Chemistry Atoms First, Second Edition
2nd Edition
ISBN: 9781308211657
Author: Burdge
Publisher: McGraw Hill
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Question
Chapter 10.3, Problem 10.3.2SR
Interpretation Introduction
Interpretation:
The mass of Copper produced from the given thermochemical equation has to be calculated.
Concept Introduction:
Heat:
Heat is flow of thermal energy involving two bodies at various temperatures. The flow of heat implies that energy is either released or absorbed on describing about energy changes that takes place during a process.
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1. Consider the following molecular-level diagrams of a titration.
O-HA molecule
-Aion
°°
о
°
(a)
о
(b)
(c)
(d)
a. Which diagram best illustrates the microscopic representation for the
EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium.
hydroxide?
(e)
Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single
file upload below:
Review of this week's reaction:
H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O --->
H₂NC(=NH)N(CH3)CH2COOH (creatine)
Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing
the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts)
Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts)
Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3
pts)
NH2(C=NH)-N(CH)CH2COOH
This bond
Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem
Q9 is valid). (4 pts)
Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should
be ready to understand the first half of one of the Grignard reactions presented in a past…
Propose a synthesis pathway for the
following transformations. b) c) d)
Chapter 10 Solutions
Chemistry Atoms First, Second Edition
Ch. 10.1 - Prob. 10.1.1SRCh. 10.1 - Prob. 10.1.2SRCh. 10.1 - Prob. 10.1.3SRCh. 10.2 - Calculate the overall change in internal energy,...Ch. 10.2 - Calculate the change in total internal energy for...Ch. 10.2 - Calculate the magnitude of q for a system that...Ch. 10.2 - The diagram on the left shows a system before a...Ch. 10.2 - Prob. 10.2.1SRCh. 10.2 - Prob. 10.2.2SRCh. 10.3 - Determine the work done (in joules) when a sample...
Ch. 10.3 - Calculate the work done by or on the system during...Ch. 10.3 - (a) Against what external pressure must a gas...Ch. 10.3 - The diagram on the left shows a sample of gas...Ch. 10.3 - Given the thermochemical equation for...Ch. 10.3 - Calculate the solar energy required to produce...Ch. 10.3 - Prob. 3PPBCh. 10.3 - The diagrams represent systems before and after...Ch. 10.3 - Prob. 10.3.1SRCh. 10.3 - Prob. 10.3.2SRCh. 10.4 - Prob. 10.4WECh. 10.4 - Prob. 4PPACh. 10.4 - Prob. 4PPBCh. 10.4 - A metal pellet with a mass of 100.0 g. originally...Ch. 10.4 - What would the final temperature be if the pellet...Ch. 10.4 - Prob. 5PPBCh. 10.4 - Prob. 5PPCCh. 10.4 - A Famous Amos bite-sized chocolate chip cookie...Ch. 10.4 - A serving of Grape-Nuts cereal (5.80 g) is burned...Ch. 10.4 - Prob. 6PPBCh. 10.4 - Suppose an experiment to determine the energy...Ch. 10.4 - Prob. 10.4.1SRCh. 10.4 - Prob. 10.4.2SRCh. 10.4 - Prob. 10.4.3SRCh. 10.4 - Prob. 10.4.4SRCh. 10.5 - Given the following thermochemical equations....Ch. 10.5 - Use the thermochemical equations provided in...Ch. 10.5 - Prob. 10.5.1SRCh. 10.5 - Prob. 10.5.2SRCh. 10.6 - Prob. 10.8WECh. 10.6 - Using data from Appendix 2, calculate Hrn for...Ch. 10.6 - Prob. 8PPBCh. 