Chemistry - Modified MasteringChemistry
7th Edition
ISBN: 9780133892321
Author: McMurry
Publisher: PEARSON
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Chapter 11, Problem 11.119MP
A group 3A metal has a density of 2.70 g/cm3 and a cubic unit cell with an edge length of 404 pm. Reaction of a 1.07 cm3 chunk of the metal with an excess of hydrochloric acid gives a colorless gas that occupies 4.00 L at 23.0 °C and a pressure of 740 mm Hg.
(a) Identify the metal.
(b) Is the unit cell primitive, body-centered, or face-centered?
(c) What is the atomic radius of the metal atom in picometers?
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There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS).
Ca, ppm
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SV, arb. units
20.0
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10.0
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A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C.
H₂O(g) + C₁₂O(g) = 2 HOCl(g)
K = 0.0900 at 25°C
с
Calculate the equilibrium concentrations of each gas at 25 °C.
[H₂O]=
[C₁₂O]=
[HOCI]=
M
Σ
M
What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?
Chapter 11 Solutions
Chemistry - Modified MasteringChemistry
Ch. 11 - PRACTICE 11.1 The boiling point of ethanol is 78.4...Ch. 11 - APPLY 11.2 Chloroform CHCl3 has Hvap=29.2kJ/mol...Ch. 11 - Prob. 11.3PCh. 11 - APPLY 11.4 What is the sign and magnitude of q...Ch. 11 - Prob. 11.5PCh. 11 - Prob. 11.6ACh. 11 - Prob. 11.7PCh. 11 - Prob. 11.8ACh. 11 - Prob. 11.9PCh. 11 - Prob. 11.10A
Ch. 11 - PRACTICE 11.11 Polonium metal crystallizes in a...Ch. 11 - Prob. 11.12ACh. 11 - Prob. 11.13PCh. 11 - Prob. 11.14ACh. 11 - Conceptual PRACTICE 11.15 Look at the phase...Ch. 11 - Prob. 11.16ACh. 11 - Prob. 11.17PCh. 11 - Prob. 11.18PCh. 11 - Prob. 11.19PCh. 11 - Prob. 11.20PCh. 11 - Prob. 11.21PCh. 11 - Assume that you have a liquid in a cylinder...Ch. 11 - Identify each of the following kinds of packing:Ch. 11 - Prob. 11.24CPCh. 11 - Prob. 11.25CPCh. 11 - Prob. 11.26CPCh. 11 - Prob. 11.27CPCh. 11 - Prob. 11.28SPCh. 11 - Prob. 11.29SPCh. 11 - Prob. 11.30SPCh. 11 - Prob. 11.31SPCh. 11 - Prob. 11.32SPCh. 11 - Prob. 11.33SPCh. 11 - Prob. 11.34SPCh. 11 - Prob. 11.35SPCh. 11 - Prob. 11.36SPCh. 11 - Prob. 11.37SPCh. 11 - Prob. 11.38SPCh. 11 - Prob. 11.39SPCh. 11 - Prob. 11.40SPCh. 11 - Prob. 11.41SPCh. 11 - Prob. 11.42SPCh. 11 - Prob. 11.43SPCh. 11 - Prob. 11.44SPCh. 11 - Prob. 11.45SPCh. 11 - Prob. 11.46SPCh. 11 - Prob. 11.47SPCh. 11 - Prob. 11.48SPCh. 11 - Prob. 11.49SPCh. 11 - Prob. 11.50SPCh. 11 - Prob. 11.51SPCh. 11 - Prob. 11.52SPCh. 11 - Prob. 11.53SPCh. 11 - Prob. 11.54SPCh. 11 - Prob. 11.55SPCh. 11 - Prob. 11.56SPCh. 11 - Prob. 11.57SPCh. 11 - Prob. 11.58SPCh. 11 - Prob. 11.59SPCh. 11 - Prob. 11.60SPCh. 11 - Prob. 11.61SPCh. 11 - Prob. 11.62SPCh. 11 - Prob. 11.63SPCh. 11 - Prob. 11.64SPCh. 11 - Prob. 11.65SPCh. 11 - Prob. 11.66SPCh. 11 - Prob. 11.67SPCh. 11 - Copper crystallizes in a face-centered cubic unit...Ch. 11 - 11.69 Lead crystallizes in a face-centered cubic...Ch. 11 - Aluminum has a density of 2.699 g/cm3 and...Ch. 11 - Tungsten crystallizes in a body-centered cubic...Ch. 11 - Prob. 11.72SPCh. 11 - Prob. 11.73SPCh. 11 - Prob. 11.74SPCh. 11 - Prob. 11.75SPCh. 11 - Prob. 11.76SPCh. 11 - Prob. 11.77SPCh. 11 - Prob. 11.78SPCh. 11 - Prob. 11.79SPCh. 11 - Prob. 11.80SPCh. 11 - Prob. 11.81SPCh. 11 - Prob. 11.82SPCh. 11 - Prob. 11.83SPCh. 11 - Prob. 11.84SPCh. 11 - Prob. 11.85SPCh. 11 - Prob. 11.86SPCh. 11 - Prob. 11.87SPCh. 11 - Prob. 11.88SPCh. 11 - 11.89 Assume that you have samples of the...Ch. 11 - Prob. 11.90SPCh. 11 - Prob. 11.91SPCh. 11 - Prob. 11.92SPCh. 11 - Prob. 11.93SPCh. 11 - Prob. 11.94CPCh. 11 - Prob. 11.95CPCh. 11 - Prob. 11.96CPCh. 11 - Prob. 11.97CPCh. 11 - Prob. 11.98CPCh. 11 - Prob. 11.99CPCh. 11 - Prob. 11.100CPCh. 11 - Prob. 11.101CPCh. 11 - Prob. 11.102CPCh. 11 - Prob. 11.103CPCh. 11 - Prob. 11.104CPCh. 11 - Prob. 11.105CPCh. 11 - Prob. 11.106CPCh. 11 - Prob. 11.107CPCh. 11 - Prob. 11.108CPCh. 11 - Iron crystallizes in a body-centered cubic unit...Ch. 11 - Prob. 11.110CPCh. 11 - Prob. 11.111CPCh. 11 - Prob. 11.112CPCh. 11 - Prob. 11.113CPCh. 11 - Prob. 11.114CPCh. 11 - Prob. 11.115CPCh. 11 - Prob. 11.116MPCh. 11 - Prob. 11.117MPCh. 11 - Prob. 11.118MPCh. 11 - A group 3A metal has a density of 2.70 g/cm3 and a...Ch. 11 - Prob. 11.120MPCh. 11 - Prob. 11.121MP
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