Organic Chemistry
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 10, Problem 37PP

(a)

Interpretation Introduction

Interpretation:

The different alkene, alkane products formed for each given substrates when treated with a different reducing reagents are needed to be find out.

Concept Introduction:

Hydrogenation reaction: The hydrogenation is a reduction reaction which results in an addition of hydrogen. Several organic compounds is hydrogenated, it becomes more saturated.

Metal reduction reaction: The alkenes can be reduced to alkanes with H2 in the presence of metal catalyst (Pt). The two new C-H σ bonds are formed simultaneously from H atoms absorbed into the metal surface. This type of reaction stereospecific giving only the cis (syn) addition product.

Linder’s catalyst: The alkyne reduced to alkenes to give the cis (Z) alkene.

Metal and ammonia reaction: The alkyne involves sodium (Na)/NH3 . This end up reducing to alkyne to give the trans (E) alkene.

(b)

Interpretation Introduction

Interpretation:

The different alkene, alkane products formed for each given substrates when treated with a different reducing reagents are needed to be find out.

Concept Introduction:

Hydrogenation reaction: The hydrogenation is a reduction reaction which results in an addition of hydrogen. Several organic compounds is hydrogenated, it becomes more saturated.

Metal reduction reaction: The alkenes can be reduced to alkanes with H2 in the presence of metal catalyst (Pt). The two new C-H σ bonds are formed simultaneously from H atoms absorbed into the metal surface. This type of reaction stereospecific giving only the cis (syn) addition product.

Linder’s catalyst: The alkyne reduced to alkenes to give the cis (Z) alkene.

Metal and ammonia reaction: The alkyne involves sodium (Na)/NH3 . This end up reducing to alkyne to give the trans (E) alkene.

(c)

Interpretation Introduction

Interpretation:

The different alkene, alkane products formed for each given substrates when treated with a different reducing reagents are needed to be find out.

Concept Introduction:

Hydrogenation reaction: The hydrogenation is a reduction reaction which results in an addition of hydrogen. Several organic compounds is hydrogenated, it becomes more saturated.

Metal reduction reaction: The alkenes can be reduced to alkanes with H2 in the presence of metal catalyst (Pt). The two new C-H σ bonds are formed simultaneously from H atoms absorbed into the metal surface. This type of reaction stereospecific giving only the cis (syn) addition product.

Linder’s catalyst: The alkyne reduced to alkenes to give the cis (Z) alkene.

Metal and ammonia reaction: The alkyne involves sodium (Na)/NH3 . This end up reducing to alkyne to give the trans (E) alkene.

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Organic Chemistry

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