INTRO TO CHEMISTRY EBK ACCESS CARD >I<
5th Edition
ISBN: 9781260916430
Author: BAUER
Publisher: MCG
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Question
Chapter 10, Problem 71QP
Interpretation Introduction
Interpretation:
The explanation for the difference in the boiling points for
Concept Introduction:
The boiling point of a substance depends on the strength of the intermolecular forces present in the substance. An increase in the strength of the intermolecular forces increases the boiling point of substances. Nonpolar molecules have only London dispersion force whereas polar molecules might have both dipole-dipole force and hydrogen bonding force.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 10 Solutions
INTRO TO CHEMISTRY EBK ACCESS CARD >I<
Ch. 10 - How do the properties of liquids and solid differ,...Ch. 10 - Prob. 2QCCh. 10 - Prob. 3QCCh. 10 - Prob. 4QCCh. 10 - Prob. 1PPCh. 10 - Prob. 2PPCh. 10 - Prob. 3PPCh. 10 - Prob. 4PPCh. 10 - Which has the stronger London dispersion forces,...Ch. 10 - Prob. 6PP
Ch. 10 - Prob. 7PPCh. 10 - Prob. 8PPCh. 10 - Prob. 9PPCh. 10 - Prob. 10PPCh. 10 - Prob. 11PPCh. 10 - Prob. 12PPCh. 10 - Prob. 13PPCh. 10 - Prob. 14PPCh. 10 - Prob. 15PPCh. 10 - Prob. 1QPCh. 10 - Match the key terms with the description provided....Ch. 10 - Prob. 3QPCh. 10 - Prob. 4QPCh. 10 - Prob. 5QPCh. 10 - Prob. 6QPCh. 10 - Prob. 7QPCh. 10 - Prob. 8QPCh. 10 - Prob. 9QPCh. 10 - Prob. 10QPCh. 10 - Prob. 11QPCh. 10 - Prob. 12QPCh. 10 - Prob. 13QPCh. 10 - Prob. 14QPCh. 10 - Prob. 15QPCh. 10 - Prob. 16QPCh. 10 - Prob. 17QPCh. 10 - Prob. 18QPCh. 10 - Prob. 19QPCh. 10 - Prob. 20QPCh. 10 - Prob. 21QPCh. 10 - Prob. 22QPCh. 10 - Prob. 23QPCh. 10 - Prob. 24QPCh. 10 - Prob. 25QPCh. 10 - Prob. 26QPCh. 10 - Prob. 27QPCh. 10 - Prob. 28QPCh. 10 - Prob. 29QPCh. 10 - Prob. 30QPCh. 10 - Prob. 31QPCh. 10 - Prob. 32QPCh. 10 - Prob. 33QPCh. 10 - Prob. 34QPCh. 10 - Calculate the amount of heat required when 15.0 g...Ch. 10 - What is the amount of heat required to convert 105...Ch. 10 - Calculate the heat absorbed when 542 g of ice at...Ch. 10 - Prob. 38QPCh. 10 - Prob. 39QPCh. 10 - Calculated the heat released when 84.6 g of...Ch. 10 - Prob. 41QPCh. 10 - Prob. 42QPCh. 10 - Prob. 43QPCh. 10 - Prob. 44QPCh. 10 - Prob. 45QPCh. 10 - Prob. 46QPCh. 10 - Prob. 47QPCh. 10 - Prob. 48QPCh. 10 - Prob. 49QPCh. 10 - Prob. 50QPCh. 10 - Prob. 51QPCh. 10 - Prob. 52QPCh. 10 - Prob. 53QPCh. 10 - Prob. 54QPCh. 10 - Prob. 55QPCh. 10 - Prob. 56QPCh. 10 - Prob. 57QPCh. 10 - Prob. 58QPCh. 10 - Prob. 59QPCh. 10 - Prob. 60QPCh. 10 - Prob. 61QPCh. 10 - Prob. 62QPCh. 10 - Prob. 63QPCh. 10 - Prob. 64QPCh. 10 - Prob. 65QPCh. 10 - Prob. 66QPCh. 10 - Prob. 67QPCh. 10 - Prob. 68QPCh. 10 - Prob. 69QPCh. 10 - Prob. 70QPCh. 10 - Prob. 71QPCh. 10 - Prob. 72QPCh. 10 - Prob. 73QPCh. 10 - Prob. 74QPCh. 10 - Prob. 75QPCh. 10 - Prob. 76QPCh. 10 - Prob. 77QPCh. 10 - Prob. 78QPCh. 10 - Prob. 79QPCh. 10 - Prob. 80QPCh. 10 - Prob. 81QPCh. 10 - Prob. 82QPCh. 10 - Prob. 83QPCh. 10 - Prob. 84QPCh. 10 - Prob. 85QPCh. 10 - Prob. 86QPCh. 10 - Prob. 87QPCh. 10 - Prob. 88QPCh. 10 - Prob. 89QPCh. 10 - Prob. 90QPCh. 10 - Prob. 91QPCh. 10 - Prob. 92QPCh. 10 - Prob. 93QPCh. 10 - Prob. 94QPCh. 10 - Prob. 95QPCh. 10 - Prob. 96QPCh. 10 - Prob. 97QPCh. 10 - Prob. 98QPCh. 10 - Prob. 99QPCh. 10 - Prob. 100QPCh. 10 - Prob. 101QPCh. 10 - Prob. 102QPCh. 10 - Prob. 103QPCh. 10 - Prob. 104QPCh. 10 - Prob. 105QPCh. 10 - Prob. 106QPCh. 10 - Prob. 107QPCh. 10 - Prob. 108QPCh. 10 - Prob. 109QPCh. 10 - Prob. 110QPCh. 10 - Prob. 111QPCh. 10 - Prob. 112QPCh. 10 - Prob. 113QPCh. 10 - Prob. 114QPCh. 10 - Prob. 115QPCh. 10 - Prob. 116QPCh. 10 - Prob. 117QPCh. 10 - Prob. 118QPCh. 10 - Prob. 119QPCh. 10 - Prob. 120QPCh. 10 - Prob. 121QPCh. 10 - Prob. 122QPCh. 10 - Prob. 123QPCh. 10 - Prob. 124QPCh. 10 - Prob. 125QPCh. 10 - Prob. 126QPCh. 10 - Prob. 127QPCh. 10 - Prob. 128QPCh. 10 - Prob. 129QPCh. 10 - Prob. 130QPCh. 10 - Prob. 131QPCh. 10 - Prob. 132QPCh. 10 - Prob. 133QPCh. 10 - Prob. 134QPCh. 10 - Prob. 135QPCh. 10 - Prob. 136QPCh. 10 - Prob. 137QPCh. 10 - Prob. 138QPCh. 10 - Prob. 139QPCh. 10 - Prob. 140QPCh. 10 - Prob. 141QPCh. 10 - Prob. 142QPCh. 10 - Prob. 143QPCh. 10 - Prob. 144QPCh. 10 - Prob. 145QPCh. 10 - Prob. 146QPCh. 10 - Prob. 147QPCh. 10 - Prob. 148QPCh. 10 - Prob. 149QPCh. 10 - Prob. 150QPCh. 10 - Prob. 151QPCh. 10 - Prob. 152QPCh. 10 - Prob. 153QPCh. 10 - Prob. 154QP
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