CHEMISTRY W/WRKBK AND SMARTWORK (LL)
5th Edition
ISBN: 9780393693447
Author: Gilbert
Publisher: NORTON
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Chapter 11, Problem 11.96AP
Interpretation Introduction
Interpretation: The reason corresponding to the fact that the boiling point of pure sodium chloride is much higher than the boiling point of an aqueous solution of sodium chloride is to be stated.
Concept introduction: The addition of a substance (solute) in a solvent is known as dissolution. After the process of dissolution the boiling point of solvent increases and the freezing point decreases. The boiling point of the given solution is calculated by the elevation of boiling point for the given amount of solvent.
To determine: The reason corresponding to the fact that the boiling point of pure sodium chloride is much higher than the boiling point of an aqueous solution of sodium chloride.
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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z)
is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra
are provided. Draw the structure of the product as the resonance contributor lacking any formal charges.
13C NMR
DEPT 90
200
160
120
80
40
0
200
160
120
80
40
0
DEPT 135
T
200
160
120
80
40
0
Draw the unknown amide.
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Chapter 11 Solutions
CHEMISTRY W/WRKBK AND SMARTWORK (LL)
Ch. 11.1 - Prob. 1PECh. 11.2 - Prob. 2PECh. 11.2 - Prob. 3PECh. 11.2 - Prob. 4PECh. 11.3 - Prob. 5PECh. 11.4 - Prob. 6PECh. 11.4 - Prob. 7PECh. 11.5 - Prob. 8PECh. 11.5 - Prob. 9PECh. 11.5 - Prob. 10PE
Ch. 11.5 - Prob. 11PECh. 11.5 - Prob. 12PECh. 11.5 - Prob. 13PECh. 11.5 - Prob. 14PECh. 11.5 - Prob. 15PECh. 11.6 - Prob. 16PECh. 11.6 - Prob. 17PECh. 11 - Prob. 11.1VPCh. 11 - Prob. 11.2VPCh. 11 - Prob. 11.3VPCh. 11 - Prob. 11.4VPCh. 11 - Prob. 11.5VPCh. 11 - Prob. 11.6VPCh. 11 - Prob. 11.7VPCh. 11 - Prob. 11.8QPCh. 11 - Prob. 11.9QPCh. 11 - Prob. 11.10QPCh. 11 - Prob. 11.11QPCh. 11 - Prob. 11.12QPCh. 11 - Prob. 11.13QPCh. 11 - Prob. 11.14QPCh. 11 - Prob. 11.15QPCh. 11 - Prob. 11.16QPCh. 11 - Prob. 11.17QPCh. 11 - Prob. 11.18QPCh. 11 - Prob. 11.19QPCh. 11 - Prob. 11.20QPCh. 11 - Prob. 11.21QPCh. 11 - Prob. 11.22QPCh. 11 - Prob. 11.23QPCh. 11 - Prob. 11.24QPCh. 11 - Prob. 11.25QPCh. 11 - Prob. 11.26QPCh. 11 - Prob. 11.27QPCh. 11 - Prob. 11.28QPCh. 11 - Prob. 11.29QPCh. 11 - Prob. 11.30QPCh. 11 - Prob. 11.31QPCh. 11 - Prob. 11.32QPCh. 11 - Prob. 11.33QPCh. 11 - Prob. 11.34QPCh. 11 - Prob. 11.35QPCh. 11 - Prob. 11.36QPCh. 11 - Prob. 11.37QPCh. 11 - Prob. 11.38QPCh. 11 - Prob. 11.39QPCh. 11 - Prob. 11.40QPCh. 11 - Prob. 11.41QPCh. 11 - Prob. 11.42QPCh. 11 - Prob. 11.43QPCh. 11 - Prob. 11.44QPCh. 11 - Prob. 11.45QPCh. 11 - Prob. 11.46QPCh. 11 - Prob. 11.47QPCh. 11 - Prob. 11.48QPCh. 11 - Prob. 11.49QPCh. 11 - Prob. 11.50QPCh. 11 - Prob. 11.51QPCh. 11 - Prob. 11.52QPCh. 11 - Prob. 11.53QPCh. 11 - Prob. 11.54QPCh. 11 - Prob. 11.55QPCh. 11 - Prob. 11.56QPCh. 11 - Prob. 11.57QPCh. 11 - Prob. 11.58QPCh. 11 - Prob. 11.59QPCh. 11 - Prob. 11.60QPCh. 11 - Prob. 11.61QPCh. 11 - Prob. 11.62QPCh. 11 - Prob. 11.63QPCh. 11 - Prob. 11.64QPCh. 11 - Prob. 11.65QPCh. 11 - Prob. 11.66QPCh. 11 - Prob. 11.67QPCh. 11 - Prob. 11.68QPCh. 11 - Prob. 11.69QPCh. 11 - Prob. 11.70QPCh. 11 - Prob. 11.71QPCh. 11 - Prob. 11.72QPCh. 11 - Prob. 11.73QPCh. 11 - Prob. 11.74QPCh. 11 - Prob. 11.75QPCh. 11 - Prob. 11.76QPCh. 11 - Prob. 11.77QPCh. 11 - Prob. 11.78QPCh. 11 - Prob. 11.79QPCh. 11 - Prob. 11.80QPCh. 11 - Prob. 11.81QPCh. 11 - Prob. 11.82QPCh. 11 - Prob. 11.83QPCh. 11 - Prob. 11.84QPCh. 11 - Prob. 11.85QPCh. 11 - Prob. 11.86QPCh. 11 - Prob. 11.87QPCh. 11 - Prob. 11.88QPCh. 11 - Prob. 11.89QPCh. 11 - Prob. 11.90QPCh. 11 - Prob. 11.91QPCh. 11 - Prob. 11.92QPCh. 11 - Prob. 11.93QPCh. 11 - Prob. 11.94QPCh. 11 - Prob. 11.95APCh. 11 - Prob. 11.96APCh. 11 - Prob. 11.97APCh. 11 - Prob. 11.98APCh. 11 - Prob. 11.99APCh. 11 - Prob. 11.100APCh. 11 - Prob. 11.101APCh. 11 - Prob. 11.102APCh. 11 - Prob. 11.103APCh. 11 - Prob. 11.104APCh. 11 - Prob. 11.105APCh. 11 - Prob. 11.106AP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY