Chemistry: Atoms First
3rd Edition
ISBN: 9781259923142
Author: Burdge
Publisher: MCG
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Chapter 11, Problem 11.161QP
Interpretation Introduction
Interpretation: The negative deviation from ideal behavior at lower pressures and the positive deviation from ideal behavior at higher pressure have to be explained.
Concept Introduction:
Ideal gas is the most usually used form of the ideal gas equation, which describes the relationship among the four variables P, V, n, and T. An ideal gas is a hypothetical sample of gas whose pressure-volume-temperature behavior is predicted accurately by the ideal gas equation.
The compressibility factor Z of a gas is defined as
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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or
non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I
electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly
drawn and you should be able to tell that the bonding electrons and lone pair electrons
should reside in which hybridized atomic orbital 2. You should consider ring strain-
flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti-
aromaticity)
H H
N
N:
NH2
N
Aromaticity
(Circle)
Aromatic Aromatic Aromatic Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic TT
electrons
Me
H
Me
Aromaticity
(Circle)
Aromatic Aromatic Aromatic
Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic πT
electrons
H
HH…
A chemistry graduate student is studying the rate of this reaction:
2 HI (g) →H2(g) +12(g)
She fills a reaction vessel with HI and measures its concentration as the reaction proceeds:
time
(minutes)
[IH]
0
0.800M
1.0
0.301 M
2.0
0.185 M
3.0
0.134M
4.0
0.105 M
Use this data to answer the following questions.
Write the rate law for this reaction.
rate
= 0
Calculate the value of the rate constant k.
k =
Round your answer to 2 significant digits. Also be
sure your answer has the correct unit symbol.
None
Chapter 11 Solutions
Chemistry: Atoms First
Ch. 11.2 - Prob. 11.1WECh. 11.2 - Prob. 1PPACh. 11.2 - Prob. 1PPBCh. 11.2 - Prob. 1PPCCh. 11.2 - Prob. 11.2.1SRCh. 11.2 - Prob. 11.2.2SRCh. 11.3 - Prob. 11.2WECh. 11.3 - Prob. 2PPACh. 11.3 - Prob. 2PPBCh. 11.3 - Arrange the four columns of liquid [(i)(iv)] in...
Ch. 11.3 - Prob. 11.3.1SRCh. 11.3 - Which of the following is true? (Select all that...Ch. 11.3 - Prob. 11.3.3SRCh. 11.3 - Prob. 11.3.4SRCh. 11.3 - Prob. 11.3.5SRCh. 11.4 - Prob. 11.3WECh. 11.4 - Prob. 3PPACh. 11.4 - Prob. 3PPBCh. 11.4 - Prob. 3PPCCh. 11.4 - Prob. 11.4WECh. 11.4 - Prob. 4PPACh. 11.4 - Prob. 4PPBCh. 11.4 - Prob. 4PPCCh. 11.4 - If we combine 3.0 L of NO and 1.5 L of O2, and...Ch. 11.4 - What volume (in liters) of water vapor will be...Ch. 11.4 - Prob. 5PPBCh. 11.4 - Prob. 5PPCCh. 11.4 - Prob. 11.6WECh. 11.4 - Prob. 6PPACh. 11.4 - Prob. 6PPBCh. 11.4 - Prob. 6PPCCh. 