ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.)
ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.)
4th Edition
ISBN: 9781119761068
Author: Klein
Publisher: WILEY
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Chapter 10.1, Problem 10.2P
Interpretation Introduction

Interpretation:

Major product has to be predicted for the given reaction.

ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.), Chapter 10.1, Problem 10.2P , additional homework tip  1

Concept Introduction:

Diels-Alder reaction is the 4+2 addition reaction.  In other words it is the reaction between a diene and a dienophile.  Here a total of six pi bonds are involved resulting in formation of one pi bond and two single bonds.  Diels-Alder reaction occurs via a single concerted step and not by involvement of ions.  If a monosubstituted ethylene is used, the product obtained contains a stereocenter.  This can be represented as,

ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.), Chapter 10.1, Problem 10.2P , additional homework tip  2

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