Zinc metal reacts with hydrochloric acid according to the balanced equation: Zn ( s ) + 2 HCl ( aq ) → ZnCl 2 ( aq ) +H 2 ( g ) When 0.103 g of Zn(s) is combined with enough HCI to make 50.0 mL of solution in a coffee-cup calorimeter, all of the zinc reacts, raising the temperature of the solution from 22.5 °C to 23.7 °C. Find Δ H rxn for this reaction as written. (Use 1.0 g/mL for the density of the solution and 4.18 J/g °C as the specific heat capacity.)
Zinc metal reacts with hydrochloric acid according to the balanced equation: Zn ( s ) + 2 HCl ( aq ) → ZnCl 2 ( aq ) +H 2 ( g ) When 0.103 g of Zn(s) is combined with enough HCI to make 50.0 mL of solution in a coffee-cup calorimeter, all of the zinc reacts, raising the temperature of the solution from 22.5 °C to 23.7 °C. Find Δ H rxn for this reaction as written. (Use 1.0 g/mL for the density of the solution and 4.18 J/g °C as the specific heat capacity.)
Solution Summary: The author calculates the enthalpy change of a reaction by applying the law of conservation of energy.
Zinc metal reacts with hydrochloric acid according to the balanced equation:
Zn
(
s
)
+ 2 HCl
(
aq
)
→
ZnCl
2
(
aq
)
+H
2
(
g
)
When 0.103 g of Zn(s) is combined with enough HCI to make 50.0 mL of solution in a coffee-cup calorimeter, all of the zinc reacts, raising the temperature of the solution from 22.5 °C to 23.7 °C. Find
Δ
H
rxn
for this reaction as written. (Use 1.0 g/mL for the density of the solution and 4.18 J/g °C as the specific heat capacity.)
What are the IUPAC Names of all the compounds in the picture?
1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following
compounds. Please show your work. (8) SF2, CH,OH, C₂H₂
b) Based on your answers given above, list the compounds in order of their Boiling Point
from low to high. (8)
19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Chapter 10 Solutions
Chemistry: Structure and Properties Plus MasteringChemistry with eText -- Access Card Package
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