11.4 - Prob. 11.4.1SRCh. 11.4 - Prob. 11.4.2SRCh. 11.4 - Prob. 11.4.3SRCh. 11.4 - Prob. 11.4.4SRCh. 11.4 - Prob. 11.4.5SRCh. 11.4 - Prob. 11.4.6SRCh. 11.5 - Prob. 11.7WECh. 11.5 - Prob. 7PPACh. 11.5 - Prob. 7PPBCh. 11.5 - Prob. 7PPCCh. 11.5 - Prob. 11.8WECh. 11.5 - Prob. 8PPACh. 11.5 - Prob. 8PPBCh. 11.5 - Prob. 8PPCCh. 11.5 - Prob. 11.9WECh. 11.5 - Prob. 9PPACh. 11.5 - Prob. 9PPBCh. 11.5 - Prob. 9PPCCh. 11.5 - Prob. 11.5.1SRCh. 11.5 - Prob. 11.5.2SRCh. 11.5 - Determine the density of a gas with m = 146.07...Ch. 11.5 - Prob. 11.5.4SRCh. 11.6 - Prob. 11.10WECh. 11.6 - Prob. 10PPACh. 11.6 - Prob. 10PPBCh. 11.6 - Prob. 10PPCCh. 11.6 - Prob. 11.11WECh. 11.6 - Determine the excluded volume per mole and the...Ch. 11.6 - Prob. 11PPBCh. 11.6 - Prob. 11PPCCh. 11.6 - Prob. 11.6.1SRCh. 11.6 - Prob. 11.6.2SRCh. 11.7 - Prob. 11.12WECh. 11.7 - Prob. 12PPACh. 11.7 - Prob. 12PPBCh. 11.7 - Prob. 12PPCCh. 11.7 - Prob. 11.13WECh. 11.7 - Prob. 13PPACh. 11.7 - Prob. 13PPBCh. 11.7 - Prob. 13PPCCh. 11.7 - What is the partial pressure of He in a 5.00-L...Ch. 11.7 - Prob. 11.7.2SRCh. 11.7 - Prob. 11.7.3SRCh. 11.7 - Prob. 11.7.4SRCh. 11.7 - Prob. 11.7.5SRCh. 11.8 - Prob. 11.14WECh. 11.8 - Prob. 14PPACh. 11.8 - Prob. 14PPBCh. 11.8 - Prob. 14PPCCh. 11.8 - Prob. 11.15WECh. 11.8 - Prob. 15PPACh. 11.8 - Prob. 15PPBCh. 11.8 - Prob. 15PPCCh. 11.8 - Calcium metal reacts with water to produce...Ch. 11.8 - Prob. 16PPACh. 11.8 - Determine the volume of gas collected over water...Ch. 11.8 - Prob. 16PPCCh. 11.8 - Determine the volume of Cl2 gas at STP that will...Ch. 11.8 - Determine the mass of NaN3 required for an air bag...Ch. 11.8 - What mass of acetylene (C2H2) is produced by the...Ch. 11 - Determine the mole fraction of helium in a gaseous...Ch. 11 - Prob. 11.2KSPCh. 11 - Prob. 11.3KSPCh. 11 - Prob. 11.4KSPCh. 11 - Prob. 11.1QPCh. 11 - Prob. 11.2QPCh. 11 - Prob. 11.3QPCh. 11 - Prob. 11.4QPCh. 11 - Prob. 11.5QPCh. 11 - Prob. 11.6QPCh. 11 - Prob. 11.7QPCh. 11 - Prob. 11.8QPCh. 11 - Prob. 11.9QPCh. 11 - Prob. 11.10QPCh. 11 - Prob. 11.11QPCh. 11 - The 235U isotope undergoes fission when bombarded...Ch. 11 - Prob. 11.13QPCh. 11 - Prob. 11.14QPCh. 11 - Prob. 11.15QPCh. 11 - Prob. 11.16QPCh. 11 - Prob. 11.17QPCh. 11 - Prob. 11.18QPCh. 11 - Prob. 11.19QPCh. 11 - Prob. 11.20QPCh. 11 - Prob. 11.21QPCh. 11 - Prob. 11.22QPCh. 11 - Prob. 11.23QPCh. 11 - Calculate the height of a column of isopropanol...Ch. 11 - Prob. 11.25QPCh. 11 - Prob. 11.26QPCh. 11 - Prob. 11.27QPCh. 11 - Prob. 11.28QPCh. 11 - Prob. 11.29QPCh. 11 - Prob. 11.30QPCh. 11 - Prob. 11.31QPCh. 11 - A sample of air occupies 3.8 L when the pressure...Ch. 11 - Prob. 11.33QPCh. 11 - Prob. 11.34QPCh. 11 - Prob. 11.35QPCh. 11 - Prob. 11.36QPCh. 11 - Prob. 11.37QPCh. 11 - Prob. 11.38QPCh. 11 - A gaseous sample of a substance is cooled at...Ch. 11 - Prob. 11.40QPCh. 11 - Prob. 11.41QPCh. 11 - Prob. 11.42QPCh. 11 - Prob. 11.43QPCh. 11 - Prob. 11.44QPCh. 11 - Prob. 11.45QPCh. 11 - Prob. 11.46QPCh. 11 - Prob. 11.47QPCh. 11 - Prob. 11.48QPCh. 11 - Prob. 11.49QPCh. 11 - Prob. 11.50QPCh. 