The given compound as a purine or a pyrimidine and name it. Introduction: The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

Question

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Answer 1

Question

Chapter 11, Problem 11.1PP

a.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

a.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 1: Purine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 1

Fig. 1: Purine

Explanation:

The nitrogenous base that is composed of pyrimidine ring connected to the imidazole ring is a purine. There are four “nitrogen” and two “nitrogen-carbon” rings in the structure.

The given nitrogenous base has basic structure that of a purine. The given nitrogenous base is “adenine”.

b.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

b.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 2: Pyrimidine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 2

Fig. 2: Pyrimidine

Explanation:

The nitrogenous base that resembles pyrimidine and benzene in structure and has two nitrogen atoms in the ring is known as a pyrimidine. There are two nitrogen and one “nitrogen-carbon” ring.

The given nitrogenous base has basic structure that of a pyrimidine. The given nitrogenous base is “cytosine”.

The first given compound is adenine and the second compound is cytosine.

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1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on the LC-MS printout. How much different are they? 2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit, explain what each of these is and why they are present. 3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by calculating the accurate monoisotopic mass. 4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source. 5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one point of extra credit, see if you can identify this molecule as well and confirm by…

Please draw, not just describe!

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Answer 2

Question

Chapter 11, Problem 11.1PP

a.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

a.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 1: Purine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 1

Fig. 1: Purine

Explanation:

The nitrogenous base that is composed of pyrimidine ring connected to the imidazole ring is a purine. There are four “nitrogen” and two “nitrogen-carbon” rings in the structure.

The given nitrogenous base has basic structure that of a purine. The given nitrogenous base is “adenine”.

b.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

b.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 2: Pyrimidine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 2

Fig. 2: Pyrimidine

Explanation:

The nitrogenous base that resembles pyrimidine and benzene in structure and has two nitrogen atoms in the ring is known as a pyrimidine. There are two nitrogen and one “nitrogen-carbon” ring.

The given nitrogenous base has basic structure that of a pyrimidine. The given nitrogenous base is “cytosine”.

The first given compound is adenine and the second compound is cytosine.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 3

Question

Chapter 11, Problem 11.1PP

a.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

a.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 1: Purine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 1

Fig. 1: Purine

Explanation:

The nitrogenous base that is composed of pyrimidine ring connected to the imidazole ring is a purine. There are four “nitrogen” and two “nitrogen-carbon” rings in the structure.

The given nitrogenous base has basic structure that of a purine. The given nitrogenous base is “adenine”.

b.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

b.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 2: Pyrimidine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 2

Fig. 2: Pyrimidine

Explanation:

The nitrogenous base that resembles pyrimidine and benzene in structure and has two nitrogen atoms in the ring is known as a pyrimidine. There are two nitrogen and one “nitrogen-carbon” ring.

The given nitrogenous base has basic structure that of a pyrimidine. The given nitrogenous base is “cytosine”.

The first given compound is adenine and the second compound is cytosine.

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Answer 4

Question

Chapter 11, Problem 11.1PP

a.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

a.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 1: Purine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 1

Fig. 1: Purine

Explanation:

The nitrogenous base that is composed of pyrimidine ring connected to the imidazole ring is a purine. There are four “nitrogen” and two “nitrogen-carbon” rings in the structure.

The given nitrogenous base has basic structure that of a purine. The given nitrogenous base is “adenine”.

b.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

b.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 2: Pyrimidine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 2

Fig. 2: Pyrimidine

Explanation:

The nitrogenous base that resembles pyrimidine and benzene in structure and has two nitrogen atoms in the ring is known as a pyrimidine. There are two nitrogen and one “nitrogen-carbon” ring.

The given nitrogenous base has basic structure that of a pyrimidine. The given nitrogenous base is “cytosine”.

The first given compound is adenine and the second compound is cytosine.

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Answer 5

Chapter 11, Problem 11.1PP

a.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

a.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 1: Purine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 1

Fig. 1: Purine

Explanation:

The nitrogenous base that is composed of pyrimidine ring connected to the imidazole ring is a purine. There are four “nitrogen” and two “nitrogen-carbon” rings in the structure.

The given nitrogenous base has basic structure that of a purine. The given nitrogenous base is “adenine”.

b.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

b.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 2: Pyrimidine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 2

Fig. 2: Pyrimidine

Explanation:

The nitrogenous base that resembles pyrimidine and benzene in structure and has two nitrogen atoms in the ring is known as a pyrimidine. There are two nitrogen and one “nitrogen-carbon” ring.

The given nitrogenous base has basic structure that of a pyrimidine. The given nitrogenous base is “cytosine”.

The first given compound is adenine and the second compound is cytosine.

Answer 6

Chapter 11, Problem 11.1PP

a.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

a.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 1: Purine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 1

Fig. 1: Purine

Explanation:

The nitrogenous base that is composed of pyrimidine ring connected to the imidazole ring is a purine. There are four “nitrogen” and two “nitrogen-carbon” rings in the structure.

The given nitrogenous base has basic structure that of a purine. The given nitrogenous base is “adenine”.

Answer 7

Chapter 11, Problem 11.1PP

a.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

Answer 8

a.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 1: Purine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 1

Fig. 1: Purine

Explanation:

The nitrogenous base that is composed of pyrimidine ring connected to the imidazole ring is a purine. There are four “nitrogen” and two “nitrogen-carbon” rings in the structure.

The given nitrogenous base has basic structure that of a purine. The given nitrogenous base is “adenine”.

Answer 9

a.

Expert Solution

Answer 10

a.

Expert Solution

Answer 11

Expert Solution

Answer 12

b.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

b.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 2: Pyrimidine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 2

Fig. 2: Pyrimidine

Explanation:

The nitrogenous base that resembles pyrimidine and benzene in structure and has two nitrogen atoms in the ring is known as a pyrimidine. There are two nitrogen and one “nitrogen-carbon” ring.

The given nitrogenous base has basic structure that of a pyrimidine. The given nitrogenous base is “cytosine”.

The first given compound is adenine and the second compound is cytosine.

Answer 13

b.

Summary Introduction

To identify:

The given compound as a purine or a pyrimidine and name it.

Introduction:

The organic compound having a “nitrogen” atom having chemical characteristics of bases is known as “nitrogen base”. A nitrogenous base connects the two nucleic acids. It resembles the base due to the availability of a “lone pair” of electrons on the nitrogen. There are two types of nitrogenous bases “purines” and “pyrimidines”.

Answer 14

b.

Expert Solution

Explanation of Solution

Pictorial representation:

Fig. 2: Pyrimidine.

GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS, Chapter 11, Problem 11.1PP , additional homework tip 2

Fig. 2: Pyrimidine

Explanation:

The nitrogenous base that resembles pyrimidine and benzene in structure and has two nitrogen atoms in the ring is known as a pyrimidine. There are two nitrogen and one “nitrogen-carbon” ring.

The given nitrogenous base has basic structure that of a pyrimidine. The given nitrogenous base is “cytosine”.

The first given compound is adenine and the second compound is cytosine.