EBK LABORATORY MANUAL FOR GENERAL, ORGA
3rd Edition
ISBN: 9780321918352
Author: Timberlake
Publisher: YUZU
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Chapter 11, Problem 11.48PP
How do nucleoside analogs disrupt the life cycle of the HIV-1 virus?
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
८८
2
"Br
{t༐B,gt)-bemn€-nehpརི་ཚ༐lnoa
Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 11 Solutions
EBK LABORATORY MANUAL FOR GENERAL, ORGA
Ch. 11 - Prob. 11.1PPCh. 11 - Prob. 11.2PPCh. 11 - Prob. 11.3PPCh. 11 - Prob. 11.4PPCh. 11 - Prob. 11.5PPCh. 11 - Which of the pentose sugars is found in DNA? Which...Ch. 11 - Prob. 11.7PPCh. 11 - Prob. 11.8PPCh. 11 - Prob. 11.9PPCh. 11 - Prob. 11.10PP
Ch. 11 - Prob. 11.11PPCh. 11 - Prob. 11.12PPCh. 11 - Draw the dinucleotide GC that would be found in...Ch. 11 - Prob. 11.14PPCh. 11 - Prob. 11.15PPCh. 11 - Prob. 11.16PPCh. 11 - Prob. 11.17PPCh. 11 - Prob. 11.18PPCh. 11 - Write the base sequence and label the 3 and 5 ends...Ch. 11 - Write the base sequence and label the 3 and 5 ends...Ch. 11 - Prob. 11.21PPCh. 11 - I jst the similarities and differences in the...Ch. 11 - Prob. 11.23PPCh. 11 - Prob. 11.24PPCh. 11 - Prob. 11.25PPCh. 11 - In your own words, define the term translation.Ch. 11 - Prob. 11.27PPCh. 11 - Prob. 11.28PPCh. 11 - Prob. 11.29PPCh. 11 - Prob. 11.30PPCh. 11 - Provide the three-letter amino-acid sequence...Ch. 11 - Provide the three-letter amino-acid sequence...Ch. 11 - Prob. 11.33PPCh. 11 - Prob. 11.34PPCh. 11 - The following portion of DNA is in the template...Ch. 11 - The following portion of DNA is in the template...Ch. 11 - Prob. 11.37PPCh. 11 - In your own words, define a silent mutation.Ch. 11 - Prob. 11.39PPCh. 11 - Consider the following portion of mRNA produced by...Ch. 11 - Prob. 11.41PPCh. 11 - Prob. 11.42PPCh. 11 - Why do viruses need to enter a host cell?Ch. 11 - Prob. 11.44PPCh. 11 - Prob. 11.45PPCh. 11 - It a virus contains viral RNA, a. name the first...Ch. 11 - Prob. 11.47PPCh. 11 - How do nucleoside analogs disrupt the life cycle...Ch. 11 - Prob. 11.49PPCh. 11 - Prob. 11.50PPCh. 11 - Prob. 11.51PPCh. 11 - Describe the structure of a plasmid.Ch. 11 - Prob. 11.53PPCh. 11 - Prob. 11.54PPCh. 11 - Prob. 11.55APCh. 11 - Prob. 11.56APCh. 11 - Prob. 11.57APCh. 11 - Prob. 11.58APCh. 11 - Prob. 11.59APCh. 11 - Prob. 11.60APCh. 11 - Prob. 11.61APCh. 11 - Write the complementary base sequence for each of...Ch. 11 - Prob. 11.63APCh. 11 - Prob. 11.64APCh. 11 - Prob. 11.65APCh. 11 - Prob. 11.66APCh. 11 - Prob. 11.67APCh. 11 - Prob. 11.68APCh. 11 - Prob. 11.69APCh. 11 - Prob. 11.70APCh. 11 - Prob. 11.71APCh. 11 - Endorphins arc polypeptides that reduce pain. What...Ch. 11 - What is the one-letter amino-acid sequence formed...Ch. 11 - Prob. 11.74APCh. 11 - What is the anticodon on tRNA for each of the...Ch. 11 - a. A base substitution changes a codon for an...Ch. 11 - Prob. 11.77APCh. 11 - Discuss whether or not each of the following is a...Ch. 11 - Prob. 11.79APCh. 11 - Prob. 11.80APCh. 11 - Prob. 11.81APCh. 11 - List two societal benefits to recombinant DNA...Ch. 11 - Prob. 11.83APCh. 11 - Oxytocin is a small peptide hormone involved in...Ch. 11 - Alpha-melanocyte stimulating hormone (o-MSH) is a...Ch. 11 - a. If the DNA chromosomes of salmon contain 28%...Ch. 11 - A protein aiumm 35 amino acids. How many...Ch. 11 - The DNA double helix can unwind or denature at...Ch. 11 - Prob. 1IA.1QCh. 11 - Prob. 1IA.2QCh. 11 - Prob. 1IA.3QCh. 11 - Prob. 1IA.4QCh. 11 - Prob. 1IA.5QCh. 11 - Prob. 1IA.6QCh. 11 - Prob. 1IA.7QCh. 11 - Prob. 1IA.8QCh. 11 - Prob. 1IA.9QCh. 11 - Prob. 2IA.1QCh. 11 - Prob. 2IA.2QCh. 11 - Prob. 2IA.3QCh. 11 - Prob. 3IA.1QCh. 11 - Prob. 3IA.2QCh. 11 - Prob. 3IA.3QCh. 11 - Prob. 3IA.4QCh. 11 - Prob. 3IA.5QCh. 11 - Prob. 3IA.6QCh. 11 - Prob. 3IA.7QCh. 11 - Prob. 3IA.8QCh. 11 - Prob. 3IA.9QCh. 11 - Prob. 3IA.10QCh. 11 - Prob. 1ICCh. 11 - Prob. 2ICCh. 11 - Prob. 3IC
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