PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 11, Problem 11.23E
Consider Figure 11.4 and choose the correct phrase: As the vibrational quantum number increases, the extension of the vibration (increases/decreases/stays the same) while the average length of the oscillator itself (increases/decreases/stays the same). Explain your choices.
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Laser. Indicate the relationship between metastable state and stimulated emission.
The table includes macrostates characterized by 4 energy levels (&) that are
equally spaced but with different degrees of occupation.
a) Calculate the energy of all the macrostates (in joules). See if they all have
the same energy and number of particles.
b) Calculate the macrostate that is most likely to exist. For this macrostate,
show that the population of the levels is consistent with the Boltzmann
distribution.
macrostate 1 macrostate 2 macrostate 3
ε/k (K) Populations
Populations
Populations
300
5
3
4
200
7
9
8
100
15
17
16
0
33
31
32
DATO: k = 1,38×10-23 J K-1
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Chapter 11 Solutions
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
Ch. 11 - Convert 3.558mdyn/A into units of N/m.Ch. 11 - Prob. 11.2ECh. 11 - Prob. 11.3ECh. 11 - Prob. 11.4ECh. 11 - Prob. 11.5ECh. 11 - Prob. 11.6ECh. 11 - Prob. 11.7ECh. 11 - Prob. 11.8ECh. 11 - Prob. 11.9ECh. 11 - Prob. 11.10E
Ch. 11 - Prob. 11.11ECh. 11 - Prob. 11.12ECh. 11 - a For a pendulum having classical frequency of...Ch. 11 - Prob. 11.14ECh. 11 - The OH bond in water vibrates at a frequency of...Ch. 11 - Show that 2 and 3 for the harmonic oscillator are...Ch. 11 - Prob. 11.17ECh. 11 - Prob. 11.18ECh. 11 - Prob. 11.19ECh. 11 - Use the expression for 1 in equations 11.17 and...Ch. 11 - Prob. 11.21ECh. 11 - Prob. 11.22ECh. 11 - Consider Figure 11.4 and choose the correct...Ch. 11 - Based on the trend shown in Figure 11.5, draw the...Ch. 11 - Prob. 11.25ECh. 11 - Prob. 11.26ECh. 11 - Prob. 11.27ECh. 11 - Prob. 11.28ECh. 11 - Prob. 11.29ECh. 11 - Prob. 11.30ECh. 11 - Compare the mass of the electron, me, with a the...Ch. 11 - Reduced mass is not reserved only for atomic...Ch. 11 - Prob. 11.33ECh. 11 - An OH bond has a frequency of 3650cm1. Using...Ch. 11 - Prob. 11.35ECh. 11 - Prob. 11.36ECh. 11 - Prob. 11.37ECh. 11 - Prob. 11.38ECh. 11 - Prob. 11.39ECh. 11 - What are the energies and angular momenta of the...Ch. 11 - Prob. 11.41ECh. 11 - A 25-kg child is on a merry-go-round/calliope,...Ch. 11 - Prob. 11.43ECh. 11 - a Using the expression for the energy of a 2-D...Ch. 11 - Prob. 11.45ECh. 11 - Prob. 11.46ECh. 11 - Prob. 11.47ECh. 11 - The quantized angular momentum is choose one:...Ch. 11 - Prob. 11.49ECh. 11 - Prob. 11.50ECh. 11 - Prob. 11.51ECh. 11 - Can you evaluate r for the spherical harmonic Y22?...Ch. 11 - Show that 1,0 and 1,1 for 3-D rotational motion...Ch. 11 - Prob. 11.54ECh. 11 - Prob. 11.55ECh. 11 - a Using the he expression for the energy of a 3-D...Ch. 11 - Prob. 11.57ECh. 11 - In exercise 11.57 regarding C60, what are the...Ch. 11 - Draw the graphical representations see Figure...Ch. 11 - Prob. 11.60ECh. 11 - What is the physical explanation of the difference...Ch. 11 - List the charges on hydrogen-like atoms whose...Ch. 11 - Prob. 11.63ECh. 11 - Prob. 11.64ECh. 11 - Prob. 11.65ECh. 11 - Calculate the difference between the Bohr radius...Ch. 11 - To four significant figures, the first four lines...Ch. 11 - What would the wavelengths of the Balmer series...Ch. 11 - Construct an energy level diagram showing all...Ch. 11 - Prob. 11.70ECh. 11 - What is the degeneracy of an h subshell? An n...Ch. 11 - What is the numerical value of the total angular...Ch. 11 - What are the values of E, L, and Lz for an F8+...Ch. 11 - Prob. 11.74ECh. 11 - Why does the wavefunction 4,4,0 not exist?...Ch. 11 - Prob. 11.76ECh. 11 - What is the probability of finding an electron in...Ch. 11 - What is the probability of finding an electron in...Ch. 11 - Prob. 11.79ECh. 11 - Prob. 11.80ECh. 11 - State how many radial, angular, and total nodes...Ch. 11 - Prob. 11.82ECh. 11 - Prob. 11.83ECh. 11 - Verify the specific value of a, the Bohr radius,...Ch. 11 - Prob. 11.85ECh. 11 - Prob. 11.86ECh. 11 - Evaluate Lz for 3px, Compare it to the answer in...Ch. 11 - Calculate V for 1s of the H atom and compare it to...Ch. 11 - Prob. 11.89ECh. 11 - Prob. 11.90ECh. 11 - Prob. 11.91ECh. 11 - Prob. 11.92ECh. 11 - Graph the first five wavefunctions for the...Ch. 11 - Prob. 11.94ECh. 11 - Set up and evaluate numerically the integral that...Ch. 11 - Prob. 11.96E
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