10.6 - The diagrams represent a system before and after a...Ch. 10.6 - Given the following information, calculate the...Ch. 10.6 - Use the following data to calculate Hf for...Ch. 10.6 - Prob. 9PPBCh. 10.6 - The diagrams represent a system before and after a...Ch. 10.6 - Prob. 10.6.1SRCh. 10.6 - Prob. 10.6.2SRCh. 10.6 - Prob. 10.6.3SRCh. 10.7 - Use bond enthalpies from Table 10.4 to estimate...Ch. 10.7 - Use bond enthalpies from fable 10.4 to estimate...Ch. 10.7 - Prob. 10PPBCh. 10.7 - Prob. 10PPCCh. 10.7 - Prob. 10.7.1SRCh. 10.7 - Prob. 10.7.2SRCh. 10.7 - Prob. 10.7.3SRCh. 10.7 - Prob. 10.7.4SRCh. 10.8 - Prob. 10.11WECh. 10.8 - Prob. 11PPACh. 10.8 - The lattice energy of MgO is 3890 kJ/mol, and the...Ch. 10.8 - Prob. 11PPCCh. 10.8 - Prob. 10.8.1SRCh. 10.8 - Prob. 10.8.2SRCh. 10 - Define these terms: system, surroundings, thermal...Ch. 10 - What is heat? How does heat differ from thermal...Ch. 10 - Prob. 10.3QPCh. 10 - Define these terms: thermochemistry, exothermic...Ch. 10 - Prob. 10.5QPCh. 10 - Describe two exothermic processes and two...Ch. 10 - Decomposition reactions are usually endothermic,...Ch. 10 - On what law is the first law of thermodynamics...Ch. 10 - Explain what is meant by a state function. Give...Ch. 10 - Prob. 10.10QPCh. 10 - Prob. 10.11QPCh. 10 - Prob. 10.12QPCh. 10 - Prob. 10.13QPCh. 10 - Prob. 10.14QPCh. 10 - Prob. 10.15QPCh. 10 - Prob. 10.16QPCh. 10 - Define these terms: enthalpy and enthalpy of...Ch. 10 - Prob. 10.18QPCh. 10 - Prob. 10.19QPCh. 10 - Prob. 10.20QPCh. 10 - Prob. 10.21QPCh. 10 - A gas expands and does PV work on the surroundings...Ch. 10 - Prob. 10.23QPCh. 10 - Prob. 10.24QPCh. 10 - Consider the reaction at a certain temperature. If...Ch. 10 - Prob. 10.26QPCh. 10 - Prob. 10.27QPCh. 10 - Prob. 10.28QPCh. 10 - Prob. 10.1VCCh. 10 - Prob. 10.2VCCh. 10 - Prob. 10.3VCCh. 10 - Prob. 10.4VCCh. 10 - Prob. 10.5VCCh. 10 - Prob. 10.6VCCh. 10 - Prob. 10.7VCCh. 10 - Referring to the process depicted in Figure 10.10,...Ch. 10 - What is the difference between specific heat and...Ch. 10 - Define calorimetry and describe two commonly used...Ch. 10 - Prob. 10.31QPCh. 10 - Prob. 10.32QPCh. 10 - A sheet of gold weighing 10.0 g and at a...Ch. 10 - Prob. 10.34QPCh. 10 - A quantity of 2.00 102 mL of 0.862 M HC1 is mixed...Ch. 10 - Prob. 10.36QPCh. 10 - Prob. 10.37QPCh. 10 - Prob. 10.38QPCh. 10 - A 25.95-g sample of methanol at 35.6C is added to...Ch. 10 - Prob. 10.40QPCh. 10 - Prob. 10.41QPCh. 10 - Prob. 10.42QPCh. 10 - Prob. 10.43QPCh. 10 - Prob. 10.44QPCh. 10 - Prob. 10.45QPCh. 10 - Prob. 10.46QPCh. 10 - Prob. 10.47QPCh. 10 - Prob. 10.48QPCh. 10 - Prob. 10.49QPCh. 10 - Prob. 10.50QPCh. 10 - What is meant by the standard-state condition?Ch. 10 - How are the standard enthalpies of an element and...Ch. 10 - What is meant by the standard enthalpy of a...Ch. 10 - Write the equation for calculating the enthalpy of...Ch. 10 - Prob. 10.55QPCh. 10 - Prob. 10.56QPCh. 10 - Prob. 10.57QPCh. 10 - Calculate the heats of combustion for the...Ch. 10 - Calculate the heats of combustion for the...Ch. 10 - Prob. 10.60QPCh. 10 - Prob. 10.61QPCh. 10 - Prob. 10.62QPCh. 10 - From