Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 11, Problem 11.64QP
Write the van der Waals equation for a real gas. Explain the corrective terms for pressure and volume.
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
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50
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30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 11 Solutions
Chemistry: Atoms First
Ch. 11.2 - Prob. 11.1WECh. 11.2 - Prob. 1PPACh. 11.2 - Prob. 1PPBCh. 11.2 - Prob. 1PPCCh. 11.2 - Prob. 11.2.1SRCh. 11.2 - Prob. 11.2.2SRCh. 11.3 - Prob. 11.2WECh. 11.3 - Prob. 2PPACh. 11.3 - Prob. 2PPBCh. 11.3 - Arrange the four columns of liquid [(i)(iv)] in...
Ch. 11.3 - Prob. 11.3.1SRCh. 11.3 - Which of the following is true? (Select all that...Ch. 11.3 - Prob. 11.3.3SRCh. 11.3 - Prob. 11.3.4SRCh. 11.3 - Prob. 11.3.5SRCh. 11.4 - Prob. 11.3WECh. 11.4 - Prob. 3PPACh. 11.4 - Prob. 3PPBCh. 11.4 - Prob. 3PPCCh. 11.4 - Prob. 11.4WECh. 11.4 - Prob. 4PPACh. 11.4 - Prob. 4PPBCh. 11.4 - Prob. 4PPCCh. 11.4 - If we combine 3.0 L of NO and 1.5 L of O2, and...Ch. 11.4 - What volume (in liters) of water vapor will be...Ch. 11.4 - Prob. 5PPBCh. 11.4 - Prob. 5PPCCh. 11.4 - Prob. 11.6WECh. 11.4 - Prob. 6PPACh. 11.4 - Prob. 6PPBCh. 11.4 - Prob. 6PPCCh. 11.4 - Prob. 11.4.1SRCh. 11.4 - Prob. 11.4.2SRCh. 11.4 - Prob. 11.4.3SRCh. 11.4 - Prob. 11.4.4SRCh. 11.4 - Prob. 11.4.5SRCh. 11.4 - Prob. 11.4.6SRCh. 11.5 - Prob. 11.7WECh. 11.5 - Prob. 7PPACh. 11.5 - Prob. 7PPBCh. 11.5 - Prob. 7PPCCh. 11.5 - Prob. 11.8WECh. 11.5 - Prob. 8PPACh. 11.5 - Prob. 8PPBCh. 11.5 - Prob. 8PPCCh. 11.5 - Prob. 11.9WECh. 11.5 - Prob. 9PPACh. 11.5 - Prob. 9PPBCh. 11.5 - Prob. 9PPCCh. 11.5 - Prob. 11.5.1SRCh. 11.5 - Prob. 11.5.2SRCh. 11.5 - Determine the density of a gas with m = 146.07...Ch. 11.5 - Prob. 11.5.4SRCh. 11.6 - Prob. 11.10WECh. 11.6 - Prob. 10PPACh. 11.6 - Prob. 10PPBCh. 11.6 - Prob. 10PPCCh. 11.6 - Prob. 11.11WECh. 11.6 - Determine the excluded volume per mole and the...Ch. 11.6 - Prob. 11PPBCh. 11.6 - Prob. 11PPCCh. 11.6 - Prob. 11.6.1SRCh. 11.6 - Prob. 11.6.2SRCh. 11.7 - Prob. 11.12WECh. 11.7 - Prob. 12PPACh. 11.7 - Prob. 12PPBCh. 11.7 - Prob. 12PPCCh. 11.7 - Prob. 11.13WECh. 11.7 - Prob. 13PPACh. 11.7 - Prob. 13PPBCh. 11.7 - Prob. 13PPCCh. 11.7 - What is the partial pressure of He in a 5.00-L...Ch. 11.7 - Prob. 11.7.2SRCh. 11.7 - Prob. 11.7.3SRCh. 11.7 - Prob. 11.7.4SRCh. 11.7 - Prob. 11.7.5SRCh. 11.8 - Prob. 11.14WECh. 11.8 - Prob. 14PPACh. 