EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
6th Edition
ISBN: 9780100547506
Author: CRACOLICE
Publisher: YUZU
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Textbook Question
Chapter 10, Problem 70E
Classify each of the following statements as true or false:
a) Coefficients in a chemical equation express the molar proportions among both reactants and products.
b) A stoichiometry problem can be solved with an unbalanced equation.
c) In solving a stoichiometry problem, the change from quantity of given substance to quantity of wanted substance is based on masses.
d) Percentage yield is actual yield expressed as a percentage of ideal yield.
e) The quantity of product of any reaction can be calculated only through the moles of the limiting reactant.
f)
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
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The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 10 Solutions
EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
Ch. 10 - The first step in the Ostwald process for...Ch. 10 - When hydrogen sulfide reacts with oxygen, water...Ch. 10 - Magnesium hydroxide is formed from the reaction of...Ch. 10 - In our bodies, sugar is broken down by reacting...Ch. 10 - Prob. 5ECh. 10 - Aqueous solutions of potassium hydrogen sulfate...Ch. 10 - The first step in the Ostwald process for...Ch. 10 - Butane, C4H10 is a common fuel used for heating...Ch. 10 - The explosion of nitroglycerine is described by...Ch. 10 - According to the reaction 2AgNO3+CuCu(NO3)2+2Ag,...
Ch. 10 - Prob. 11ECh. 10 - Prob. 12ECh. 10 - Prob. 13ECh. 10 - Prob. 14ECh. 10 - The hard water scum that forms a ring around the...Ch. 10 - Prob. 16ECh. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - The Solvay process is multistep industrial method...Ch. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - What mass of NaHCO3 must decompose to produce 448g...Ch. 10 - Prob. 23ECh. 10 - Solid ammonium chloride decomposes to form ammonia...Ch. 10 - What mass of magnesium hydroxide will precipitate...Ch. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - The reaction of a dry cell battery may be...Ch. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - Calcium cyanamide is a common fertilizer. When...Ch. 10 - Prob. 34ECh. 10 - The Haber process for making ammonia from nitrogen...Ch. 10 - Prob. 36ECh. 10 - Prob. 37ECh. 10 - The simplest example of the hydrogenation of a...Ch. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Ammonia can be formed from a combination reaction...Ch. 10 - Carbon monoxide reacts with oxygen to form carbon...Ch. 10 - An experiment is conducted in which varying...Ch. 10 - The flasks below illustrated three trials of a...Ch. 10 - A solution containing 1.63g of barium chloride is...Ch. 10 - Prob. 46ECh. 10 - Prob. 47ECh. 10 - Prob. 48ECh. 10 - A mixture of tetraphosphorus trisulfide and...Ch. 10 - Sodium carbonate can neutralize nitric acid by the...Ch. 10 - Prob. 51ECh. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Prob. 54ECh. 10 - Prob. 55ECh. 10 - Prob. 56ECh. 10 - Prob. 57ECh. 10 - Prob. 58ECh. 10 - Prob. 59ECh. 10 - Prob. 60ECh. 10 - Question 57 through 62: Thermochemical equations...Ch. 10 - Prob. 62ECh. 10 - Quicklime, the common name for calcium oxide, CaO,...Ch. 10 - What mass in grams of hydrogen has to react to...Ch. 10 - The quicklime produced in Question 63 is...Ch. 10 - Prob. 66ECh. 10 - What mass in grams of octane, a component of...Ch. 10 - Calculate the quantity of energy (kJ) transferred...Ch. 10 - Prob. 69ECh. 10 - Classify each of the following statements as true...Ch. 10 - Prob. 71ECh. 10 - What mass in grams of calcium phosphate will...Ch. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - A laboratory test of 12.8g of aluminum ore yields...Ch. 10 - How much energy is required to decompose 1.42g of...Ch. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - A sludge containing silver chloride is a water...Ch. 10 - Prob. 80ECh. 10 - Prob. 81ECh. 10 - Prob. 82ECh. 10 - Prob. 83ECh. 10 - Prob. 84ECh. 10 - In 1866, a young chemistry student conceived the...Ch. 10 - Prob. 86ECh. 10 - A student was given a 1.6240-g sample of a mixture...Ch. 10 - A researcher dissolved 1.382g of impure copper in...Ch. 10 - What mass in grams of magnesium nitrate, Mg(NO3)2,...Ch. 10 - Prob. 90ECh. 10 - Prob. 10.1TCCh. 10 - Solutions of zinc bromide and sodium hydroxide are...Ch. 10 - Prob. 2PECh. 10 - Prob. 3PECh. 10 - How mass of fluorine is formed when 3.0grams of...Ch. 10 - Prob. 5PECh. 10 - Prob. 6PECh. 10 - Prob. 7PECh. 10 - Prob. 8PECh. 10 - Prob. 9PECh. 10 - A solution containing 43.5g of calcium nitrate is...Ch. 10 - Prob. 11PECh. 10 - Prob. 12PECh. 10 - Prob. 13PECh. 10 - Prob. 14PECh. 10 - Prob. 15PECh. 10 - Prob. 1PCECh. 10 - Prob. 2PCECh. 10 - Prob. 3PCECh. 10 - Prob. 4PCECh. 10 - Prob. 5PCECh. 10 - Prob. 6PCECh. 10 - Eight problem-classification examples follow. Test...Ch. 10 - Prob. 8PCE
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
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