EBK ORGANIC AND BIOLOGICAL CHEMISTRY
7th Edition
ISBN: 9780100547742
Author: STOKER
Publisher: YUZU
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Chapter 11, Problem 11.94EP
Interpretation Introduction
Interpretation: The difference between snRNA and snRNPs has to be predicted.
Concept introduction: snRNA represents the small nuclear RNA molecule. snRNPs form spliceosomes to remove the introns from genes.
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Given the reaction R+ Q → P, indicate
(A). the rate law with respect to P:
(B). the rate law with respect to R:
(C). the rate law with respect to Q:
d[P]
dt
d[R]
dt
d[Q]
dt
The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)?
b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Chapter 11 Solutions
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
Ch. 11.1 - Which of the following statements concerning...Ch. 11.1 - Which of the following statements concerning...Ch. 11.2 - Any given nucleotide in a nucleic acid contains a....Ch. 11.2 - How many different sugars and how many different...Ch. 11.2 - How many different heterocyclic bases that are...Ch. 11.3 - Which of the following is present in nucleotides...Ch. 11.3 - Prob. 2QQCh. 11.3 - Prob. 3QQCh. 11.3 - Prob. 4QQCh. 11.4 - Prob. 1QQ
Ch. 11.4 - Prob. 2QQCh. 11.4 - Prob. 3QQCh. 11.4 - In a segment of a nucleic acid a terminal...Ch. 11.4 - Prob. 5QQCh. 11.5 - Which of the following statements concerning a DNA...Ch. 11.5 - Prob. 2QQCh. 11.5 - Prob. 3QQCh. 11.5 - Prob. 4QQCh. 11.6 - Prob. 1QQCh. 11.6 - In DNA replication the DNA double helix unwinds...Ch. 11.6 - Prob. 3QQCh. 11.6 - Prob. 4QQCh. 11.6 - Prob. 5QQCh. 11.7 - Prob. 1QQCh. 11.7 - The product of the first phase of protein...Ch. 11.8 - Prob. 1QQCh. 11.8 - Prob. 2QQCh. 11.8 - Prob. 3QQCh. 11.8 - Prob. 4QQCh. 11.9 - Which of the following statements concerning the...Ch. 11.9 - What is the complementary hnRNA base sequence...Ch. 11.9 - The location in a DNA strand carrying the...Ch. 11.9 - Prob. 4QQCh. 11.9 - Which of the following types of RNA is not part of...Ch. 11.10 - Prob. 1QQCh. 11.10 - The genetic code is a listing that gives...Ch. 11.10 - Prob. 3QQCh. 11.10 - Without reference to the genetic code, which of...Ch. 11.11 - Which of the following is an incorrect pairing of...Ch. 11.11 - Prob. 2QQCh. 11.11 - A tRNA molecule with the anticodon 5 AAG 3 will...Ch. 11.12 - Which of the following statements about ribosomes...Ch. 11.12 - Prob. 2QQCh. 11.12 - Prob. 3QQCh. 11.12 - Prob. 4QQCh. 11.12 - Prob. 5QQCh. 11.13 - Which of the following describes the effect of a...Ch. 11.13 - Prob. 2QQCh. 11.13 - Which of the following statements applies to both...Ch. 11.14 - Prob. 1QQCh. 11.14 - Prob. 2QQCh. 11.15 - Prob. 1QQCh. 11.15 - Prob. 2QQCh. 11.15 - The role of E. coli plasmids in obtaining rDNA is...Ch. 11.15 - Prob. 4QQCh. 11.15 - Prob. 5QQCh. 11.16 - Prob. 1QQCh. 11.16 - Prob. 2QQCh. 11 - Indicate whether each of the following statements...Ch. 11 - Indicate whether each of the following statements...Ch. 11 - Indicate whether each of the following pentoses is...Ch. 11 - Indicate