Pearson eText Organic Chemistry -- Instant Access (Pearson+)
Pearson eText Organic Chemistry -- Instant Access (Pearson+)
9th Edition
ISBN: 9780135213728
Author: Leroy Wade, Jan Simek
Publisher: PEARSON+
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Chapter 10.11B, Problem 10.26P

(a)

Interpretation Introduction

To determine: The synthesis of the given alcohol by reducing appropriate carbonyl compound.

Interpretation: The synthesis of the given alcohol by reducing appropriate carbonyl compound is to be shown.

Concept introduction: The synthesis of the primary or secondary alcohols is done by reaction carbonyl compound like carboxylic acid, ketone, aldehyde and ester by reducing agents like LiAlH4 or NaBH4 in the presence of appropriate solvent in the reaction.

LiAlH4 reduces aldehyde, carboxylic acids and esters to primary alcohol, and ketones to secondary alcohol. Sodium borohydride NaBH4 is a selective reducing reagent that reduces aldehyde to primary alcohol, and ketones to secondary alcohol.

(b)

Interpretation Introduction

To determine: The synthesis of the given alcohol by reducing appropriate carbonyl compound.

Interpretation: The synthesis of the given alcohol by reducing appropriate carbonyl compound is to be shown.

Concept introduction: The synthesis of the primary or secondary alcohols is done by reaction carbonyl compound like carboxylic acid, ketone, aldehyde and ester by reducing agents like LiAlH4 or NaBH4 in the presence of appropriate solvent in the reaction.

LiAlH4 reduces aldehyde, carboxylic acids and esters to primary alcohol, and ketones to secondary alcohol. Sodium borohydride NaBH4 is a selective reducing reagent that reduces aldehyde to primary alcohol, and ketones to secondary alcohol.

(c)

Interpretation Introduction

To determine: The synthesis of the given alcohol by reducing appropriate carbonyl compound.

Interpretation: The synthesis of the given alcohol by reducing appropriate carbonyl compound is to be shown.

Concept introduction: The synthesis of the primary or secondary alcohols is done by reaction carbonyl compound like carboxylic acid, ketone, aldehyde and ester by reducing agents like LiAlH4 or NaBH4 in the presence of appropriate solvent in the reaction.

LiAlH4 reduces aldehyde, carboxylic acids and esters to primary alcohol, and ketones to secondary alcohol. Sodium borohydride NaBH4 is a selective reducing reagent that reduces aldehyde to primary alcohol, and ketones to secondary alcohol.

(d)

Interpretation Introduction

To determine: The synthesis of the given alcohol by reducing appropriate carbonyl compound.

Interpretation: The synthesis of the given alcohol by reducing appropriate carbonyl compound is to be shown.

Concept introduction: The synthesis of the primary or secondary alcohols is done by reaction carbonyl compound like carboxylic acid, ketone, aldehyde and ester by reducing agents like LiAlH4 or NaBH4 in the presence of appropriate solvent in the reaction.

LiAlH4 reduces aldehyde, carboxylic acids and esters to primary alcohol, and ketones to secondary alcohol. Sodium borohydride NaBH4 is a selective reducing reagent that reduces aldehyde to primary alcohol, and ketones to secondary alcohol.

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Chapter 10 Solutions

Pearson eText Organic Chemistry -- Instant Access (Pearson+)

Ch. 10.8B - Prob. 10.11PCh. 10.8B - Prob. 10.12PCh. 10.9A - Prob. 10.13PCh. 10.9B - Prob. 10.14PCh. 10.9C - Show how you would synthesize each tertiary...Ch. 10.9D - Prob. 10.16PCh. 10.9D - Show how you would add Grignard reagents to acid...Ch. 10.9D - A formate ester, such as ethyl formate, reacts...Ch. 10.9E - Prob. 10.19PCh. 10.9E - In Section9-7B, we saw how acetylide ions add to...Ch. 10.9F - Prob. 10.21PCh. 10.10A - Prob. 10.22PCh. 10.10B - Prob. 10.23PCh. 10.11B - Predict the products you would expect from the...Ch. 10.11B - Prob. 10.25PCh. 10.11B - Prob. 10.26PCh. 10.12 - Prob. 10.27PCh. 10.12 - Prob. 10.28PCh. 10.12 - Authentic skunk spray has become valuable for use...Ch. 10 - Give a systematic (IUPAC) name for each alcohol....Ch. 10 - Give systematic (IUPAC) names for the following...Ch. 10 - Draw the structures of the following compounds...Ch. 10 - Predict which member of each pair has the higher...Ch. 10 - Predict which member of each pair is more acidic,...Ch. 10 - Predict which member of each group is most soluble...Ch. 10 - Draw the organic products you would expect to...Ch. 10 - Prob. 10.37SPCh. 10 - Show how you would synthesize the following...Ch. 10 - Show how you would use Grignard syntheses to...Ch. 10 - Show how you would accomplish the following...Ch. 10 - Show how you would synthesize the following: a....Ch. 10 - Complete the following acid-base reactions. In...Ch. 10 - Prob. 10.43SPCh. 10 - Prob. 10.44SPCh. 10 - Geminal diols, or 1,1-diols, are usually unstable,...Ch. 10 - Vinyl alcohols are generally unstable, quickly...Ch. 10 - Compound A (C7H11Br) is treated with magnesium in...Ch. 10 - Prob. 10.48SPCh. 10 - Prob. 10.49SPCh. 10 - Prob. 10.50SPCh. 10 - Prob. 10.51SPCh. 10 - Prob. 10.52SPCh. 10 - Prob. 10.53SPCh. 10 - Prob. 10.54SPCh. 10 - Prob. 10.55SPCh. 10 - Prob. 10.56SPCh. 10 - Show how this 1 alcohol can be made from the...Ch. 10 - Prob. 10.58SPCh. 10 - Prob. 10.59SPCh. 10 - Prob. 10.60SP
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