EBK CHEMISTRY:CENTRAL SCIENCE
14th Edition
ISBN: 9780134554570
Author: Brown
Publisher: PEARSON
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Chapter 10, Problem 120IE
(a)
Interpretation Introduction
To determine: The percentage of the composition of the given substance.
(b)
Interpretation Introduction
To determine: The empirical formula mass of the given herbicide.
(c)
Interpretation Introduction
To determine: The information required to calculate the molecular formula of the given herbicide.
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Use the References to access important values if needed for this question.
What is the IUPAC name of each of the the following?
0
CH3CHCNH₂
CH3
CH3CHCNHCH2CH3
CH3
You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Chapter 10 Solutions
EBK CHEMISTRY:CENTRAL SCIENCE
Ch. 10.2 - Prob. 10.1.1PECh. 10.2 -
Gallium melts just above room temperature...Ch. 10.2 - Prob. 10.2.1PECh. 10.2 - Prob. 10.2.2PECh. 10.3 - Prob. 10.3.1PECh. 10.3 - Prob. 10.3.2PECh. 10.4 - Prob. 10.4.1PECh. 10.4 - Prob. 10.4.2PECh. 10.4 - Prob. 10.5.1PECh. 10.4 - Prob. 10.5.2PE
Ch. 10.4 - Prob. 10.6.1PECh. 10.4 - Prob. 10.6.2PECh. 10.5 - Prob. 10.7.1PECh. 10.5 - Prob. 10.7.2PECh. 10.5 - Prob. 10.8.1PECh. 10.5 - Prob. 10.8.2PECh. 10.5 - Prob. 10.9.1PECh. 10.5 - Prob. 10.9.2PECh. 10.6 - Prob. 10.10.1PECh. 10.6 - Prob. 10.10.2PECh. 10.6 - Prob. 10.11.1PECh. 10.6 - Prob. 10.11.2PECh. 10.7 - Prob. 10.12.1PECh. 10.7 - Prob. 10.12.2PECh. 10.8 - Fill in the blanks for the following statement:...Ch. 10.8 - Prob. 10.13.2PECh. 10.8 - Prob. 10.14.1PECh. 10.8 - Prob. 10.14.2PECh. 10.9 - Calculate the pressure of a 2975-mol sample of N2...Ch. 10.9 - Prob. 10.15.2PECh. 10 - Prob. 1DECh. 10 - Prob. 1ECh. 10 - Prob. 2ECh. 10 - Consider the sample of gas depicted here_ What...Ch. 10 - Imagine that the reaction 2CO(g)+O2(g)2CO(g)...Ch. 10 - Suppose you have a fixed amount of an ideal gas at...Ch. 10 - Prob. 6ECh. 10 - Prob. 7ECh. 10 - Prob. 8ECh. 10 - Prob. 9ECh. 10 - Prob. 10ECh. 10 -
10.11 A thin glass tube 1 m long is filled with...Ch. 10 -
10.12 The graph below shows the change in...Ch. 10 - Prob. 13ECh. 10 - Prob. 14ECh. 10 - Prob. 15ECh. 10 - Prob. 16ECh. 10 - Prob. 17ECh. 10 - a. The compound 1-iodododecane is a nonvolatile...Ch. 10 - Prob. 19ECh. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - Prob. 22ECh. 10 - Prob. 23ECh. 10 - Prob. 24ECh. 10 - You have a gas at 25C confined to a cylinder with...Ch. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Nitrogen and hydrogen gases react to form ammonia...Ch. 10 -
10.29
a. What conditions are represented by the...Ch. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - Prob. 33ECh. 10 - Prob. 34ECh. 10 - Prob. 35ECh. 10 - Prob. 36ECh. 10 - Calculate the number of molecules in deep breath...Ch. 10 - If the pressure exerted by ozone, O3, in the...Ch. 10 - A scuba diver’s tank contain 0.29 kg of O2...Ch. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Chlorine is widely used to purify municipal water...Ch. 10 - Many gases are shipped in high-pressure...Ch. 10 - Prob. 45ECh. 10 - Prob. 46ECh. 10 - Rank the following gases from least to denser at...Ch. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - Prob. 51ECh. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Prob. 54ECh. 10 - Magnesium can be used as a ‘getter” in evacuated...Ch. 10 - Prob. 56ECh. 10 - The metabolic oxidation of glucose, C6H12O6, in...Ch. 10 - Prob. 58ECh. 10 - Prob. 59ECh. 10 - Prob. 60ECh. 10 - Consider the apparatus shown in the following...Ch. 10 - Prob. 62ECh. 10 - A mixture containing 0.75 mol He(g), 0.330 mol...Ch. 10 - A deep-sea diver uses a gas cylinder with a volume...Ch. 10 - Prob. 65ECh. 10 - Prob. 66ECh. 10 - Prob. 67ECh. 10 - Prob. 68ECh. 10 - Prob. 69ECh. 10 - Prob. 70ECh. 10 - Prob. 71ECh. 10 - Prob. 72ECh. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - Prob. 75ECh. 10 - Indicate which of the following statement...Ch. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - Prob. 79ECh. 10 - Suppose you have two 1-L flasks, one containing N2...Ch. 10 - Prob. 81ECh. 10 -
10.8
Place the following gases in order of...Ch. 10 - Prob. 83ECh. 10 - Prob. 84ECh. 10 - Prob. 85ECh. 10 - Prob. 86ECh. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Prob. 89ECh. 10 - Prob. 90ECh. 10 - Prob. 91ECh. 10 - Prob. 92ECh. 10 - Prob. 93ECh. 10 - Prob. 94ECh. 10 - Prob. 95ECh. 10 - Prob. 96ECh. 10 - Prob. 97AECh. 10 - A gas bubble with a volume of 1.0 mm3 originates...Ch. 10 - A 15.0-L tank is filled with helium gas at a...Ch. 10 - Prob. 100AECh. 10 - Prob. 101AECh. 10 - Prob. 102AECh. 10 - Prob. 103AECh. 10 - Prob. 104AECh. 10 - Prob. 105AECh. 10 - Prob. 106AECh. 10 - Prob. 107AECh. 10 - Prob. 108AECh. 10 - Prob. 109AECh. 10 - The density of gas of unknown molar mass was...Ch. 10 - A glass vessel fitted with a stopcock valve has a...Ch. 10 - Prob. 112AECh. 10 -
10.113 consider the following gases. All at STP:...Ch. 10 - Prob. 114AECh. 10 - Prob. 115AECh. 10 - Prob. 116AECh. 10 - Prob. 117AECh. 10 - Prob. 118IECh. 10 - Prob. 119IECh. 10 - Prob. 120IECh. 10 -
10.121 A 4.00-g sample of a mixture of CaO and...Ch. 10 - Prob. 122IECh. 10 - Prob. 123IECh. 10 - Chlorine dioxide gas (CIO2) is used as a...Ch. 10 - Natural gas is very abundant in many Middle...Ch. 10 - Prob. 126IECh. 10 - Prob. 127IE
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- Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forward
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