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Concept explainers
Interpretation:
The value of
Concept introduction:
A unit cell is the smallest amount of 3-Dimensional piece of a solid comprising of basic particles of the solid in varied but generally common arrangements which when recurring over and again in dissimilar directions gives the complete solid crystal. There are numerous unit cells depending on the parameters, i.e. axial angles and axial length and second, on basis of location of constituent particles within the unit cell.
All unit cell is characterized in terms of lattice points--the points in space regarding which the particles are liberated to vibrate inside the crystal.
Face-centered cubic unit cell - It too begins with similar particles resting on the 8 corners of the cube. But this structure too contains the similar particles inside the centers of the 6 faces of the unit cell, for a sum of fourteen similar kind of lattice point.
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Chapter 11 Solutions
Chemistry - Modified MasteringChemistry
- Propose syntheses of the following compounds starting with benzene or toluene. Assume ortho and isomers can be separated. a. b. O₂N- Cl COOH para 0. Propose syntheses to carry out each of the following conversions. Assume ortho and para isomers can be separated a. Br b. COOH CH3 NH₂ PABA (active ingredient in some sunscreens)arrow_forwardH3C H C=C CH3 H m-chloroperoxybenzoic acid CH2Cl2, rt C-C--. H3CH2CC H H3C CH3 Cl₂ H₂O NaOH H₂O D. S- E. CH3 H₂O₂, H₂O It CH₂O Na + CHI F. HI, H₂O heat G. 4 OH CH3CHCH3 + ICH2CH3 1. NaH (CH3)3COH (CH3)3 COCHCH2CH3 2. CH3arrow_forward5. Show how the ether below could be prepared from toluene and any other necessary reagents. Show all reagents and all intermediate structures. H3C- H3C- CI OCH2CH3arrow_forward
- Given the major organic product(s) of each of the following reactions. If none is predicted, write "N.R." [answer 61 a. b. H3C C. NO₂ CH3CH2CH2Cl AICI 3 1) NaOH CI 2) H3O+ NO₂ 1. SnCl2, H3O+ 2. NaOH 3arrow_forwardPlease correct answer and don't used hand raitingarrow_forwardTo answer the following questions, consider the reaction below: CH3 . CH3 OH a. The best reagents for accomplishing the above transformation are.... a. 1. OsO4, pyridine 2. NaHSO3, H₂O b. 1. Hg(OAc)2, H₂O 1. C. 2. NaBH4 RCO₂H, CH2Cl₂ 2. H₂O* d. 1. BH3, THF 2. H₂O₂, OH b. The alcohol product is classified as a: a. 1° alcohol b. 2° alcohol C. 3° alcohol d. 4° alcohol c. The conversion of an alcohol into an alkyl chloride by reaction with SOCI2 is an example of: a. b. ن نخنه C. d. an El process an Syl process an E2 process an Sy2 processarrow_forward
- Estimation of ash in food Questions: Q1: What does the word ash refer to? Q2: Mention the types of ash in food Q3: Mention the benefit of using a glass dryerarrow_forwardDraw structures corresponding to the names given a. m-fluoronitrobenzene b. p-bromoaniline c. o-chlorophenol d. 3,5-dimethylbenzoic acidarrow_forwardIllustrate the reaction mechanism the following reactionarrow_forward
- Propose a synthesis for the following compound using benzene or toluene and any other reagents necessary. Show all major intermediate compounds that would probably be isolated during the course of your synthesis. on. Harrow_forwardProvide correct IUPAC names for each of the following compounds. NOT a. b. C. 2003 H,N- CH3 NH2 CHarrow_forward. Consider the reaction below to answer the following questions. OH 1. NaH 2. CH3I, ether O-CH3 A. Write the complete stepwise mechanism for the reaction. Show all intermediate structures and all electron flow with arrows. B. Mechanistically, the Williamson ether synthesis outlined above is: ن نخنه a. an El process b. an SN1 process C. an E2 process d. an SN2 process C. Alternatively, cyclopentyl methyl ether may be synthesized from cyclopentene. synthesis of cyclopentyl methyl ether from cyclopentene. Outline aarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
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