11.8 - Prob. 14PPBCh. 11.8 - Prob. 14PPCCh. 11.8 - Prob. 11.15WECh. 11.8 - Prob. 15PPACh. 11.8 - Prob. 15PPBCh. 11.8 - Prob. 15PPCCh. 11.8 - Calcium metal reacts with water to produce...Ch. 11.8 - Prob. 16PPACh. 11.8 - Determine the volume of gas collected over water...Ch. 11.8 - Prob. 16PPCCh. 11.8 - Determine the volume of Cl2 gas at STP that will...Ch. 11.8 - Determine the mass of NaN3 required for an air bag...Ch. 11.8 - What mass of acetylene (C2H2) is produced by the...Ch. 11 - Determine the mole fraction of helium in a gaseous...Ch. 11 - Prob. 11.2KSPCh. 11 - Prob. 11.3KSPCh. 11 - Prob. 11.4KSPCh. 11 - Prob. 11.1QPCh. 11 - Prob. 11.2QPCh. 11 - Prob. 11.3QPCh. 11 - Prob. 11.4QPCh. 11 - Prob. 11.5QPCh. 11 - Prob. 11.6QPCh. 11 - Prob. 11.7QPCh. 11 - Prob. 11.8QPCh. 11 - Prob. 11.9QPCh. 11 - Prob. 11.10QPCh. 11 - Prob. 11.11QPCh. 11 - The 235U isotope undergoes fission when bombarded...Ch. 11 - Prob. 11.13QPCh. 11 - Prob. 11.14QPCh. 11 - Prob. 11.15QPCh. 11 - Prob. 11.16QPCh. 11 - Prob. 11.17QPCh. 11 - Prob. 11.18QPCh. 11 - Prob. 11.19QPCh. 11 - Prob. 11.20QPCh. 11 - Prob. 11.21QPCh. 11 - Prob. 11.22QPCh. 11 - Prob. 11.23QPCh. 11 - Calculate the height of a column of isopropanol...Ch. 11 - Prob. 11.25QPCh. 11 - Prob. 11.26QPCh. 11 - Prob. 11.27QPCh. 11 - Prob. 11.28QPCh. 11 - Prob. 11.29QPCh. 11 - Prob. 11.30QPCh. 11 - Prob. 11.31QPCh. 11 - A sample of air occupies 3.8 L when the pressure...Ch. 11 - Prob. 11.33QPCh. 11 - Prob. 11.34QPCh. 11 - Prob. 11.35QPCh. 11 - Prob. 11.36QPCh. 11 - Prob. 11.37QPCh. 11 - Prob. 11.38QPCh. 11 - A gaseous sample of a substance is cooled at...Ch. 11 - Prob. 11.40QPCh. 11 - Prob. 11.41QPCh. 11 - Prob. 11.42QPCh. 11 - Prob. 11.43QPCh. 11 - Prob. 11.44QPCh. 11 - Prob. 11.45QPCh. 11 - Prob. 11.46QPCh. 11 - Prob. 11.47QPCh. 11 - Prob. 11.48QPCh. 11 - Prob. 11.49QPCh. 11 - Prob. 11.50QPCh. 11 - Prob. 11.51QPCh. 11 - Prob. 11.52QPCh. 11 - Prob. 11.53QPCh. 11 - Prob. 11.54QPCh. 11 - Prob. 11.55QPCh. 11 - Prob. 11.56QPCh. 11 - Prob. 11.57QPCh. 11 - A certain anesthetic contains 64.9 percent C, 13.5...Ch. 11 - A compound has the empirical formula SF4. At 20C,...Ch. 11 - Prob. 11.60QPCh. 11 - Prob. 11.61QPCh. 11 - Prob. 11.62QPCh. 11 - Prob. 11.63QPCh. 11 - Write the van der Waals equation for a real gas....Ch. 11 - Prob. 11.65QPCh. 11 - Prob. 11.66QPCh. 11 - Prob. 11.67QPCh. 11 - Prob. 11.68QPCh. 11 - Prob. 11.69QPCh. 11 - Prob. 11.70QPCh. 11 - Prob. 11.71QPCh. 11 - Prob. 11.72QPCh. 11 - Prob. 11.73QPCh. 11 - Prob. 11.74QPCh. 11 - Prob. 11.75QPCh. 11 - Prob. 11.76QPCh. 11 - Prob. 11.77QPCh. 11 - Prob. 11.78QPCh. 11 - Prob. 11.79QPCh. 11 - Prob. 11.1VCCh. 11 - Prob. 11.2VCCh. 11 - Prob. 11.3VCCh. 11 - Prob. 11.4VCCh. 11 - Prob. 11.80QPCh. 11 - Prob. 11.81QPCh. 11 - Prob. 11.82QPCh. 11 - Prob. 11.83QPCh. 11 - Prob. 11.84QPCh. 11 - Prob. 11.85QPCh. 11 - Prob. 11.86QPCh. 11 - Prob. 11.87QPCh. 11 - Prob. 11.88QPCh. 11 - Ethanol (C2H5OH) bums in air: C2H5OH(l) + O2(g) ...Ch. 11 - Prob. 11.90QPCh. 11 - Prob. 11.91QPCh. 11 - Prob. 11.92QPCh. 11 - Prob. 11.93QPCh. 11 - Prob. 11.94QPCh. 11 - Prob. 11.95QPCh. 11 - Prob. 11.96QPCh. 11 - Prob. 11.97QPCh. 11 - Prob. 11.98QPCh. 11 - Prob. 11.99QPCh. 11 - Prob. 11.100QPCh. 11 - Prob. 11.101QPCh. 11 - Prob. 11.102QPCh. 11 - Prob. 11.103QPCh. 11 - Prob. 11.104QPCh. 11 - Prob. 11.105QPCh. 11 - Prob. 11.106QPCh. 11 - Prob. 11.107QPCh. 11 - Prob. 11.108QPCh. 11 - Prob. 11.109QPCh. 11 - A 180.0-mg sample of an alloy of iron and metal X...Ch. 11 - Prob. 11.111QPCh. 11 - Prob. 11.112QPCh. 11 - Prob. 11.113QPCh. 11 - Prob. 11.114QPCh. 11 - Prob. 11.115QPCh. 11 - Prob. 11.116QPCh. 11 - Prob. 11.117QPCh. 11 - Prob. 11.118QPCh. 11 - Prob. 11.119QPCh. 11 - Prob. 11.120QPCh. 11 - Prob. 11.121QPCh. 11 - Prob. 11.122QPCh. 11 - Prob. 11.123QPCh. 11 - Prob. 11.124QPCh. 11 - Prob. 11.125QPCh. 11 - Acidic oxides such as carbon dioxide react with...Ch. 11 - Prob. 11.127QPCh. 11 - Prob. 11.128QPCh. 11 - Prob. 11.129QPCh. 11 - Prob. 11.130QPCh. 11 - Prob. 11.131QPCh. 11 - Prob. 11.132QPCh. 11 - Prob. 11.133QPCh. 11 - Prob. 11.134QPCh. 11 - Prob. 11.135QPCh. 11 - Prob. 11.136QPCh. 11 - Prob. 11.137QPCh. 11 - Prob. 11.138QPCh. 11 - Prob. 11.139QPCh. 11 - Prob. 11.140QPCh. 11 - Prob. 11.141QPCh. 11 - At what temperature will He atoms have the same...Ch. 11 - Prob. 11.143QPCh. 11 - Prob. 11.144QPCh. 11 - Prob. 11.145QPCh. 11 - Prob. 11.146QPCh. 11 - Prob. 11.147QPCh. 11 - Prob. 11.148QPCh. 11 - Prob. 11.149QPCh. 11 - Prob. 11.150QPCh. 11 - Prob. 11.151QPCh. 11 - A 5.00-mole sample of NH3 gas is kept in a 1.92-L...Ch. 11 - Prob. 11.153QPCh. 11 - Prob. 11.154QPCh. 11 - Prob. 11.155QPCh. 11 - Prob. 11.156QPCh. 11 - Prob. 11.157QPCh. 11 - Prob. 11.158QPCh. 11 - Prob. 11.159QPCh. 11 - Prob. 11.160QPCh. 11 - Prob. 11.161QP
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