the standard enthalpies of formation,...Ch. 10 - Prob. 10.64QPCh. 10 - Prob. 10.65QPCh. 10 - Prob. 10.66QPCh. 10 - Which is the more negative quantity at 25C: Hf for...Ch. 10 - Prob. 10.68QPCh. 10 - Prob. 10.69QPCh. 10 - Prob. 10.70QPCh. 10 - Prob. 10.71QPCh. 10 - Prob. 10.72QPCh. 10 - Prob. 10.73QPCh. 10 - Prob. 10.74QPCh. 10 - Prob. 10.75QPCh. 10 - Prob. 10.76QPCh. 10 - For the reaction 2C2H6(g)+7O2(g)4CO2(g)+6H2O(g)...Ch. 10 - Prob. 10.78QPCh. 10 - Prob. 10.79QPCh. 10 - Prob. 10.9VCCh. 10 - Prob. 10.10VCCh. 10 - Prob. 10.11VCCh. 10 - Prob. 10.12VCCh. 10 - Explain how the lattice energy of an ionic...Ch. 10 - Specify which compound in each of the following...Ch. 10 - Prob. 10.82QPCh. 10 - Prob. 10.83QPCh. 10 - Prob. 10.84QPCh. 10 - Prob. 10.85QPCh. 10 - Prob. 10.86QPCh. 10 - Prob. 10.87QPCh. 10 - Hydrazine (N2H4) decomposes according to the...Ch. 10 - Prob. 10.89QPCh. 10 - Prob. 10.90QPCh. 10 - Prob. 10.91QPCh. 10 - Prob. 10.92QPCh. 10 - Prob. 10.93QPCh. 10 - Prob. 10.94QPCh. 10 - You are given the following data....Ch. 10 - Prob. 10.96QPCh. 10 - Prob. 10.97QPCh. 10 - Prob. 10.98QPCh. 10 - Prob. 10.99QPCh. 10 - Compare the heat produced by the complete...Ch. 10 - The so-called hydrogen economy is based on...Ch. 10 - Prob. 10.102QPCh. 10 - Prob. 10.103QPCh. 10 - Prob. 10.104QPCh. 10 - Prob. 10.105QPCh. 10 - Prob. 10.106QPCh. 10 - Prob. 10.107QPCh. 10 - Prob. 10.108QPCh. 10 - A certain gas initially at 0.050 L undergoes...Ch. 10 - Prob. 10.110QPCh. 10 - The first step in the industrial recovery of zinc...Ch. 10 - Calculate the standard enthalpy change for the...Ch. 10 - Portable hot packs are available for skiers and...Ch. 10 - Prob. 10.114QPCh. 10 - Prob. 10.115QPCh. 10 - Prob. 10.116QPCh. 10 - Prob. 10.117QPCh. 10 - Prob. 10.118QPCh. 10 - Prob. 10.119QPCh. 10 - Prob. 10.120QPCh. 10 - Prob. 10.121QPCh. 10 - Prob. 10.122QPCh. 10 - Prob. 10.123QPCh. 10 - Prob. 10.124QPCh. 10 - Prob. 10.125QPCh. 10 - Vinyl chloride (C2H3Cl) differs from ethylene...Ch. 10 - Prob. 10.127QPCh. 10 - Prob. 10.128QPCh. 10 - Prob. 10.129QPCh. 10 - Determine the standard enthalpy of formation of...Ch. 10 - Prob. 10.131QPCh. 10 - Prob. 10.132QPCh. 10 - Prob. 10.133QPCh. 10 - Prob. 10.134QPCh. 10 - Prob. 10.135QPCh. 10 - Prob. 10.136QPCh. 10 - Both glucose and fructose arc simple sugars with...Ch. 10 - About 6.0 1013 kg of CO2 is fixed (converted to...Ch. 10 - Experiments show that it takes 1656 kJ/mol to...Ch. 10 - From a thermochemical point of view, explain why a...Ch. 10 - Prob. 10.141QPCh. 10 - Prob. 10.142QPCh. 10 - Prob. 10.143QPCh. 10 - Prob. 10.144QPCh. 10 - Prob. 10.145QPCh. 10 - Prob. 10.146QPCh. 10 - Prob. 10.147QPCh. 10 - Prob. 10.148QPCh. 10 - A drivers manual states that the stopping distance...Ch. 10 - Prob. 10.150QPCh. 10 - Prob. 10.151QPCh. 10 - Prob. 10.152QPCh. 10 - When 1.034 g of naphthalene (C10H8), is burned in...Ch. 10 - Prob. 10.154QPCh. 10 - A gas company in Massachusetts charges 27 cents...Ch. 10 - Prob. 10.156QPCh. 10 - Prob. 10.157QPCh. 10 - According to information obtained from...Ch. 10 - Using data from Appendix 2, calculate the standard...Ch. 10 - Using data from Appendix 2, calculate the standard...Ch. 10 - Prob. 10.3KSPCh. 10 - Prob. 10.4KSP
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