11 - Prob. 11.51QPCh. 11 - Prob. 11.52QPCh. 11 - Prob. 11.53QPCh. 11 - Prob. 11.54QPCh. 11 - Prob. 11.55QPCh. 11 - Prob. 11.56QPCh. 11 - Prob. 11.57QPCh. 11 - A certain anesthetic contains 64.9 percent C, 13.5...Ch. 11 - A compound has the empirical formula SF4. At 20C,...Ch. 11 - Prob. 11.60QPCh. 11 - Prob. 11.61QPCh. 11 - Prob. 11.62QPCh. 11 - Prob. 11.63QPCh. 11 - Write the van der Waals equation for a real gas....Ch. 11 - Prob. 11.65QPCh. 11 - Prob. 11.66QPCh. 11 - Prob. 11.67QPCh. 11 - Prob. 11.68QPCh. 11 - Prob. 11.69QPCh. 11 - Prob. 11.70QPCh. 11 - Prob. 11.71QPCh. 11 - Prob. 11.72QPCh. 11 - Prob. 11.73QPCh. 11 - Prob. 11.74QPCh. 11 - Prob. 11.75QPCh. 11 - Prob. 11.76QPCh. 11 - Prob. 11.77QPCh. 11 - Prob. 11.78QPCh. 11 - Prob. 11.79QPCh. 11 - Prob. 11.1VCCh. 11 - Prob. 11.2VCCh. 11 - Prob. 11.3VCCh. 11 - Prob. 11.4VCCh. 11 - Prob. 11.80QPCh. 11 - Prob. 11.81QPCh. 11 - Prob. 11.82QPCh. 11 - Prob. 11.83QPCh. 11 - Prob. 11.84QPCh. 11 - Prob. 11.85QPCh. 11 - Prob. 11.86QPCh. 11 - Prob. 11.87QPCh. 11 - Prob. 11.88QPCh. 11 - Ethanol (C2H5OH) bums in air: C2H5OH(l) + O2(g) ...Ch. 11 - Prob. 11.90QPCh. 11 - Prob. 11.91QPCh. 11 - Prob. 11.92QPCh. 11 - Prob. 11.93QPCh. 11 - Prob. 11.94QPCh. 11 - Prob. 11.95QPCh. 11 - Prob. 11.96QPCh. 11 - Prob. 11.97QPCh. 11 - Prob. 11.98QPCh. 11 - Prob. 11.99QPCh. 11 - Prob. 11.100QPCh. 11 - Prob. 11.101QPCh. 11 - Prob. 11.102QPCh. 11 - Prob. 11.103QPCh. 11 - Prob. 11.104QPCh. 11 - Prob. 11.105QPCh. 11 - Prob. 11.106QPCh. 11 - Prob. 11.107QPCh. 11 - Prob. 11.108QPCh. 11 - Prob. 11.109QPCh. 11 - A 180.0-mg sample of an alloy of iron and metal X...Ch. 11 - Prob. 11.111QPCh. 11 - Prob. 11.112QPCh. 11 - Prob. 11.113QPCh. 11 - Prob. 11.114QPCh. 11 - Prob. 11.115QPCh. 11 - Prob. 11.116QPCh. 11 - Prob. 11.117QPCh. 11 - Prob. 11.118QPCh. 11 - Prob. 11.119QPCh. 11 - Prob. 11.120QPCh. 11 - Prob. 11.121QPCh. 11 - Prob. 11.122QPCh. 11 - Prob. 11.123QPCh. 11 - Prob. 11.124QPCh. 11 - Prob. 11.125QPCh. 11 - Acidic oxides such as carbon dioxide react with...Ch. 11 - Prob. 11.127QPCh. 11 - Prob. 11.128QPCh. 11 - Prob. 11.129QPCh. 11 - Prob. 11.130QPCh. 11 - Prob. 11.131QPCh. 11 - Prob. 11.132QPCh. 11 - Prob. 11.133QPCh. 11 - Prob. 11.134QPCh. 11 - Prob. 11.135QPCh. 11 - Prob. 11.136QPCh. 11 - Prob. 11.137QPCh. 11 - Prob. 11.138QPCh. 11 - Prob. 11.139QPCh. 11 - Prob. 11.140QPCh. 11 - Prob. 11.141QPCh. 11 - At what temperature will He atoms have the same...Ch. 11 - Prob. 11.143QPCh. 11 - Prob. 11.144QPCh. 11 - Prob. 11.145QPCh. 11 - Prob. 11.146QPCh. 11 - Prob. 11.147QPCh. 11 - Prob. 11.148QPCh. 11 - Prob. 11.149QPCh. 11 - Prob. 11.150QPCh. 11 - Prob. 11.151QPCh. 11 - A 5.00-mole sample of NH3 gas is kept in a 1.92-L...Ch. 11 - Prob. 11.153QPCh. 11 - Prob. 11.154QPCh. 11 - Prob. 11.155QPCh. 11 - Prob. 11.156QPCh. 11 - Prob. 11.157QPCh. 11 - Prob. 11.158QPCh. 11 - Prob. 11.159QPCh. 11 - Prob. 11.160QPCh. 11 - Prob. 11.161QP
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