Connect Online Access 1-Semester for Organic Chemistry

6th Edition

ISBN: 9781260475609

Author: SMITH, Janice

Publisher: Mcgraw-hill Higher Education (us)

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Textbook Question

Chapter 10, Problem 62P

Bromoetherification, the addition of the elements of Br and OR to a double bond, is a common method for

constructing rings containing oxygen atoms. This reaction has been used in the synthesis of the polyether

antibiotic monensin (Problem 21.37). Draw a stepwise mechanism for the following intramolecular

bromoetherification reaction.

Chapter 10, Problem 62P, Bromoetherification, the addition of the elements of Br and OR to a double bond, is a common method

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Chapter 10, Problem 61P

Chapter 10, Problem 63P

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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

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Chapter 10 Solutions

Connect Online Access 1-Semester for Organic Chemistry

Ch. 10.1 - Prob. 1P Ch. 10.2 - Problem 10.2 How many degrees of unsaturation are...Ch. 10.3 - Give the IUPAC name for each alkene. abcde Ch. 10.3 - Give the IUPAC name for each polyfunctional...Ch. 10.3 - Prob. 9P Ch. 10.6 - Linolenic acidTable 10.2 and stearidonic acid are...Ch. 10.7 - Prob. 12P Ch. 10.9 - Problem 10.13 What product is formed when each...Ch. 10.9 - Prob. 14P Ch. 10.10 - Problem 10.15 Draw the products formed when each...

Ch. 10.10 - Prob. 16P Ch. 10.10 - Prob. 17P Ch. 10.10 - Addition of HBr to which of the following alkenes...Ch. 10.11 - Problem 10.19 Draw the products, including...Ch. 10.11 - Prob. 20P Ch. 10.12 - Problem 10.21 What two alkenes give rise to each...Ch. 10.12 - Prob. 22P Ch. 10.13 - Problem 10.23 Draw the products of each reaction,...Ch. 10.14 - Problem 10.24 Draw all stereoisomers formed in...Ch. 10.15 - Prob. 25P Ch. 10.16 - Problem 10.26 What alkylborane is formed from...Ch. 10.16 - Draw the products formed when each alkene is...Ch. 10.16 - What alkene can be used to prepare each alcohol as...Ch. 10.16 - Prob. 29P Ch. 10.17 - Draw the products of each reaction using the two...Ch. 10.18 - Problem 10.31 Devise a synthesis of each compound...Ch. 10 - Give the IUPAC name for each compound. a.b.Ch. 10 - a Label the carbon-carbon double bond in A as E or...Ch. 10 - Prob. 34P Ch. 10 - 10.35 Calculate the number of degrees of...Ch. 10 - Prob. 36P Ch. 10 - Label the alkene in each drug as E or Z....Ch. 10 - Give the IUPAC name for each compound. a. c. e. b....Ch. 10 - Prob. 39P Ch. 10 - 10.40 (a) Draw all possible stereoisomers of, and...Ch. 10 - Prob. 41P Ch. 10 - 10.42 Now that you have learned how to name...Ch. 10 - Prob. 43P Ch. 10 - Prob. 44P Ch. 10 - Prob. 45P Ch. 10 - Draw the products formed when (CH3)2C=CH2 is...Ch. 10 - What alkene can be used to prepare each alkyl...Ch. 10 - Prob. 48P Ch. 10 - Draw the constitutional isomer formed in each...Ch. 10 - Prob. 50P Ch. 10 - Draw all stereoisomers formed in each reaction. a....Ch. 10 - Draw the products of each reaction, including...Ch. 10 - Prob. 53P Ch. 10 - Draw a stepwise mechanism that shows how all three...Ch. 10 - Less stable alkenes can be isomerized to more...Ch. 10 - Prob. 60P Ch. 10 - Prob. 61P Ch. 10 - Bromoetherification, the addition of the elements...Ch. 10 - Devise a synthesis of each product from the given...Ch. 10 - 10.65 Draw a synthesis of each compound from...

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Solution Summary: The author explains the mechanism for the formation of intramolecular bromoetherification reaction.

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