Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Chapter 10.1, Problem 4PP
If the available number of valence electrons for a molecule or polyatomic ion does not complete all of the octets in a Lewis structure, what should you do?
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Answer F please
4. Refer to the data below to answer the following questions:
The octapeptide saralasin is a specific antagonist of angiotensin II. A derivative of saralasin is used
therapeutically as an antihypertensive. Amino acid analysis of saralasin show the presence of the
following amino acids:
Ala, Arg, His, Pro, Sar, Tyr, Val, Val
A.Sar is the abbreviation for sarcosine, N-methyl aminoethanoic acid. Draw the structure of sarcosine.
B. N-Terminal analysis by the Edman method shows saralasin contains sarcosine at the N-terminus.
Partial hydrolysis of saralasin with dilute hydrochloric acid yields the following fragments:
Tyr-Val-His
Sar-Arg-Val
His-Pro-Ala
Val-Tyr-Val
Arg-Val-Tyr
What is the structure of saralasin?
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Chapter 10 Solutions
Basic Chemistry
Ch. 10.1 - Determine the total number of valence electrons...Ch. 10.1 - Determine the total number of valence electrons...Ch. 10.1 - Prob. 3PPCh. 10.1 - If the available number of valence electrons for a...Ch. 10.1 - Draw the Lewis structures for each of the...Ch. 10.1 - Draw the Lewis structures for each of the...Ch. 10.1 - Draw the Lewis structures for each of the...Ch. 10.1 - Draw the Lewis structures for each of the...Ch. 10.2 - Prob. 9PPCh. 10.2 - When does a molecular compound have resonance?
Ch. 10.2 - Draw two resonance structures for each of the...Ch. 10.2 - Draw two resonance structures for each of the...Ch. 10.3 - Prob. 13PPCh. 10.3 - Choose the shape (1 to 6) that matches each of the...Ch. 10.3 - Prob. 15PPCh. 10.3 - Prob. 16PPCh. 10.3 - Prob. 17PPCh. 10.3 - Prob. 18PPCh. 10.3 - Use VSEPR theory to predict the shape of each of...Ch. 10.3 - Prob. 20PPCh. 10.3 - Prob. 21PPCh. 10.3 - Draw the Lewis structure and predict the shape for...Ch. 10.4 - Describe the trend in electronegativity as...Ch. 10.4 - Describe the trend in electronegativity as...Ch. 10.4 - Prob. 25PPCh. 10.4 - Which electronegativity difference (a, b, or c)...Ch. 10.4 - Using the periodic table, arrange the atoms in...Ch. 10.4 - Using the periodic table, arrange the atoms in...Ch. 10.4 - Predict whether the bond between each of the...Ch. 10.4 - Predict whether the bond between each of the...Ch. 10.4 - For the bond between each of the following pairs...Ch. 10.4 - For the bond between each of the following pairs...Ch. 10.5 - Why is F2 a nonpolar molecule, but HF is a polar...Ch. 10.5 - Why is CCl4 a nonpolar molecule, but PCl3 is a...Ch. 10.5 - Identify each of the following molecules as polar...Ch. 10.5 - Identify each of the following molecules as polar...Ch. 10.5 - Prob. 37PPCh. 10.5 - Prob. 38PPCh. 10.6 - Prob. 39PPCh. 10.6 - Prob. 40PPCh. 10.6 - Identify the strongest intermolecular forces...Ch. 10.6 - Identify the strongest intermolecular forces...Ch. 10.6 - Prob. 43PPCh. 10.6 - Prob. 44PPCh. 10.7 - Using Figure 10.6, calculate the heat change...Ch. 10.7 - Using Figure 10.6, calculate the heat change...Ch. 10.7 - Prob. 47PPCh. 10.7 - Using Figure 10.6, calculate the heat change...Ch. 10.7 - Using Figure 10.6 and the specific heat of water,...Ch. 10.7 - Using Figure 10.6 and the specific heat of water,...Ch. 10.7 - An ice bag containing 275 g of ice at 0 °C was...Ch. 10.7 - Prob. 52PPCh. 10.7 - Prob. 53PPCh. 10.7 - In the preparation of liquid nitrogen, how many...Ch. 10.7 - Using the electronegativity values in Figure 10.2,...Ch. 10.7 - Prob. 56PPCh. 10.7 - Prob. 57PPCh. 10.7 - a. Draw two resonance structures for bicarbonate...Ch. 10 - State the number of valence electrons, bonding...Ch. 10 - State the number of valence electrons, bonding...Ch. 10 - Prob. 61UTCCh. 10 - Prob. 62UTCCh. 10 - Consider the following bonds: Ca and O, C and O, K...Ch. 10 - Consider the following bonds: F and Cl, Cl and Cl,...Ch. 10 - Identify the major intermolecular forces between...Ch. 10 - Prob. 66UTCCh. 10 - Prob. 67UTCCh. 10 - Prob. 68UTCCh. 10 - Prob. 69UTCCh. 10 - Prob. 70UTCCh. 10 - Prob. 71UTCCh. 10 - Prob. 72UTCCh. 10 - Prob. 73APPCh. 10 - Determine the total number of valence electrons in...Ch. 10 - Draw the Lewis structures for each of the...Ch. 10 - Draw the Lewis structures for each of the...Ch. 10 - Draw resonance structures for each of the...Ch. 10 - Prob. 78APPCh. 10 - Use the periodic table to arrange the following...Ch. 10 - Use the periodic table to arrange the following...Ch. 10 - Select the more polar bond in each of the...Ch. 10 - Select the more polar bond in each of the...Ch. 10 - Show the dipole arrow for each of the following...Ch. 10 - Show the dipole arrow for each of the following...Ch. 10 - Calculate the electronegativity difference and...Ch. 10 - Calculate the electronegativity difference and...Ch. 10 - Prob. 87APPCh. 