 11 - Prob. 11D.3BECh. 11 - Prob. 11D.4AECh. 11 - Prob. 11D.4BECh. 11 - Prob. 11D.5AECh. 11 - Prob. 11D.5BECh. 11 - Prob. 11D.6AECh. 11 - Prob. 11D.6BECh. 11 - Prob. 11D.7AECh. 11 - Prob. 11D.7BECh. 11 - Prob. 11D.2PCh. 11 - Prob. 11E.1DQCh. 11 - Prob. 11E.1AECh. 11 - Prob. 11E.1BECh. 11 - Prob. 11E.2AECh. 11 - Prob. 11E.2BECh. 11 - Prob. 11E.3AECh. 11 - Prob. 11E.3BECh. 11 - Prob. 11E.1PCh. 11 - Prob. 11E.2PCh. 11 - Prob. 11F.1DQCh. 11 - Prob. 11F.2DQCh. 11 - Prob. 11F.3DQCh. 11 - Prob. 11F.4DQCh. 11 - Prob. 11F.5DQCh. 11 - Prob. 11F.6DQCh. 11 - Prob. 11F.1AECh. 11 - Prob. 11F.1BECh. 11 - Prob. 11F.2AECh. 11 - Prob. 11F.2BECh. 11 - Prob. 11F.3AECh. 11 - Prob. 11F.3BECh. 11 - Prob. 11F.4AECh. 11 - Prob. 11F.4BECh. 11 - Prob. 11F.5AECh. 11 - Prob. 11F.5BECh. 11 - Prob. 11F.6AECh. 11 - Prob. 11F.6BECh. 11 - Prob. 11F.7AECh. 11 - Prob. 11F.7BECh. 11 - Prob. 11F.8AECh. 11 - Prob. 11F.8BECh. 11 - Prob. 11F.9AECh. 11 - Prob. 11F.9BECh. 11 - Prob. 11F.10AECh. 11 - Prob. 11F.10BECh. 11 - Prob. 11F.11AECh. 11 - Prob. 11F.11BECh. 11 - Prob. 11F.12AECh. 11 - Prob. 11F.12BECh. 11 - Prob. 11F.13AECh. 11 - Prob. 11F.13BECh. 11 - Prob. 11F.1PCh. 11 - Prob. 11F.2PCh. 11 - Prob. 11F.3PCh. 11 - Prob. 11F.4PCh. 11 - Prob. 11F.5PCh. 11 - Prob. 11F.6PCh. 11 - Prob. 11F.7PCh. 11 - Prob. 11F.8PCh. 11 - Prob. 11F.9PCh. 11 - Prob. 11F.10PCh. 11 - Prob. 11F.11PCh. 11 - Prob. 11F.12PCh. 11 - Prob. 11G.1DQCh. 11 - Prob. 11G.2DQCh. 11 - Prob. 11G.3DQCh. 11 - Prob. 11G.4DQCh. 11 - Prob. 11G.5DQCh. 11 - Prob. 11G.1AECh. 11 - Prob. 11G.1BECh. 11 - Prob. 11G.2AECh. 11 - Prob. 11G.2BECh. 11 - Prob. 11G.1PCh. 11 - Prob. 11G.2PCh. 11 - Prob. 11G.3PCh. 11 - Prob. 11G.4PCh. 11 - Prob. 11G.5PCh. 11 - Prob. 11G.6PCh. 11 - Prob. 11.1IACh. 11 - Prob. 11.5IACh. 11 - Prob. 11.8IA
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