The isomer of given molecular formula should be identified. Concept introduction: Isomer: A molecule having same molecular formula with different chemical formula is called isomer. Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer) .

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Answer 1

Question

Chapter 10, Problem 25PP

(a)

Interpretation Introduction

Interpretation:

The isomer of given molecular formula should be identified.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(b)

Interpretation Introduction

Interpretation:

All four mono chlorination products have to be drawn.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Mono-chlorination: The alkyl group reacts with chlorine in presence of photochemical conditions to give mono-chlorinated product.

(c)

Interpretation Introduction

Interpretation:

The predominates product of bromination has to be drawn.

Concept introduction:

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction).

Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

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When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.

When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol. Which experimental number must be initialled by the Lab TA for the first run of Part 1 of the experiment? a) the heat capacity of the calorimeter b) Mass of sample c) Ti d) The molarity of the HCl e) Tf

Predict products for the Following organic rxn/s by writing the structurels of the correct products. Write above the line provided" your answer D2 ①CH3(CH2) 5 CH3 + D₂ (adequate)" + 2 mited) 19 Spark Spark por every item. 4 CH 3 11 3 CH 3 (CH2) 4 C-H + CH3OH CH2 CH3 + CH3 CH2OH 0 CH3 fou + KMnDy→ C43 + 2 KMn Dy→→ C-OH ") 0 C-OH 1110 (4.) 9+3 =C CH3 + HNO 3 0 + Heat> + CH3 C-OH + Heat CH2CH3 - 3 2 + D Heat H 3 CH 3 CH₂ CH₂ C = CH + 2 H₂ → 2 2

Answer 2

Question

Chapter 10, Problem 25PP

(a)

Interpretation Introduction

Interpretation:

The isomer of given molecular formula should be identified.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(b)

Interpretation Introduction

Interpretation:

All four mono chlorination products have to be drawn.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Mono-chlorination: The alkyl group reacts with chlorine in presence of photochemical conditions to give mono-chlorinated product.

(c)

Interpretation Introduction

Interpretation:

The predominates product of bromination has to be drawn.

Concept introduction:

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction).

Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

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Answer 3

Question

Chapter 10, Problem 25PP

(a)

Interpretation Introduction

Interpretation:

The isomer of given molecular formula should be identified.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(b)

Interpretation Introduction

Interpretation:

All four mono chlorination products have to be drawn.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Mono-chlorination: The alkyl group reacts with chlorine in presence of photochemical conditions to give mono-chlorinated product.

(c)

Interpretation Introduction

Interpretation:

The predominates product of bromination has to be drawn.

Concept introduction:

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction).

Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

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Answer 4

Question

Chapter 10, Problem 25PP

(a)

Interpretation Introduction

Interpretation:

The isomer of given molecular formula should be identified.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(b)

Interpretation Introduction

Interpretation:

All four mono chlorination products have to be drawn.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Mono-chlorination: The alkyl group reacts with chlorine in presence of photochemical conditions to give mono-chlorinated product.

(c)

Interpretation Introduction

Interpretation:

The predominates product of bromination has to be drawn.

Concept introduction:

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction).

Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

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Answer 5

Chapter 10, Problem 25PP

(a)

Interpretation Introduction

Interpretation:

The isomer of given molecular formula should be identified.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(b)

Interpretation Introduction

Interpretation:

All four mono chlorination products have to be drawn.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Mono-chlorination: The alkyl group reacts with chlorine in presence of photochemical conditions to give mono-chlorinated product.

(c)

Interpretation Introduction

Interpretation:

The predominates product of bromination has to be drawn.

Concept introduction:

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction).

Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

Answer 6

Chapter 10, Problem 25PP

(a)

Interpretation Introduction

Interpretation:

The isomer of given molecular formula should be identified.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Answer 7

Chapter 10, Problem 25PP

(a)

Interpretation Introduction

Interpretation:

The isomer of given molecular formula should be identified.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Answer 8

(b)

Interpretation Introduction

Interpretation:

All four mono chlorination products have to be drawn.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Mono-chlorination: The alkyl group reacts with chlorine in presence of photochemical conditions to give mono-chlorinated product.

Answer 9

(b)

Interpretation Introduction

Interpretation:

All four mono chlorination products have to be drawn.

Concept introduction:

Isomer: A molecule having same molecular formula with different chemical formula is called isomer.

Mono-chlorination: The alkyl group reacts with chlorine in presence of photochemical conditions to give mono-chlorinated product.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The predominates product of bromination has to be drawn.

Concept introduction:

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction).

Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The predominates product of bromination has to be drawn.

Concept introduction:

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction).

Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

Answer 12

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Answer 14

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Answer 15

Ch. 10.1 - Prob. 1CC Ch. 10.1 - Prob. 1LTS Ch. 10.1 - Prob. 2PTS Ch. 10.1 - Prob. 3PTS Ch. 10.1 - Prob. 4ATS Ch. 10.1 - Prob. 2LTS Ch. 10.1 - Prob. 5PTS Ch. 10.1 - Prob. 6PTS Ch. 10.1 - Prob. 7ATS Ch. 10.2 - Prob. 3LTS

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