a) Interpretation: Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated. Concept introduction: Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary. To state: Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Question

(11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)!

Answer 1

Question

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

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(11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)!

. 3°C with TH 12. (10pts total) Provide the major product for each reaction depicted below. If no reaction occurs write NR. Assume heat dissipation is carefully controlled in the fluorine reaction. 3H 24 total (30) 24 21 2h • 6H total ● 8H total 34 래 Br2 hv major product will be most Substituted 12 hv Br NR I too weak of a participate in P-1 F₂ hv Statistically most favored product will be major = most subst = thermo favored hydrogen atom abstractor to LL F

Five chemistry project topic that does not involve practical

Answer 2

Question

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

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Answer 3

Question

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

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Answer 4

Question

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

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Answer 5

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 6

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 7

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 8

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 9

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 10

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 11

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 12

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Answer 23

Ch. 10.1 - Prob. 1P Ch. 10.1 - Draw structures corresponding to the following...Ch. 10.2 - Prob. 3P Ch. 10.2 - Taking the relative reactivities of 1Â°, 2Â°, and...Ch. 10.4 - Prob. 5P Ch. 10.4 - The major product of the reaction of...Ch. 10.4 - Prob. 7P Ch. 10.5 - Prob. 8P Ch. 10.6 - Prob. 9P Ch. 10.6 - How might you replace a halogen substituent by a...

Solution Summary: The author explains that alcohols react with HX to yield the corresponding alkyl halide.

Chapter 10 Solutions