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Concept explainers
(a)
Interpretation:
Rotational constants for
Concept Introduction:
Rotational constant B can be calculated using the following formula.
Where,
The total moment of inertia can be calculated by following equation.
Where,
(a)
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Answer to Problem 11B.5E
The rotational constant A and B are
Explanation of Solution
The
Since mass of all oxygen atoms and their distance from the sulfur atom is same, moment of inertia can be written as follows,
Given,
Let the rotational constant corresponds to
Given,
Since mass of all oxygen atoms and their distance from the sulfur atom is same, moment of inertia can be written as follows,
Given,
Let the rotational constant corresponds to
Given,
The rotational constant A and B are
(b)
Interpretation:
The use of microwave spectroscopy for distinguishing the relative abundance of
Concept Introduction:
Rotational constant B can be calculated using the following formula.
Where,
The total moment of inertia can be calculated by following equation.
Where,
(b)
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Explanation of Solution
Microwave spectroscopy cannot be used to distinguish the relative abundance of
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Chapter 11 Solutions
Elements Of Physical Chemistry
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