Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Textbook Question
Chapter 10, Problem 26P
Hypofluorous acid (HOF) is the simplest possible compound that allows comparison between fluorine and oxygenin their abilities to form hydrogen bonds. AlthoughF attracts electrons more strongly than O, solid HOFunexpectedly contains no
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a. Determine the electrochemical potential of the following cell using
E°Mg2+/Mg = -2.362 V.
Mg | Mg2+ (a=104) || H* (a = 4) | H2 (p
= 0.5 bar) | Pt
b. A galvanic chain consists of Co²+ / Co and Ag+ / Ag half-cells with
EºCo²+/Co = -0.282 V and Eº Ag+/Ag = 0.799 V. Determine which half-cell will be
reduced and which one will be oxidised. Furthermore, calculate the electrochemical
potential as well as the equilibrium constant of the whole cell at
i. [Co²+] = 0.1 M and [Ag+] = 0.5 M
ii. [Co²+] = 0.001 M and [Ag*] = 1.5 M
The equilibrium voltage of the following cell has been measured at 0.522 V at 25 °C.
Pt | H2, g❘ HClaq || AgClaq | Ags
State the redox reactions present in this cell. Calculate the pH value of the electrolyte
solution with KL, AgCl = 1.96 · 10-10 mol² / L². Assume that the concentrations of H+ and
Clare equal.
Here are the energies (in kcal/mol) for staggered and eclipsed interactions
for CH, CC, and CBr bonds
eclipsed (0°) staggered (60°)
bonds
CH/CH
1.0
0.0
CH/CC
1.3
0.0
Br:
CC/CC
3.0
0.9
Br
CH/CBr
1.8
0.0
CC / CBr
3.3
1.0
CBr / CBr
3.7
1.2
a) I've drawn the Newman projection for one of the staggered conformations of the molecule
above, looking down the C2-C3 bond. Draw Newman projections for the other two staggered
and the three eclipsed conformations (in order).
CH₂
H3C.
H'
H
Br
b) Calculate the relative energies for each of the conformations and write them below each
conformation.
Chapter 10 Solutions
Principles of Modern Chemistry
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