If the species is neutral compound whether the black sphere in the given molecular shape can represent selenium or not is to be determined. Concept introduction: The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs. The molecular geometry table is as follows: Steric number or Number electron groups Number of lone pairs Molecular geometry 2 0 Linear 3 0 Trigonal planar 1 Bent 4 0 Tetrahedral 1 Trigonal pyramidal 2 Bent 5 0 Trigonal bipyramidal 1 Sea-saw 2 T-shaped 3 Linear 6 0 Octahedral 1 Square pyramidal 2 Square planar

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Answer 1

Question

Chapter 10, Problem 10.89P

(a)

Interpretation Introduction

Interpretation:

If the species is neutral compound whether the black sphere in the given molecular shape can represent selenium or not is to be determined.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

(b)

Interpretation Introduction

Interpretation:

If the species is anion whether the black sphere in the given molecular shape can represent nitrogen or not is to be determined.

Concept introduction:

When a neutral atom gains electrons, it acquires a negative charge on it due to the presence of excess electrons as compared to the protons. This results in the formation of the anion. When a neutral atom loses electrons, it acquires a positive charge on it due to the presence of excess protons as compared to the electrons. This results in the formation of the cation.

(c)

Interpretation Introduction

Interpretation:

The charge on the species is to be determined if the black sphere represents a bromine atom.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

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2. Write a complete mechanism for the reaction shown below. NaOCH LOCH₁ O₂N NO2 CH₂OH, 20 °C O₂N NO2

4. Propose a synthesis of the target molecules from the respective starting materials. a) b) LUCH C Br OH

The following mechanism for the gas phase reaction of H2 and ICI that is consistent with the observed rate law is: step 1 step 2 slow: H2(g) +ICI(g) → HCl(g) + HI(g) fast: ICI(g) + HI(g) → HCl(g) + |2(g) (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. + → + (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete the rate law for the overall reaction that is consistent with this mechanism. (Use the form k[A][B]"..., where '1' is understood (so don't write it) for m, n etc.) Rate =

Answer 2

Question

Chapter 10, Problem 10.89P

(a)

Interpretation Introduction

Interpretation:

If the species is neutral compound whether the black sphere in the given molecular shape can represent selenium or not is to be determined.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

(b)

Interpretation Introduction

Interpretation:

If the species is anion whether the black sphere in the given molecular shape can represent nitrogen or not is to be determined.

Concept introduction:

When a neutral atom gains electrons, it acquires a negative charge on it due to the presence of excess electrons as compared to the protons. This results in the formation of the anion. When a neutral atom loses electrons, it acquires a positive charge on it due to the presence of excess protons as compared to the electrons. This results in the formation of the cation.

(c)

Interpretation Introduction

Interpretation:

The charge on the species is to be determined if the black sphere represents a bromine atom.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

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Answer 3

Question

Chapter 10, Problem 10.89P

(a)

Interpretation Introduction

Interpretation:

If the species is neutral compound whether the black sphere in the given molecular shape can represent selenium or not is to be determined.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

(b)

Interpretation Introduction

Interpretation:

If the species is anion whether the black sphere in the given molecular shape can represent nitrogen or not is to be determined.

Concept introduction:

When a neutral atom gains electrons, it acquires a negative charge on it due to the presence of excess electrons as compared to the protons. This results in the formation of the anion. When a neutral atom loses electrons, it acquires a positive charge on it due to the presence of excess protons as compared to the electrons. This results in the formation of the cation.

(c)

Interpretation Introduction

Interpretation:

The charge on the species is to be determined if the black sphere represents a bromine atom.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

Expert Solution & Answer

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Answer 4

Question

Chapter 10, Problem 10.89P

(a)

Interpretation Introduction

Interpretation:

If the species is neutral compound whether the black sphere in the given molecular shape can represent selenium or not is to be determined.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

(b)

Interpretation Introduction

Interpretation:

If the species is anion whether the black sphere in the given molecular shape can represent nitrogen or not is to be determined.

Concept introduction:

When a neutral atom gains electrons, it acquires a negative charge on it due to the presence of excess electrons as compared to the protons. This results in the formation of the anion. When a neutral atom loses electrons, it acquires a positive charge on it due to the presence of excess protons as compared to the electrons. This results in the formation of the cation.

