Interpret and match the given potential map with HOCl, FOCl and HOF molecules. Concept introduction: The electrostatic potential map is the representation of the atoms present in a molecule carrying partial positive or negative charges on them. The atom carrying higher positive or negative charges are shown with the darker color in the potential map. The intensity of the color in the potential map is the indication of the amount of charge the atom carrying on it. For example; the electrostatic potential map for chloromethane is shown as: The color code for the atom present in a given molecule carrying higher positive charge is violet or dark blue while the color code for the atom present carrying higher negative charge is orange.
Interpret and match the given potential map with HOCl, FOCl and HOF molecules. Concept introduction: The electrostatic potential map is the representation of the atoms present in a molecule carrying partial positive or negative charges on them. The atom carrying higher positive or negative charges are shown with the darker color in the potential map. The intensity of the color in the potential map is the indication of the amount of charge the atom carrying on it. For example; the electrostatic potential map for chloromethane is shown as: The color code for the atom present in a given molecule carrying higher positive charge is violet or dark blue while the color code for the atom present carrying higher negative charge is orange.
Solution Summary: The author explains that the electrostatic potential map is the representation of the atoms present in a molecule carrying partial positive or negative charges.
Interpret and match the given potential map with HOCl, FOCl and HOF molecules.
Concept introduction:
The electrostatic potential map is the representation of the atoms present in a molecule carrying partial positive or negative charges on them. The atom carrying higher positive or negative charges are shown with the darker color in the potential map. The intensity of the color in the potential map is the indication of the amount of charge the atom carrying on it. For example; the electrostatic potential map for chloromethane is shown as:
The color code for the atom present in a given molecule carrying higher positive charge is violet or dark blue while the color code for the atom present carrying higher negative charge is orange.
Consider the reaction of a propanoate ester with hydroxide ion shown below. A
series of four alcohol leaving groups were tested to determine which would be the
best leaving group.
Based on the pKa values of the alcohols, predict which alcohol would produce the
fastest hydrolysis reaction.
HO
FOR
A
Alcohol I, pKa =16.0
B
Alcohol II, pKa =10.0
C
Alcohol III, pKa = 7.2
+ ROH
D
Alcohol IV, pKa = 6.6
Curved arrows are used to illustrate the flow of electrons. Using
the provided starting and product structures, draw the curved
electron-pushing arrows for the following reaction or
mechanistic step(s).
Be sure to account for all bond-breaking and bond-making
steps.
:0:
NaOH, H₂O
00:4
Na O
heat
NaO
Select to Add Arrows
Select to Add Arrows
:0:
Na
a
NaOH, H2O
:0:
NaOH,
H2O
heat
heat
Na
ONH
Select to Add Arrows
Curved arrows are used to illustrate the flow of electrons. Using
the provided starting and product structures, draw the curved
electron-pushing arrows for the following reaction or
mechanistic step(s).
Be sure to account for all bond-breaking and bond-making
steps.
H
CH3NH3+
:0:
:0:
HO
CH3NH2
HH
iSelect to Add Arrows i
Select to Add Arrows i
HH
CH3NH3+
CH3NH2
Select to Add Arrows i
CH3NH3
CH3NH2
ايكدا
HH
Select to Add Arrows
Chapter 10 Solutions
General Chemistry: Principles and Modern Applications, Loose Leaf Version (11th Edition)
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INTRODUCTION TO MOLECULAR QUANTUM MECHANICS -Valence bond theory - 1; Author: AGK Chemistry;https://www.youtube.com/watch?v=U8kPBPqDIwM;License: Standard YouTube License, CC-BY