CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
8th Edition
ISBN: 9780135204634
Author: Robinson
Publisher: PEARSON
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Textbook Question
Chapter 11, Problem 11.39SP
Why is the heat of sublimation,
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Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Could you redraw these and also explain how to solve them for me pleas
Chapter 11 Solutions
CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
Ch. 11 - Prob. 11.1PCh. 11 - The normal boiling point of water is 100.0 C, and...Ch. 11 - PRACTICE 11.1 The boiling point of ethanol is 78.4...Ch. 11 - APPLY 11.2 Chloroform CHCl3 has Hvap=29.2kJ/mol...Ch. 11 - How much heat is required to convert15.0 g of...Ch. 11 - APPLY 11.4 What is the sign and magnitude of q...Ch. 11 - Look at the phase diagram of H2O in Figure 11.7,...Ch. 11 - Prob. 11.8ACh. 11 - Why was a new solvent needed for extracting...Ch. 11 - A fire extinguisher containing carbon dioxide has...
Ch. 11 - Look at the phase diagram of CO2 in Figure11.13,...Ch. 11 - Liquid carbon dioxide is also used as non-toxic...Ch. 11 - For the phase transition CO2(s)CO2(g), predict the...Ch. 11 - A sample of supercritical carbon dioxide was...Ch. 11 - Assume that you have a liquid in a cylinder...Ch. 11 - The phase diagram of a substance is shown below....Ch. 11 - Prob. 11.17CPCh. 11 - Prob. 11.18CPCh. 11 - The following compound undergoes a phase...Ch. 11 - A magnetized needle gently placed on the surface...Ch. 11 - Water flows quickly through the narrow neck of a...Ch. 11 - Predict which substance in each pair has the...Ch. 11 - Prob. 11.23SPCh. 11 - The chemical structure for oleic acid, the primary...Ch. 11 - Prob. 11.25SPCh. 11 - Prob. 11.26SPCh. 11 - The vapor pressure of SiCI4 is 100 mm Hg at 5.4 C,...Ch. 11 - What is the vapor pressure of CS2 in mm Hg at 20.0...Ch. 11 - What is the vapor pressure of SiCI4 in mm Hg at...Ch. 11 - Dichloromethane, CH2CI2, is an organic solvent...Ch. 11 - Prob. 11.31SPCh. 11 - Use the plot you made in Problem 11.30 to find a...Ch. 11 - Prob. 11.33SPCh. 11 - Prob. 11.34SPCh. 11 - Prob. 11.35SPCh. 11 - Prob. 11.36SPCh. 11 - Acetone,acommon laboratorysolvent,has...Ch. 11 - Why is Hvap usually larger than Hfusion ?Ch. 11 - Why is the heat of sublimation, Hsubl, equal to...Ch. 11 - Naphthalene, better known as "mothballs," has bp =...Ch. 11 - Prob. 11.41SPCh. 11 - Prob. 11.42SPCh. 11 - Prob. 11.43SPCh. 11 - Prob. 11.44SPCh. 11 - Prob. 11.45SPCh. 11 - How much energy in kilojoules is needed to heat...Ch. 11 - Prob. 11.47SPCh. 11 - How much energy in kilojoules is released when...Ch. 11 - How much energy in kilojoules is released when...Ch. 11 - Prob. 11.50SPCh. 11 - Prob. 11.51SPCh. 11 - Prob. 11.52SPCh. 11 - Prob. 11.53SPCh. 11 - Prob. 11.54SPCh. 11 - Look at the phase diagram of H2O in Figure 11.7,...Ch. 11 - Prob. 11.56SPCh. 11 - Oxygen has Tt=54.3K,Pt=1.14mmHg,Tc=154.6K, and...Ch. 11 - Prob. 11.58SPCh. 11 - Prob. 11.59SPCh. 11 - Prob. 11.60SPCh. 11 - Prob. 11.61SPCh. 11 - Benzene has a melting point of 5.53 C and a...Ch. 11 - Prob. 11.63SPCh. 11 - How many phase transitions did you pass through in...Ch. 11 - Prob. 11.65SPCh. 11 - Prob. 11.66SPCh. 11 - Prob. 11.67SPCh. 11 - Prob. 11.68SPCh. 11 - Prob. 11.69SPCh. 11 - Prob. 11.70SPCh. 11 - Prob. 11.71SPCh. 11 - Prob. 11.72SPCh. 11 - Prob. 11.73SPCh. 11 - For each of the following substances, identify the...Ch. 11 - The chlorofluorocarbon refrigerant...Ch. 11 - Prob. 11.76MPCh. 11 - Prob. 11.77MP
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- In the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forwardNonearrow_forwardNonearrow_forward
- Nonearrow_forwardWhat spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.arrow_forwardQuestion 6 What is the major product of the following Diels-Alder reaction? ? Aldy by day of A. H о B. C. D. E. OB OD Oc OE OAarrow_forward
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