(c)

Interpretation Introduction

Interpretation:

The charge on the species is to be determined if the black sphere represents a bromine atom.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

Expert Solution & Answer

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Answer 5

Chapter 10, Problem 10.89P

(a)

Interpretation Introduction

Interpretation:

If the species is neutral compound whether the black sphere in the given molecular shape can represent selenium or not is to be determined.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

(b)

Interpretation Introduction

Interpretation:

If the species is anion whether the black sphere in the given molecular shape can represent nitrogen or not is to be determined.

Concept introduction:

When a neutral atom gains electrons, it acquires a negative charge on it due to the presence of excess electrons as compared to the protons. This results in the formation of the anion. When a neutral atom loses electrons, it acquires a positive charge on it due to the presence of excess protons as compared to the electrons. This results in the formation of the cation.

(c)

Interpretation Introduction

Interpretation:

The charge on the species is to be determined if the black sphere represents a bromine atom.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

Answer 6

Chapter 10, Problem 10.89P

(a)

Interpretation Introduction

Interpretation:

If the species is neutral compound whether the black sphere in the given molecular shape can represent selenium or not is to be determined.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

Answer 7

Chapter 10, Problem 10.89P

(a)

Interpretation Introduction

Interpretation:

If the species is neutral compound whether the black sphere in the given molecular shape can represent selenium or not is to be determined.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

Answer 8

(b)

Interpretation Introduction

Interpretation:

If the species is anion whether the black sphere in the given molecular shape can represent nitrogen or not is to be determined.

Concept introduction:

When a neutral atom gains electrons, it acquires a negative charge on it due to the presence of excess electrons as compared to the protons. This results in the formation of the anion. When a neutral atom loses electrons, it acquires a positive charge on it due to the presence of excess protons as compared to the electrons. This results in the formation of the cation.

Answer 9

(b)

Interpretation Introduction

Interpretation:

If the species is anion whether the black sphere in the given molecular shape can represent nitrogen or not is to be determined.

Concept introduction:

When a neutral atom gains electrons, it acquires a negative charge on it due to the presence of excess electrons as compared to the protons. This results in the formation of the anion. When a neutral atom loses electrons, it acquires a positive charge on it due to the presence of excess protons as compared to the electrons. This results in the formation of the cation.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The charge on the species is to be determined if the black sphere represents a bromine atom.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

Answer 11

(c)

Interpretation Introduction

Interpretation:

The charge on the species is to be determined if the black sphere represents a bromine atom.

Concept introduction:

The molecular shape is the three-dimensional arrangement of atoms in the molecule. It depends on the bond pairs as well as lone pairs.

The molecular geometry table is as follows:

Steric number or Number electron groups Number of lone pairs Molecular geometry

2

0

Linear

3
0 Trigonal planar
1 Bent

4
0 Tetrahedral
1 Trigonal pyramidal
2 Bent

5
0 Trigonal bipyramidal
1 Sea-saw
2 T-shaped
3 Linear

6
0 Octahedral
1 Square pyramidal
2
Square planar

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 10.1 - Write a Lewis structure for H2S; ; SOCl2. Ch. 10.1 - Prob. 10.1BFP Ch. 10.1 - Prob. 10.2AFP Ch. 10.1 - Prob. 10.2BFP Ch. 10.1 - Prob. 10.3AFP Ch. 10.1 - Prob. 10.3BFP Ch. 10.1 - Prob. 10.4AFP Ch. 10.1 - Prob. 10.4BFP Ch. 10.1 - Write a Lewis structure with minimal formal...Ch. 10.1 - Prob. 10.5BFP

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Chapter 10 Solutions

Steric number or Number electron groups	Number of lone pairs	Molecular geometry
2	0	Linear
3	0	Trigonal planar
3	1	Bent
4	0	Tetrahedral
	1	Trigonal pyramidal
	2	Bent
5	0	Trigonal bipyramidal
	1	Sea-saw
	2	T-shaped
	3	Linear
6	0	Octahedral
	1	Square pyramidal
	2	Square planar