Foundations of College Chemistry 15e Binder Ready Version + WileyPLUS Registration Card
15th Edition
ISBN: 9781119231318
Author: Morris Hein
Publisher: Wiley (WileyPLUS Products)
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Chapter 10, Problem 46PE
Interpretation Introduction
Interpretation:
The period and group number in which the d orbital appears first has to be given.
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 10 Solutions
Foundations of College Chemistry 15e Binder Ready Version + WileyPLUS Registration Card
Ch. 10.1 - Prob. 10.1PCh. 10.2 - Prob. 10.2PCh. 10.3 - Prob. 10.3PCh. 10.4 - Prob. 10.4PCh. 10.5 - Prob. 10.5PCh. 10.5 - Prob. 10.6PCh. 10.5 - Prob. 10.7PCh. 10 - Prob. 1RQCh. 10 - Prob. 2RQCh. 10 - Prob. 3RQ
Ch. 10 - Prob. 4RQCh. 10 - Prob. 5RQCh. 10 - Prob. 6RQCh. 10 - Prob. 7RQCh. 10 - Prob. 8RQCh. 10 - Prob. 9RQCh. 10 - Prob. 10RQCh. 10 - Prob. 11RQCh. 10 - Prob. 12RQCh. 10 - Prob. 13RQCh. 10 - Prob. 14RQCh. 10 - Prob. 15RQCh. 10 - Prob. 16RQCh. 10 - Prob. 17RQCh. 10 - Prob. 18RQCh. 10 - Prob. 19RQCh. 10 - Prob. 20RQCh. 10 - Prob. 21RQCh. 10 - Prob. 22RQCh. 10 - Prob. 23RQCh. 10 - Prob. 24RQCh. 10 - Prob. 25RQCh. 10 - Prob. 1PECh. 10 - Prob. 2PECh. 10 - Prob. 3PECh. 10 - Prob. 4PECh. 10 - Prob. 5PECh. 10 - Prob. 6PECh. 10 - Prob. 7PECh. 10 - Prob. 8PECh. 10 - Prob. 9PECh. 10 - Prob. 10PECh. 10 - Prob. 11PECh. 10 - Prob. 12PECh. 10 - Prob. 13PECh. 10 - Prob. 14PECh. 10 - Prob. 15PECh. 10 - Prob. 16PECh. 10 - Prob. 17PECh. 10 - Prob. 18PECh. 10 - Prob. 19PECh. 10 - Prob. 20PECh. 10 - Prob. 21PECh. 10 - Prob. 22PECh. 10 - Prob. 23PECh. 10 - Prob. 24PECh. 10 - Prob. 25PECh. 10 - Prob. 26PECh. 10 - Prob. 27PECh. 10 - Prob. 28PECh. 10 - Prob. 29PECh. 10 - Prob. 30PECh. 10 - Prob. 31PECh. 10 - Prob. 32PECh. 10 - Prob. 33PECh. 10 - Prob. 34PECh. 10 - Prob. 35PECh. 10 - Prob. 36PECh. 10 - Prob. 37PECh. 10 - Prob. 38PECh. 10 - Prob. 39PECh. 10 - Prob. 40PECh. 10 - Prob. 41PECh. 10 - Prob. 42PECh. 10 - Prob. 43PECh. 10 - Prob. 44PECh. 10 - Prob. 45PECh. 10 - Prob. 46PECh. 10 - Prob. 47PECh. 10 - Prob. 48PECh. 10 - Prob. 49PECh. 10 - Prob. 50PECh. 10 - Prob. 51AECh. 10 - Prob. 52AECh. 10 - Prob. 53AECh. 10 - Prob. 54AECh. 10 - Prob. 57AECh. 10 - Prob. 58AECh. 10 - Prob. 59AECh. 10 - Prob. 60AECh. 10 - Prob. 61AECh. 10 - Prob. 62AECh. 10 - Prob. 63AECh. 10 - Prob. 64AECh. 10 - Prob. 65AECh. 10 - Prob. 66AECh. 10 - Prob. 67AECh. 10 - Prob. 68AECh. 10 - Prob. 69AECh. 10 - Prob. 70AECh. 10 - Prob. 71AECh. 10 - Prob. 72AECh. 10 - Prob. 73AECh. 10 - Prob. 74AECh. 10 - Prob. 75AECh. 10 - Prob. 76AECh. 10 - Prob. 77AECh. 10 - Prob. 78CECh. 10 - Prob. 79CECh. 10 - Prob. 80CECh. 10 - Prob. 81CECh. 10 - Prob. 82CE
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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