Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 10, Problem 10B.1ST
Interpretation Introduction

Interpretation:

The energy of interaction has to be calculated using the medium as water with given data.

Concept introduction:

Polar molecules are the molecules having a positive and negative end and so there will be a charge separation.

A polar molecule is a molecule where the polar bonds are asymmetrically arranged (the dipoles do not cancel)

A nonpolar molecule is a molecule with no polar bonds or a molecule where the polar bonds are symmetrically arranged.

In polar molecule the charge separation occurred with respect to the difference in electronegativity of atoms in the molecule.

Interaction between partial charges:

V(r)=Q1Q24πεrQ1andQ2-Chargesr-Separationε-Permitivityof mediumElements Of Physical Chemistry, Chapter 10, Problem 10B.1ST

ε=εrε0εr-Relativepermitivityε0-Vacuumpermitivity

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