Chemistry (7th Edition)
7th Edition
ISBN: 9780321943170
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 11, Problem 11.48SP
Interpretation Introduction
To determine:
To find the vapour pressure of carbon disuliphide
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30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in
class, but the partition function that describes the translational and rotational motion of a homonuclear
diatomic molecule is given by
Itrans (V,T) =
=
2πmkBT
h²
V
grot (T)
4π²IKBT
h²
Where h is Planck's constant and I is molecular moment of inertia.
The overall partition function is qmolec Qtrans qrot.
Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational
modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a
volume of 1 m³. Here is some useful data:
Moment of inertia:
I2 I 7.46 x 10-
45
kg m²
2
O2 I 1.91 x 101
-46
kg m²
K
for each reaction step.
Be sure to account for all bond-breaking and bond-making
steps.
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Problem 30 of 20
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Draw the principal organic product of the following reaction.
Chapter 11 Solutions
Chemistry (7th Edition)
Ch. 11 - PRACTICE 11.1 The boiling point of ethanol is 78.4...Ch. 11 - APPLY 11.2 Chloroform CHCl3 has Hvap=29.2kJ/mol...Ch. 11 - Prob. 11.3PCh. 11 - APPLY 11.4 What is the sign and magnitude of q...Ch. 11 - Prob. 11.5PCh. 11 - Prob. 11.6ACh. 11 - Prob. 11.7PCh. 11 - Prob. 11.8ACh. 11 - Prob. 11.9PCh. 11 - Prob. 11.10A
Ch. 11 - PRACTICE 11.11 Polonium metal crystallizes in a...Ch. 11 - Prob. 11.12ACh. 11 - Prob. 11.13PCh. 11 - Prob. 11.14ACh. 11 - Conceptual PRACTICE 11.15 Look at the phase...Ch. 11 - Prob. 11.16ACh. 11 - Prob. 11.17PCh. 11 - Prob. 11.18PCh. 11 - Prob. 11.19PCh. 11 - Prob. 11.20PCh. 11 - Prob. 11.21PCh. 11 - Assume that you have a liquid in a cylinder...Ch. 11 - Identify each of the following kinds of packing:Ch. 11 - Prob. 11.24CPCh. 11 - Prob. 11.25CPCh. 11 - Prob. 11.26CPCh. 11 - Prob. 11.27CPCh. 11 - Prob. 11.28SPCh. 11 - Prob. 11.29SPCh. 11 - Prob. 11.30SPCh. 11 - Prob. 11.31SPCh. 11 - Prob. 11.32SPCh. 11 - Prob. 11.33SPCh. 11 - Prob. 11.34SPCh. 11 - Prob. 11.35SPCh. 11 - Prob. 11.36SPCh. 11 - Prob. 11.37SPCh. 11 - Prob. 11.38SPCh. 11 - Prob. 11.39SPCh. 11 - Prob. 11.40SPCh. 11 - Prob. 11.41SPCh. 11 - Prob. 11.42SPCh. 11 - Prob. 11.43SPCh. 11 - Prob. 11.44SPCh. 11 - Prob. 11.45SPCh. 11 - Prob. 11.46SPCh. 11 - Prob. 11.47SPCh. 11 - Prob. 11.48SPCh. 11 - Prob. 11.49SPCh. 11 - Prob. 11.50SPCh. 11 - Prob. 11.51SPCh. 11 - Prob. 11.52SPCh. 11 - Prob. 11.53SPCh. 11 - Prob. 11.54SPCh. 11 - Prob. 11.55SPCh. 11 - Prob. 11.56SPCh. 11 - Prob. 11.57SPCh. 11 - Prob. 11.58SPCh. 11 - Prob. 11.59SPCh. 11 - Prob. 11.60SPCh. 11 - Prob. 11.61SPCh. 11 - Prob. 11.62SPCh. 11 - Prob. 11.63SPCh. 11 - Prob. 11.64SPCh. 11 - Prob. 11.65SPCh. 11 - Prob. 11.66SPCh. 11 - Prob. 11.67SPCh. 11 - Copper crystallizes in a face-centered cubic unit...Ch. 11 - 11.69 Lead crystallizes in a face-centered cubic...Ch. 11 - Aluminum has a density of 2.699 g/cm3 and...Ch. 11 - Tungsten crystallizes in a body-centered cubic...Ch. 11 - Prob. 11.72SPCh. 11 - Prob. 11.73SPCh. 11 - Prob. 11.74SPCh. 11 - Prob. 11.75SPCh. 11 - Prob. 11.76SPCh. 11 - Prob. 11.77SPCh. 11 - Prob. 11.78SPCh. 11 - Prob. 11.79SPCh. 11 - Prob. 11.80SPCh. 11 - Prob. 11.81SPCh. 11 - Prob. 11.82SPCh. 11 - Prob. 11.83SPCh. 11 - Prob. 11.84SPCh. 11 - Prob. 11.85SPCh. 11 - Prob. 11.86SPCh. 11 - Prob. 11.87SPCh. 11 - Prob. 11.88SPCh. 11 - 11.89 Assume that you have samples of the...Ch. 11 - Prob. 11.90SPCh. 11 - Prob. 11.91SPCh. 11 - Prob. 11.92SPCh. 11 - Prob. 11.93SPCh. 11 - Prob. 11.94CPCh. 11 - Prob. 11.95CPCh. 11 - Prob. 11.96CPCh. 11 - Prob. 11.97CPCh. 11 - Prob. 11.98CPCh. 11 - Prob. 11.99CPCh. 11 - Prob. 11.100CPCh. 11 - Prob. 11.101CPCh. 11 - Prob. 11.102CPCh. 11 - Prob. 11.103CPCh. 11 - Prob. 11.104CPCh. 11 - Prob. 11.105CPCh. 11 - Prob. 11.106CPCh. 11 - Prob. 11.107CPCh. 11 - Prob. 11.108CPCh. 11 - Iron crystallizes in a body-centered cubic unit...Ch. 11 - Prob. 11.110CPCh. 11 - Prob. 11.111CPCh. 11 - Prob. 11.112CPCh. 11 - Prob. 11.113CPCh. 11 - Prob. 11.114CPCh. 11 - Prob. 11.115CPCh. 11 - Prob. 11.116MPCh. 11 - Prob. 11.117MPCh. 11 - Prob. 11.118MPCh. 11 - A group 3A metal has a density of 2.70 g/cm3 and a...Ch. 11 - Prob. 11.120MPCh. 11 - Prob. 11.121MP
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