whether each of the pentoses in Problem...Ch. 11 - With the help of Figure 22-2, identify each of the...Ch. 11 - With the help of Figure 22-2, identify each of the...Ch. 11 - With the help of Figure 22-2, what is the...Ch. 11 - With the help of Figure 22-2, what is the...Ch. 11 - With the help of Figure 22-2, indicate whether...Ch. 11 - With the help of Figure 22-2, indicate whether...Ch. 11 - Prob. 11.11EPCh. 11 - How many different choices are there for each of...Ch. 11 - Indicate whether each of the following statements...Ch. 11 - Prob. 11.14EPCh. 11 - What is the name of the nucleoside that contains...Ch. 11 - What is the name of the nucleoside that contains...Ch. 11 - Indicate whether each of the following statements...Ch. 11 - Indicate whether each of the following statements...Ch. 11 - Indicate whether each of the following is a DNA...Ch. 11 - Indicate whether each of the following is a DNA...Ch. 11 - Prob. 11.21EPCh. 11 - Prob. 11.22EPCh. 11 - What nitrogen-containing base and what sugar are...Ch. 11 - What nitrogen-containing base and what sugar are...Ch. 11 - Prob. 11.25EPCh. 11 - Prob. 11.26EPCh. 11 - Consider the following nucleotide. a. What is the...Ch. 11 - Consider the following nucleotide. a. What is the...Ch. 11 - Prob. 11.29EPCh. 11 - Prob. 11.30EPCh. 11 - For the trinucleotide 5 GCA 3 a. How many...Ch. 11 - For the trinucleotide 5 UCG 3 a. How many...Ch. 11 - Is the trinucleotide in Problem 22-31 found only...Ch. 11 - Is the trinucleotide in Problem 22-32 found only...Ch. 11 - In the lengthening of a polynucleotide chain,...Ch. 11 - Prob. 11.36EPCh. 11 - Draw the structure of the RNA dinucleotide 5 UG 3.Ch. 11 - Draw the structure of the DNA dinucleotide 5 TA 3.Ch. 11 - For the trinucleotide 5 T-G-A 3 a. How many...Ch. 11 - For the trinucleotide 5 U-C-G 3 a. How many...Ch. 11 - Prob. 11.41EPCh. 11 - Prob. 11.42EPCh. 11 - Prob. 11.43EPCh. 11 - Prob. 11.44EPCh. 11 - The base content of a particular DNA molecule is...Ch. 11 - The base content of a particular DNA molecule is...Ch. 11 - What structural consideration prevents the bases A...Ch. 11 - What structural consideration prevents the bases C...Ch. 11 - The base composition for one of the strands of a...Ch. 11 - The base composition for one of the strands of a...Ch. 11 - Convert each of the following 3-to-5 DNA base...Ch. 11 - Convert each of the following 3-to-5 DNA base...Ch. 11 - Using the concept of complementary base pairing,...Ch. 11 - Using the concept of complementary base pairing,...Ch. 11 - For the DNA segment 5 TTGCAC 3 how many of each of...Ch. 11 - For the DNA segment 5 TAGATG 3 how many of each of...Ch. 11 - What is the base sequence, specified in the 5-to-3...Ch. 11 - What is the base sequence, specified in the 5-to-3...Ch. 11 - In the replication of a DNA molecule, two daughter...Ch. 11 - In the replication of a DNA molecule, two daughter...Ch. 11 - How does the synthesis of a daughter DNA strand...Ch. 11 - In the context of DNA replication, what is the...Ch. 11 - Prob. 11.63EPCh. 11 - Prob. 11.64EPCh. 11 - Prob. 11.65EPCh. 11 - Prob. 11.66EPCh. 11 - Prob. 11.67EPCh. 11 - Prob. 11.68EPCh. 11 - Indicate whether each of the following statements...Ch. 11 - Prob. 11.70EPCh. 11 - Indicate whether each of the following statements...Ch. 11 - Prob. 11.72EPCh. 11 - Prob. 11.73EPCh. 11 - Prob. 11.74EPCh. 11 - Indicate whether the predominant cellular location...Ch. 11 - Indicate whether the predominant cellular location...Ch. 11 - Indicate whether each of the following situations...Ch. 11 - Indicate whether each of the following processes...Ch. 11 - Indicate whether each of the following statements...Ch. 11 - Indicate whether each of the following statements...Ch. 11 - Prob. 11.81EPCh. 11 - What is the base sequence, given in the 5-to-3...Ch. 11 - For each of the following DNA template strands,...Ch. 11 - For each of the following DNA template strands,...Ch. 11 - Prob. 11.85EPCh. 11 - Prob. 11.86EPCh. 11 - Prob. 11.87EPCh. 11 - Prob. 11.88EPCh. 11 - What mRNA base sequence, specified in the 5-to-3...Ch. 11 - Prob. 11.90EPCh. 11 - Prob. 11.91EPCh. 11 - What mRNA base sequence, specified in the 5-to-3...Ch. 11 - Prob. 11.93EPCh. 11 - Prob. 11.94EPCh. 11 - Prob. 11.95EPCh. 11 - Prob. 11.96EPCh. 11 - Prob. 11.97EPCh. 11 - Prob. 11.98EPCh. 11 - Prob. 11.99EPCh. 11 - Prob. 11.100EPCh. 11 - Prob. 11.101EPCh. 11 - Using the information in Table 22-2, determine...Ch. 11 - Using the information in Table 22-2, determine the...Ch. 11 - Prob. 11.104EPCh. 11 - Explain why the base sequence ATC could not be a...Ch. 11 - Explain why the base sequence AGAC could not be a...Ch. 11 - Prob. 11.107EPCh. 11 - Predict the sequence of amino acids coded by the...Ch. 11 - Prob. 11.109EPCh. 11 - Prob. 11.110EPCh. 11 - Determine each of the following items using the...Ch. 11 - Prob. 11.112EPCh. 11 - Prob. 11.113EPCh. 11 - Prob. 11.114EPCh. 11 - Prob. 11.115EPCh. 11 - Prob. 11.116EPCh. 11 - Prob. 11.117EPCh. 11 - Prob. 11.118EPCh. 11 - Which amino acid will a tRNA molecule be carrying...Ch. 11 - Prob. 11.120EPCh. 11 - Prob. 11.121EPCh. 11 - Identify the amino acid associated with each of...Ch. 11 - Prob. 11.123EPCh. 11 - Prob. 11.124EPCh. 11 - Indicate whether each of the following statements...Ch. 11 - Prob. 11.126EPCh. 11 - Prob. 11.127EPCh. 11 - Prob. 11.128EPCh. 11 - Prob. 11.129EPCh. 11 - Prob. 11.130EPCh. 11 - Prob. 11.131EPCh. 11 - Prob. 11.132EPCh. 11 - Which of these RNA types(1) mRNA, (2) hnRNA, (3)...Ch. 11 - Prob. 11.134EPCh. 11 - Consider the following mRNA base sequence 5CUUCAG3...Ch. 11 - Consider the following mRNA base sequence 5ACCCAC3...Ch. 11 - Consider the following DNA base sequence 3TTAATA5...Ch. 11 - Prob. 11.138EPCh. 11 - The DNA template strand segment 3TTCAAACCGTAC5...Ch. 11 - The DNA template strand segment 3TTCAAACCGTAC5...Ch. 11 - Prob. 11.141EPCh. 11 - Prob. 11.142EPCh. 11 - Prob. 11.143EPCh. 11 - Prob. 11.144EPCh. 11 - Prob. 11.145EPCh. 11 - Prob. 11.146EPCh. 11 - Prob. 11.147EPCh. 11 - Prob. 11.148EPCh. 11 - Prob. 11.149EPCh. 11 - Prob. 11.150EPCh. 11 - Prob. 11.151EPCh. 11 - Which of the following processes(1) transcription...Ch. 11 - Prob. 11.153EPCh. 11 - Prob. 11.154EP
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