Organic Chemistry
Organic Chemistry
3rd Edition
ISBN: 9781119338352
Author: Klein
Publisher: WILEY
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Chapter 10.10, Problem 8LTS
Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Chiral: Four different atoms attached to a carbon atom is called chiral molecule.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: Two compounds which are non-superimposable mirror image of each other are called as enantiomers.

Diastereomers: Two molecules are considered to be diasteromers if they are non-super imposable and non-mirror image of each other.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer

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Shown below is the mechanism presented for the formation of biasplatin in reference 1 from the Background and Experiment document. The amounts used of each reactant are shown.  Either draw or describe a better alternative to this mechanism. (Note that the first step represents two steps combined and the proton loss is not even shown; fixing these is not the desired improvement.)  (Hints: The first step is correct, the second step is not; and the amount of the anhydride is in large excess to serve a purpose.)
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Draw a reasonable mechanism for the following reaction:
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