EBK CHEMISTRY
12th Edition
ISBN: 9780133911312
Author: Timberlake
Publisher: YUZU
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 10 Solutions
EBK CHEMISTRY
Ch. 10.1 - Indicate whether each of the following statements...Ch. 10.1 - Indicate whether each of the following statements...Ch. 10.1 - Prob. 10.3QAPCh. 10.1 - Name each of the following acids or bases: Al(OH)3...Ch. 10.1 - Prob. 10.5QAPCh. 10.1 - Prob. 10.6QAPCh. 10.1 - Identify the reactant that is Bronsted-Lowry acid...Ch. 10.1 - Identify the reactant that is Bronsted-Lowry acid...Ch. 10.1 - Prob. 10.9QAPCh. 10.1 - Prob. 10.10QAP
Ch. 10.1 - Prob. 10.11QAPCh. 10.1 - Prob. 10.12QAPCh. 10.1 - Identify the Bronsted-Lowry acid-base pairs in...Ch. 10.1 - Identify the Bronsted-Lowry acid-base pairs in...Ch. 10.2 - Using TABLE10.3, identify the stronger acid in...Ch. 10.2 - Using TABLE10.3, identify the stronger acid in...Ch. 10.2 - Using TABLE10.3, identify the weaker acid in each...Ch. 10.2 - Using TABLE10.3, identify the weaker acid in each...Ch. 10.3 - What is meant by the term reversible reaction?Ch. 10.3 - When does a reversible reaction reach equilibrium?Ch. 10.3 - Which of the following are at equilibrium? The...Ch. 10.3 - Which of the following are not at equilibrium? The...Ch. 10.3 - Use Le Ch?telier’s principle to predict whether...Ch. 10.3 - Use Le Châtelier’s principle to predict whether...Ch. 10.4 - Why are the concentrations of H3O+and OH- equal in...Ch. 10.4 - Prob. 10.26QAPCh. 10.4 - Prob. 10.27QAPCh. 10.4 - If a base is added to pure water, why does the...Ch. 10.4 - Indicate whether each of the following solutions...Ch. 10.4 - Indicate whether each of the following solutions...Ch. 10.4 - Prob. 10.31QAPCh. 10.4 - Prob. 10.32QAPCh. 10.4 - Calculate the [OH-] of each aqueous solution with...Ch. 10.4 - Prob. 10.34QAPCh. 10.5 - Why does a neutral solution have a pH of 7.0?Ch. 10.5 - If you know the [OH-] , how can you determine the...Ch. 10.5 - State whether each of the following is acidic,...Ch. 10.5 - State whether each of the following is acidic,...Ch. 10.5 - Calculate the pH of each solution given the...Ch. 10.5 - Prob. 10.40QAPCh. 10.5 - Prob. 10.41QAPCh. 10.5 - Prob. 10.42QAPCh. 10.6 - Complete and balance the equation for each of the...Ch. 10.6 - Prob. 10.44QAPCh. 10.6 - Balance each of the following neutralization...Ch. 10.6 - Balance each of the following neutralization...Ch. 10.6 - Write a balanced equation for the neutralization...Ch. 10.6 - Write a balanced equation for the neutralization...Ch. 10.6 - What is the molarity of a solution of HCl if 5.00...Ch. 10.6 - Prob. 10.50QAPCh. 10.6 - If 32.8 mL of a 0.162 M NaOH solution is required...Ch. 10.6 - If 38.2 mL of a 0.163 M KOH solution is required...Ch. 10.7 - Which of the following represents a buffer system?...Ch. 10.7 - Which of the following represents a buffer system?...Ch. 10.7 - Consider the buffer system of hydrofluoric acid,...Ch. 10.7 - Consider the buffer system of nitrous acid, HNO2,...Ch. 10 - Identify each of the following as an acid or a...Ch. 10 - Prob. 10.58UTCCh. 10 - Prob. 10.59UTCCh. 10 - Complete the following table: (10.2) Base...Ch. 10 - State whether each of the following solutions is...Ch. 10 - Prob. 10.62UTCCh. 10 - Prob. 10.63UTCCh. 10 - Adding a few drops of a strong acid to water will...Ch. 10 - Prob. 10.65UTCCh. 10 - Prob. 10.66UTCCh. 10 - Prob. 10.67AQAPCh. 10 - Prob. 10.68AQAPCh. 10 - Using TABLE10.3, identify the stronger acid in...Ch. 10 - Using TABLEIO.3 , identify the weaker acid in each...Ch. 10 - Prob. 10.71AQAPCh. 10 - Prob. 10.72AQAPCh. 10 - Determine the pH for the following solutions:...Ch. 10 - Prob. 10.74AQAPCh. 10 - Prob. 10.75AQAPCh. 10 - Prob. 10.76AQAPCh. 10 - Prob. 10.77AQAPCh. 10 - Calculate the [H3O+] and [OH-] for a solution with...Ch. 10 - Prob. 10.79AQAPCh. 10 - Prob. 10.80AQAPCh. 10 - Prob. 10.81AQAPCh. 10 - Prob. 10.82AQAPCh. 10 - Prob. 10.83AQAPCh. 10 - Calculate the volume, in milliliters, of a 0.2 15...Ch. 10 - Prob. 10.85AQAPCh. 10 - A 1O.O-mL sample of vinegar, which is an aqueous...Ch. 10 - Prob. 10.87CQCh. 10 - Prob. 10.88CQCh. 10 - Prob. 10.89CQCh. 10 - Prob. 10.90CQCh. 10 - Prob. 10.91CQCh. 10 - Prob. 10.92CQCh. 10 - Determine each of the following for a 0.050 M KOH...Ch. 10 - Determine each of the following for a 0.100 M HBr...Ch. 10 - A 0.204 M NaOH solution is used to titrate 50.0 mL...Ch. 10 - A 0.312 M KOH solution is used to titrate 15.0 mL...Ch. 10 - Prob. 10.97CQCh. 10 - Prob. 10.98CQCh. 10 - One of the most acidic lakes in the United States...Ch. 10 - Prob. 10.100CQ
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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