PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 11, Problem 11.31E
Compare the mass of the electron,
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Students have asked these similar questions
(11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
.
3°C
with
TH
12. (10pts total) Provide the major product for each reaction depicted below. If no reaction
occurs write NR. Assume heat dissipation is carefully controlled in the fluorine reaction.
3H
24 total (30)
24
21
2h
• 6H total
● 8H total
34
래
Br2
hv
major product
will be most
Substituted
12
hv
Br
NR
I too weak of a
participate in P-1
F₂
hv
Statistically
most favored
product will be
major
=
most subst =
thermo favored
hydrogen atom abstractor to
LL
F
Five chemistry project topic that does not involve practical
Chapter 11 Solutions
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
Ch. 11 - Convert 3.558mdyn/A into units of N/m.Ch. 11 - Prob. 11.2ECh. 11 - Prob. 11.3ECh. 11 - Prob. 11.4ECh. 11 - Prob. 11.5ECh. 11 - Prob. 11.6ECh. 11 - Prob. 11.7ECh. 11 - Prob. 11.8ECh. 11 - Prob. 11.9ECh. 11 - Prob. 11.10E
Ch. 11 - Prob. 11.11ECh. 11 - Prob. 11.12ECh. 11 - a For a pendulum having classical frequency of...Ch. 11 - Prob. 11.14ECh. 11 - The OH bond in water vibrates at a frequency of...Ch. 11 - Show that 2 and 3 for the harmonic oscillator are...Ch. 11 - Prob. 11.17ECh. 11 - Prob. 11.18ECh. 11 - Prob. 11.19ECh. 11 - Use the expression for 1 in equations 11.17 and...Ch. 11 - Prob. 11.21ECh. 11 - Prob. 11.22ECh. 11 - Consider Figure 11.4 and choose the correct...Ch. 11 - Based on the trend shown in Figure 11.5, draw the...Ch. 11 - Prob. 11.25ECh. 11 - Prob. 11.26ECh. 11 - Prob. 11.27ECh. 11 - Prob. 11.28ECh. 11 - Prob. 11.29ECh. 11 - Prob. 11.30ECh. 11 - Compare the mass of the electron, me, with a the...Ch. 11 - Reduced mass is not reserved only for atomic...Ch. 11 - Prob. 11.33ECh. 11 - An OH bond has a frequency of 3650cm1. Using...Ch. 11 - Prob. 11.35ECh. 11 - Prob. 11.36ECh. 11 - Prob. 11.37ECh. 11 - Prob. 11.38ECh. 11 - Prob. 11.39ECh. 11 - What are the energies and angular momenta of the...Ch. 11 - Prob. 11.41ECh. 11 - A 25-kg child is on a merry-go-round/calliope,...Ch. 11 - Prob. 11.43ECh. 11 - a Using the expression for the energy of a 2-D...Ch. 11 - Prob. 11.45ECh. 11 - Prob. 11.46ECh. 11 - Prob. 11.47ECh. 11 - The quantized angular momentum is choose one:...Ch. 11 - Prob. 11.49ECh. 11 - Prob. 11.50ECh. 11 - Prob. 11.51ECh. 11 - Can you evaluate r for the spherical harmonic Y22?...Ch. 11 - Show that 1,0 and 1,1 for 3-D rotational motion...Ch. 11 - Prob. 11.54ECh. 11 - Prob. 11.55ECh. 11 - a Using the he expression for the energy of a 3-D...Ch. 11 - Prob. 11.57ECh. 11 - In exercise 11.57 regarding C60, what are the...Ch. 11 - Draw the graphical representations see Figure...Ch. 11 - Prob. 11.60ECh. 11 - What is the physical explanation of the difference...Ch. 11 - List the charges on hydrogen-like atoms whose...Ch. 11 - Prob. 11.63ECh. 11 - Prob. 11.64ECh. 11 - Prob. 11.65ECh. 11 - Calculate the difference between the Bohr radius...Ch. 11 - To four significant figures, the first four lines...Ch. 11 - What would the wavelengths of the Balmer series...Ch. 11 - Construct an energy level diagram showing all...Ch. 11 - Prob. 11.70ECh. 11 - What is the degeneracy of an h subshell? An n...Ch. 11 - What is the numerical value of the total angular...Ch. 11 - What are the values of E, L, and Lz for an F8+...Ch. 11 - Prob. 11.74ECh. 11 - Why does the wavefunction 4,4,0 not exist?...Ch. 11 - Prob. 11.76ECh. 11 - What is the probability of finding an electron in...Ch. 11 - What is the probability of finding an electron in...Ch. 11 - Prob. 11.79ECh. 11 - Prob. 11.80ECh. 11 - State how many radial, angular, and total nodes...Ch. 11 - Prob. 11.82ECh. 11 - Prob. 11.83ECh. 11 - Verify the specific value of a, the Bohr radius,...Ch. 11 - Prob. 11.85ECh. 11 - Prob. 11.86ECh. 11 - Evaluate Lz for 3px, Compare it to the answer in...Ch. 11 - Calculate V for 1s of the H atom and compare it to...Ch. 11 - Prob. 11.89ECh. 11 - Prob. 11.90ECh. 11 - Prob. 11.91ECh. 11 - Prob. 11.92ECh. 11 - Graph the first five wavefunctions for the...Ch. 11 - Prob. 11.94ECh. 11 - Set up and evaluate numerically the integral that...Ch. 11 - Prob. 11.96E
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