(a) Interpretation: It is to be determined how the given compound can be produced from an alkene. Concept introduction: An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

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Answer 1

Question

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

It is to be determined how the given compound can be produced from an alkene.

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Interpretation Introduction

(b)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Interpretation Introduction

(c)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Complete the spectroscopy with structure

Answer 2

Question

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

It is to be determined how the given compound can be produced from an alkene.

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Interpretation Introduction

(b)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Interpretation Introduction

(c)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

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Answer 3

Question

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

It is to be determined how the given compound can be produced from an alkene.

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Interpretation Introduction

(b)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Interpretation Introduction

(c)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

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Answer 4

Question

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

It is to be determined how the given compound can be produced from an alkene.

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Interpretation Introduction

(b)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Interpretation Introduction

(c)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

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Answer 5

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

It is to be determined how the given compound can be produced from an alkene.

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Interpretation Introduction

(b)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Interpretation Introduction

(c)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Answer 6

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

It is to be determined how the given compound can be produced from an alkene.

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Answer 7

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

It is to be determined how the given compound can be produced from an alkene.

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Answer 8

Interpretation Introduction

(b)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Answer 9

Interpretation Introduction

(b)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Answer 10

Interpretation Introduction

(c)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Answer 11

Interpretation Introduction

(c)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Answer 12

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Answer 13

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Answer 15

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

Solution Summary: The author explains that an electrophile is an electron-deficient species that is attacked by a nucleophile. Alkenes undergo acid-catalyzed hydration reactions.

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