PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
2nd Edition
ISBN: 9781266811852
Author: SMITH
Publisher: MCG
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Question
Chapter 10, Problem 10.48AP
a.
Interpretation Introduction
Interpretation:
The condensed structure of given compound has to be written.
Concept Introduction:
Condensed Structures:
The condensed structure is drawn for the compounds having a chain of atoms bonded together. It cannot be used to draw the ring structure. It is used to represent the organic structures in a simple form.
The following rules can be used to draw a condensed structure:
- In order to write a condensed structure start at the left side and then ends at right side of the compound.
- Then lone pairs of electrons on heteroatom have to be omitted. Further simplify the compound and written in parentheses form.
b.
Interpretation Introduction
Interpretation:
The condensed formula of given compound has to be drawn.
Concept Introduction:
Refer part a.
c.
Interpretation Introduction
Interpretation:
The condensed structure of given compound has to be represented.
Concept Introduction:
Refer part a.
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Solution
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Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag
the appropriate image to the correct position in the reactions.)
Route 1
Aldehyde 1
or
+98
Aldehyde 2
Route 2
Q6
+100
Solved in 1 attempt
Q7
+95
Solved in 2 attempts
Q8
+98
Unlimited attempts
possible
+
+
Grignard 1
OH
H3O+
Grignard 2
Answer Bank
Q9
+90
MgBr
Unlimited attempts
possible
CH3CH2CH2MgBr
Q10
Unlimited attempts
Q11
?
?
+100
in 1 attempt
2-methyl-3-hexanol
CH3CH2MgBr
H
H
о
H
Attempt 3
2) (4 pt) After the reaction was completed, the student collected the following data. Crude
product data is the data collected after the reaction is finished, but before the product
is purified. "Pure" product data is the data collected after attempted purification using
recrystallization.
Student B's data:
Crude product data
"Pure"
product data
after
recrystallization
Crude mass: 0.93 g grey solid
Crude mp: 96-106 °C
Crude % yield:
Pure mass: 0.39 g white solid
Pure mp: 111-113 °C
Pure % yield:
a) Calculate the crude and pure percent yields for the student's reaction.
b) Summarize what is indicated by the crude and pure melting points.
Don't used hand raiting
Chapter 10 Solutions
PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
Ch. 10.1 - Prob. 10.1PCh. 10.2 - Fill in all Hs and lone pairs in each compound. a....Ch. 10.3 - Convert each compound to a condensed formula.Ch. 10.3 - Convert each condensed formula to a complete...Ch. 10.3 - Convert each skeletal structure to a complete...Ch. 10.3 - How many Hs are bonded to each indicated carbon...Ch. 10.4 - Identify the functional groups in each compound....Ch. 10.4 - For each compound: [1] Identify the functional...Ch. 10.4 - Prob. 10.9PCh. 10.4 - Prob. 10.10P
Ch. 10.4 - Convert the ball-and-stick model of the local...Ch. 10.5 - How many hydrogen atoms are present in each...Ch. 10.5 - Prob. 10.13PCh. 10.5 - Prob. 10.14PCh. 10.5 - Prob. 10.15PCh. 10.5 - Prob. 10.16PCh. 10.6 - Give the IUPAC name for each compound.Ch. 10.6 - Prob. 10.18PCh. 10.6 - Prob. 10.19PCh. 10.6 - Prob. 10.20PCh. 10.7 - Prob. 10.21PCh. 10.7 - Prob. 10.22PCh. 10.9 - Answer the following questions about pentane...Ch. 10.9 - Prob. 10.24PCh. 10.9 - Prob. 10.25PCh. 10.10 - Prob. 10.26PCh. 10 - Prob. 10.27UKCCh. 10 - Prob. 10.28UKCCh. 10 - Prob. 10.29UKCCh. 10 - Prob. 10.30UKCCh. 10 - Prob. 10.31UKCCh. 10 - The largest known cycloalkane with a single ring...Ch. 10 - Draw three constitutional isomers having molecular...Ch. 10 - Draw four constitutional isomers having molecular...Ch. 10 - Answer the following questions about the alkane...Ch. 10 - Answer the questions in Problem 10.35 for the...Ch. 10 - Prob. 10.37UKCCh. 10 - Procaine (trade name Novocain) is a local...Ch. 10 - Prob. 10.39APCh. 10 - Prob. 10.40APCh. 10 - Complete each structure by filling in all Hs and...Ch. 10 - Prob. 10.42APCh. 10 - Prob. 10.43APCh. 10 - Prob. 10.44APCh. 10 - Prob. 10.45APCh. 10 - Prob. 10.46APCh. 10 - Convert each compound to a condensed structure.Ch. 10 - Prob. 10.48APCh. 10 - Prob. 10.49APCh. 10 - Prob. 10.50APCh. 10 - Prob. 10.51APCh. 10 - Prob. 10.52APCh. 10 - Albuterol (trade names: Proventil and Ventolin) is...Ch. 10 - Prob. 10.54APCh. 10 - Prob. 10.55APCh. 10 - Prob. 10.56APCh. 10 - Prob. 10.57APCh. 10 - Prob. 10.58APCh. 10 - Prob. 10.59APCh. 10 - Prob. 10.60APCh. 10 - Prob. 10.61APCh. 10 - Prob. 10.62APCh. 10 - Prob. 10.63APCh. 10 - Prob. 10.64APCh. 10 - Prob. 10.65APCh. 10 - Prob. 10.66APCh. 10 - Prob. 10.67APCh. 10 - Prob. 10.68APCh. 10 - Prob. 10.69APCh. 10 - Prob. 10.70APCh. 10 - Give the IUPAC name for each compound.Ch. 10 - Prob. 10.72APCh. 10 - Prob. 10.73APCh. 10 - Prob. 10.74APCh. 10 - Prob. 10.75APCh. 10 - Prob. 10.76APCh. 10 - Give the structure corresponding to each IUPAC...Ch. 10 - Prob. 10.78APCh. 10 - Prob. 10.79APCh. 10 - Each of the following IUPAC names is incorrect....Ch. 10 - Prob. 10.81APCh. 10 - Prob. 10.82APCh. 10 - Prob. 10.83APCh. 10 - Prob. 10.84APCh. 10 - Prob. 10.85APCh. 10 - Prob. 10.86APCh. 10 - Write a balanced equation for the incomplete...Ch. 10 - Prob. 10.88APCh. 10 - Prob. 10.89APCh. 10 - Prob. 10.90APCh. 10 - Prob. 10.91APCh. 10 - Prob. 10.92APCh. 10 - Answer the following questions for the cycloalkane...Ch. 10 - Prob. 10.94APCh. 10 - Prob. 10.95CPCh. 10 - Prob. 10.96CP
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- A DEPT NMR spectrum is shown for a molecule with the molecular formula of C5H12O. Draw the structure that best fits this data. 200 180 160 140 120 100 一盆 00 40 8- 20 ppm 0 Qarrow_forwardDon't used hand raitingarrow_forwardShown below is the major resonance structure for a molecule. Draw the second best resonance structure of the molecule. Include all non-zero formal charges. H. H. +N=C H H H Cl: Click and drag to start drawing a structure. : ? g B S olo Ar B Karrow_forward
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