(a) Interpretation: The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does not occur is to be predicated. Concept introduction: Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

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Answer 1

Question

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does not occur is to be predicated.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(b)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does occur is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

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Answer 2

Question

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does not occur is to be predicated.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(b)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does occur is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

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Answer 3

Question

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does not occur is to be predicated.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(b)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does occur is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

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Answer 4

Question

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does not occur is to be predicated.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(b)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does occur is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

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Answer 5

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does not occur is to be predicated.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(b)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does occur is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 6

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does not occur is to be predicated.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 7

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does not occur is to be predicated.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does occur is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The labeling pattern observed in the product of the radioactively labeled compound with water if the neighboring-group participation does occur is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

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