MASTERING CHEMISTY NVCC ACCESS CODE
MASTERING CHEMISTY NVCC ACCESS CODE
1st Edition
ISBN: 9780136444459
Author: Tro
Publisher: PEARSON
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Chapter 10, Problem 16E
Interpretation Introduction

To determine: Partial pressure and its relation with total pressure of gas in sample.

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Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400
• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak

Chapter 10 Solutions

MASTERING CHEMISTY NVCC ACCESS CODE

Ch. 10 - Prob. 11ECh. 10 - Prob. 12ECh. 10 - Prob. 13ECh. 10 - Prob. 14ECh. 10 - Prob. 15ECh. 10 - Prob. 16ECh. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - Prob. 19ECh. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - Prob. 22ECh. 10 - If a reaction occurs in the gas phase at STP, the...Ch. 10 - Prob. 24ECh. 10 - Prob. 25ECh. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - A 48.3-mL sample of gas in a cylinder is warmed...Ch. 10 - A syringe containing 1.55 mL of oxygen gas is...Ch. 10 - A balloon contains 0.158 mol of gas and has a...Ch. 10 - Prob. 36ECh. 10 - Prob. 37ECh. 10 - Prob. 38ECh. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - Prob. 44ECh. 10 - Prob. 45ECh. 10 - Prob. 46ECh. 10 - A wine-dispensing system uses argon canisters to...Ch. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - Aerosol cans carry clear warnings against...Ch. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Use the molar volume of a gas at STP to calculate...Ch. 10 - What is the density (in g/L) of hydrogen gas at...Ch. 10 - Prob. 56ECh. 10 - Prob. 57ECh. 10 - A 113-mL gas sample has a mass of 0.171 g at a...Ch. 10 - A sample of gas has a mass of 38.8 mg. Its volume...Ch. 10 - Prob. 60ECh. 10 - A gas mixture contains each of these gases at the...Ch. 10 - A gas mixture with a total pressure of 745 mmHg...Ch. 10 - We add a 1.20-g sample of dry ice to a 755-mL...Ch. 10 - A 275-mL flask contains pure helium at a pressure...Ch. 10 - A gas mixture contains 1.25 g N2 and 0.85 g O2 in...Ch. 10 - Prob. 66ECh. 10 - The hydrogen gas formed in a chemical reaction is...Ch. 10 - Prob. 68ECh. 10 - Prob. 69ECh. 10 - Prob. 70ECh. 10 - Prob. 71ECh. 10 - Prob. 72ECh. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - Prob. 75ECh. 10 - Prob. 76ECh. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - Prob. 79ECh. 10 - Prob. 80ECh. 10 - Prob. 81ECh. 10 - Prob. 82ECh. 10 - CH3OH can be synthesized by the reaction:...Ch. 10 - Oxygen gas reacts with powered aluminum according...Ch. 10 - Automobile airbags inflate following serious...Ch. 10 - Lithium reacts with nitrogen gas according to the...Ch. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Prob. 89ECh. 10 - Carbon monoxide gas reacts with hydrogen gas to...Ch. 10 - Prob. 91ECh. 10 - Prob. 92ECh. 10 - Prob. 93ECh. 10 - Use the vander Waals equation and the ideal gas...Ch. 10 - Pennies that are currently being minted are...Ch. 10 - A 2.85 g sample of an unknown chlorofluorocarbon...Ch. 10 - Prob. 97ECh. 10 - A 118 mL flask is evacuated and found to have a...Ch. 10 - Prob. 99ECh. 10 - A gaseous hydrogen- and carbon-containing compound...Ch. 10 - Prob. 101ECh. 10 - Consider the reaction: 2Ag2O(s)4Ag(s)+O2(g) If...Ch. 10 - When hydrochloric acid is poured over potassium...Ch. 10 - Consider the reaction: 2SO2(g)+O2(g)2SO(g)3 If...Ch. 10 - Ammonium carbonate decomposes upon heating...Ch. 10 - Ammonium nitrate decomposes explosively upon...Ch. 10 - Prob. 107ECh. 10 - Prob. 108ECh. 10 - Gaseous ammonia is injected into the exhaust...Ch. 10 - Prob. 110ECh. 10 - Prob. 111ECh. 10 - Prob. 112ECh. 10 - Prob. 113ECh. 10 - Prob. 114ECh. 10 - Prob. 115ECh. 10 - Prob. 116ECh. 10 - Prob. 117ECh. 10 - Prob. 118ECh. 10 - Prob. 119ECh. 10 - Prob. 120ECh. 10 - Prob. 121ECh. 10 - Prob. 122ECh. 10 - Prob. 123ECh. 10 - Prob. 124ECh. 10 - Prob. 125ECh. 10 - Prob. 126ECh. 10 - When 0.583 g of neon is added to an 800-cm3bulb...Ch. 10 - A gas mixture composed of helium and argon has a...Ch. 10 - Prob. 129ECh. 10 - Prob. 130ECh. 10 - Prob. 131ECh. 10 - Prob. 132ECh. 10 - Prob. 133ECh. 10 - Prob. 134ECh. 10 - The atmosphere slowly oxidizes hydrocarbons in a...Ch. 10 - Prob. 136ECh. 10 - Prob. 137ECh. 10 - Prob. 138ECh. 10 - Prob. 139ECh. 10 - Prob. 140ECh. 10 - Prob. 141ECh. 10 - Prob. 142ECh. 10 - Prob. 143ECh. 10 - Which gas would you expect to deviate most from...Ch. 10 - Prob. 145ECh. 10 - Prob. 146ECh. 10 - Prob. 147ECh. 10 - Prob. 148ECh. 10 - Prob. 149ECh. 10 - Prob. 150ECh. 10 - Prob. 151ECh. 10 - Calculate the pressure exerted by 1 mol of an...Ch. 10 - Prob. 153ECh. 10 - Prob. 1SAQCh. 10 - Prob. 2SAQCh. 10 - Prob. 3SAQCh. 10 - Prob. 4SAQCh. 10 - Prob. 5SAQCh. 10 - Prob. 6SAQCh. 10 - Prob. 7SAQCh. 10 - A gas mixture is a 1.55-L container at 298 K...Ch. 10 - Prob. 9SAQCh. 10 - Prob. 10SAQCh. 10 - Prob. 11SAQCh. 10 - Prob. 12SAQCh. 10 - Prob. 13SAQCh. 10 - Prob. 14SAQCh. 10 - Prob. 15SAQ
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