The steps are to be labelled as either proton transfer or S N 2 under each reaction arrow in the mechanism. Concept introduction: Halogens like Cl 2 , Br 2 , and I 2 can behave as substrates in S N 2 reactions in part because of their polarizability. Cl 2 , Br 2 , and I 2 are relatively highly polarizable due to their abundance of electrons, especially nonbonded electrons. Consequently, when an electron-rich species like the enolate anion approaches, the electrons on the halogen molecule are repelled quite readily, generating a substantial induced dipole. The halogen atom that is nearer the nucleophile, therefore, becomes electron poor. As a result, a curved arrow can be drawn from the electron-rich nucleophile to the electron-poor halogen atom.

Question

Want to see the full answer?

Answer 1

Question

Chapter 10, Problem 10.7YT

Interpretation Introduction

Interpretation:

The steps are to be labelled as either proton transfer or S_N2 under each reaction arrow in the mechanism.

Concept introduction:

Halogens like Cl₂, Br₂, and I₂ can behave as substrates in S_N2 reactions in part because of their polarizability. Cl₂, Br₂, and I₂ are relatively highly polarizable due to their abundance of electrons, especially nonbonded electrons. Consequently, when an electron-rich species like the enolate anion approaches, the electrons on the halogen molecule are repelled quite readily, generating a substantial induced dipole. The halogen atom that is nearer the nucleophile, therefore, becomes electron poor. As a result, a curved arrow can be drawn from the electron-rich nucleophile to the electron-poor halogen atom.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Bookmarks Profiles Tab Window Help Chemical Formula - Aktiv Che X + → C 11 a app.aktiv.com Google Chrome isn't your default browser Set as default Question 12 of 16 Q Fri Feb 2 Verify it's you New Chrome availabl- Write the balanced molecular chemical equation for the reaction in aqueous solution for mercury(I) nitrate and chromium(VI) sulfate. If no reaction occurs, simply write only NR. Be sure to include the proper phases for all species within the reaction. 3 Hg(NO3)2(aq) + Cг2(SO4)3(aq) → 3 Hg₂SO (s) + 2 Cr(NO3), (aq) ean Ui mate co ence an climate bility inc ulnerabili women, main critic CLIMATE-INI ernational + 10 O 2 W FEB 1 + 4- 3- 2- 2 2 ( 3 4 NS 28 2 ty 56 + 2+ 3+ 4+ 7 8 9 0 5 (s) (1) Ch O 8 9 (g) (aq) Hg NR CI Cr x H₂O A 80 Q A DII A F2 F3 FA F5 F6 F7 F8 F9 #3 EA $ do 50 % 6 CO & 7 E R T Y U 8 ( 9 0 F10 34 F11 川 F12 Subr + delete 0 { P }

Deducing the reactants of a Diels-Alder reaction n the molecule on the right-hand side of this organic reaction be made in good yield from no more than two reactants, in one step, by moderately heating the reactants? ? Δ • If your answer is yes, then draw the reactant or reactants in the drawing area below. You can draw the reactants in any arrangement you like. • If your answer is no, check the box under the drawing area instead. Explanation Check Click and drag to start drawing a structure. >

Predict the major products of the following organic reaction: + Some important notes: A ? • Draw the major product, or products, of the reaction in the drawing area below. • If there aren't any products, because no reaction will take place, check the box below the drawing area instead. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. Explanation Check Click and drag to start drawing a structure.