10 - For each of the following, draw the Lewis...Ch. 10 - For each of the following, draw the Lewis...Ch. 10 - For each of the following, draw the Lewis...Ch. 10 - Prob. 91APPCh. 10 - Predict the shape and polarity of each of the...Ch. 10 - Prob. 93APPCh. 10 - Prob. 94APPCh. 10 - Prob. 95APPCh. 10 - Indicate the major type of intermolecular...Ch. 10 - When it rains or snows, the air temperature seems...Ch. 10 - Prob. 98APPCh. 10 - Using Figure 10.6, calculate the grams of ice that...Ch. 10 - Using Figure 10.6, calculate the grams of ethanol...Ch. 10 - Prob. 101APPCh. 10 - Using Figure 10.6, calculate the grams of benzene...Ch. 10 - Prob. 103CPCh. 10 - Prob. 104CPCh. 10 - Prob. 105CPCh. 10 - Prob. 106CPCh. 10 - Prob. 107CPCh. 10 - The melting point of benzene is 5.5 °C, and its...Ch. 10 - A 45.0-g piece of ice at 0.0 °C is added to a...Ch. 10 - An ice cube at 0 °C with a mass of 115 g is added...Ch. 10 - Prob. 111CPCh. 10 - Prob. 112CPCh. 10 - Prob. 13CICh. 10 - Prob. 14CICh. 10 - Prob. 15CICh. 10 - Ethanol, C2H6O , is obtained from renewable crops...Ch. 10 - Chloral hydrate, a sedative and hypnotic, was the...Ch. 10 - Ethylene glycol, C2H6O2 , used as a coolant and...Ch. 10 - Prob. 19CICh. 10 - Prob. 20CI
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- PLEASE PLEASE PLEASE use hand drawn structures when possarrow_forward. M 1- MATCH each of the following terms to a structure from the list below. There is only one correct structure for each term and structures may be used more than once. Place the letter of the structure in the blank to the left of the corresponding term. A. Sanger dideoxy method C. Watson-Crick B. GAUCGUAAA D. translation E. HOH2C OH OH G. transcription I. AUGGCUGAG 0 K. OPOH2C 0- OH N- H NH2 F. -OPOH2C 0- OH OH H. Maxam-Gilbert method J. replication N L. HOH2C a. b. C. d. e. f. g. B M. AGATCGCTC a pyrimidine nucleoside RNA base sequence with guanine at the 3' end. DNA base sequence with cytosine at the 3' end. a purine nucleoside DNA sequencing method for the human genome 2'-deoxyadenosine 5'-phosphate process by which mRNA directs protein synthesis OH NH2arrow_forwardPlease use hand drawn structures when neededarrow_forward
- B. Classify the following amino acid. Atoms other than carbon and hydrogen are labeled. a. acidic b. basic C. neutral C. Consider the following image. Which level of protein structure is shown here? a. primary b. secondary c. tertiary d. quaternary D. Consider the following image. H RH H HR H R HR HR RH Which level of protein structure is shown in the box? a. primary b. secondary R c. tertiary d. quaternary コー Rarrow_forwardBriefly answer three from the followings: a. What are the four structures of the protein? b. Why is the side chain (R) attached to the alpha carbon in the amino acids is important for the function? c. What are the types of amino acids? And how is it depend on the (R) structure? d. Write a reaction to prepare an amino acid. prodarrow_forwardAnswe Answer A and B pleasearrow_forward
- 3. Refer to the data below to answer the following questions: Isoelectric point Amino Acid Arginine 10.76 Glutamic Acid 3.22 Tryptophan 5.89 A. Define isoelectric point. B. The most basic amino acid is C. The most acidic amino acid is sidizo zoarrow_forward3. A gas mixture contains 50 mol% H2 and 50 mol% He. 1.00-L samples of this gas mixture are mixed with variable volumes of O2 (at 0 °C and 1 atm). A spark is introduced to allow the mixture to undergo complete combustion. The final volume is measured at 0 °C and 1 atm. Which graph best depicts the final volume as a function of the volume of added O2? (A) 2.00 1.75 Final Volume, L 1.50 1.25 1.00 0.75 0.50 0.25 0.00 0.00 0.25 0.50 2.00 (B) 1.75 1.50 Final Volume, L 1.25 1.00 0.75 0.50- 0.25 0.00 0.75 1.00 0.00 0.25 Volume O₂ added, L 2 0.50 0.75 1.00 Volume O₂ added, L 2 2.00 2.00 (C) (D) 1.75 1.75 1.50 1.50 Final Volume, L 1.25 1.00 0.75 0.50 Final Volume, L 1.25 1.00 0.75 0.50 0.25 0.25 0.00 0.00 0.00 0.25 0.50 0.75 1.00 0.00 0.25 Volume O₂ added, L 0.50 0.75 1.00 Volume O₂ added, L 2arrow_forwardLeucine is an essential amino acid with the systematic name 2-amino-3-methylpentanoic acid. It has pai 2.36 and pKa2 = 9.60. H2N-C(R)H-COOH and R is -CH2-CH(CH3)2 A. Draw the condensed structure for leucine, and label all chirality centers with an asterisk. B. How many possible stereoisomers of leucine are there? C. Draw a Fischer projection of L-leucine and label the chirality center(s) as R or S. D. What is the p/ of leucine? E. Draw the structure of the predominant form of leucine at 10.00. F. Draw the structure of the predominant form of leucine at pH = 1.50. G. Leucine is described as an essential amino acid. What does this mean? H. Show the alkyl halide you would use to prepare leucine by the amidomalonate method. =arrow_forward
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